IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-50801-3.html
   My bibliography  Save this article

Photosynthesis of CH3OH via oxygen-atom-grafting from CO2 to CH4 enabled by AuPd/GaN

Author

Listed:
  • Hui Su

    (McGill University)

  • Jing-Tan Han

    (McGill University)

  • Botong Miao

    (McGill University)

  • Mahdi Salehi

    (McGill University)

  • Chao-Jun Li

    (McGill University)

Abstract

The direct co-conversion of methane and carbon dioxide into valuable chemicals has been a longstanding scientific pursuit for carbon neutrality and combating climate change. Herein, we present a photo-driven chemical process that reforms these two major greenhouse gases together to generate green methanol and CO, two high-valued industrial chemicals. Isotopic labeling and control experiments indicate an oxygen-atom-graft occurs, wherein CO2 transfers one O into the C–H bond of CH4 via photo-activated interfacial catalysis with AuPd nanoparticles supported on GaN. The photoexcited AuPd/GaN interface effectively orchestrates the CH4 oxidation and the CO2 reduction producing 13.66 mmol g−1 of CH3OH yield over 10 h. This design provides a solid scientific basis for the photo-driven oxygen-atom-grafting process to be further extended to visible light region.

Suggested Citation

  • Hui Su & Jing-Tan Han & Botong Miao & Mahdi Salehi & Chao-Jun Li, 2024. "Photosynthesis of CH3OH via oxygen-atom-grafting from CO2 to CH4 enabled by AuPd/GaN," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50801-3
    DOI: 10.1038/s41467-024-50801-3
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-50801-3
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-50801-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Xiyi Li & Chao Li & Youxun Xu & Qiong Liu & Mounib Bahri & Liquan Zhang & Nigel D. Browning & Alexander J. Cowan & Junwang Tang, 2023. "Efficient hole abstraction for highly selective oxidative coupling of methane by Au-sputtered TiO2 photocatalysts," Nature Energy, Nature, vol. 8(9), pages 1013-1022, September.
    2. Chang Liu & Jincan Kang & Zheng-Qing Huang & Yong-Hong Song & Yong-Shan Xiao & Jian Song & Jia-Xin He & Chun-Ran Chang & Han-Qing Ge & Ye Wang & Zhao-Tie Liu & Zhong-Wen Liu, 2021. "Gallium nitride catalyzed the direct hydrogenation of carbon dioxide to dimethyl ether as primary product," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    3. Xiaoyang Huang & Ouardia Akdim & Mark Douthwaite & Kai Wang & Liang Zhao & Richard J. Lewis & Samuel Pattisson & Isaac T. Daniel & Peter J. Miedziak & Greg Shaw & David J. Morgan & Sultan M. Althahban, 2022. "Au–Pd separation enhances bimetallic catalysis of alcohol oxidation," Nature, Nature, vol. 603(7900), pages 271-275, March.
    4. Lili Zhang & Le Liu & Ziye Pan & Rui Zhang & Zhuoyang Gao & Guangming Wang & Keke Huang & Xiaoyue Mu & Fuquan Bai & Yan Wang & Wei Zhang & Zhonghua Cui & Lu Li, 2022. "Visible-light-driven non-oxidative dehydrogenation of alkanes at ambient conditions," Nature Energy, Nature, vol. 7(11), pages 1042-1051, November.
    5. Davis, Steven J & Lewis, Nathan S. & Shaner, Matthew & Aggarwal, Sonia & Arent, Doug & Azevedo, Inês & Benson, Sally & Bradley, Thomas & Brouwer, Jack & Chiang, Yet-Ming & Clack, Christopher T.M. & Co, 2018. "Net-Zero Emissions Energy Systems," Institute of Transportation Studies, Working Paper Series qt7qv6q35r, Institute of Transportation Studies, UC Davis.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. de Chalendar, Jacques A. & Benson, Sally M., 2021. "A physics-informed data reconciliation framework for real-time electricity and emissions tracking," Applied Energy, Elsevier, vol. 304(C).
    2. Xi Yang & Chris P. Nielsen & Shaojie Song & Michael B. McElroy, 2022. "Breaking the hard-to-abate bottleneck in China’s path to carbon neutrality with clean hydrogen," Nature Energy, Nature, vol. 7(10), pages 955-965, October.
    3. Kazuki Shun & Kohsuke Mori & Takumi Kidawara & Satoshi Ichikawa & Hiromi Yamashita, 2024. "Heteroatom doping enables hydrogen spillover via H+/e− diffusion pathways on a non-reducible metal oxide," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Yi, Yuxin & Zhang, Liming & Du, Lei & Sun, Helin, 2024. "Cross-regional integration of renewable energy and corporate carbon emissions: Evidence from China's cross-regional surplus renewable energy spot trading pilot," Energy Economics, Elsevier, vol. 135(C).
    5. Grace D. Kroeger & Matthew G. Burgess, 2024. "Electric utility plans are consistent with Renewable Portfolio Standards and Clean Energy Standards in most US states," Climatic Change, Springer, vol. 177(1), pages 1-18, January.
    6. Stede, Jan & Pauliuk, Stefan & Hardadi, Gilang & Neuhoff, Karsten, 2021. "Carbon pricing of basic materials: Incentives and risks for the value chain and consumers," EconStor Open Access Articles and Book Chapters, ZBW - Leibniz Information Centre for Economics, vol. 189.
    7. Xie, Shiwei & Hu, Zhijian & Wang, Jueying & Chen, Yuwei, 2020. "The optimal planning of smart multi-energy systems incorporating transportation, natural gas and active distribution networks," Applied Energy, Elsevier, vol. 269(C).
    8. Josefine A. Olsson & Sabbie A. Miller & Mark G. Alexander, 2023. "Near-term pathways for decarbonizing global concrete production," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    9. Isaac Holmes-Gentle & Saurabh Tembhurne & Clemens Suter & Sophia Haussener, 2023. "Kilowatt-scale solar hydrogen production system using a concentrated integrated photoelectrochemical device," Nature Energy, Nature, vol. 8(6), pages 586-596, June.
    10. Ren, Lei & Zhou, Sheng & Peng, Tianduo & Ou, Xunmin, 2022. "Greenhouse gas life cycle analysis of China's fuel cell medium- and heavy-duty trucks under segmented usage scenarios and vehicle types," Energy, Elsevier, vol. 249(C).
    11. Ángel Galán-Martín & Daniel Vázquez & Selene Cobo & Niall Dowell & José Antonio Caballero & Gonzalo Guillén-Gosálbez, 2021. "Delaying carbon dioxide removal in the European Union puts climate targets at risk," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    12. Shao, Tianming & Pan, Xunzhang & Li, Xiang & Zhou, Sheng & Zhang, Shu & Chen, Wenying, 2022. "China's industrial decarbonization in the context of carbon neutrality: A sub-sectoral analysis based on integrated modelling," Renewable and Sustainable Energy Reviews, Elsevier, vol. 170(C).
    13. Sovacool, Benjamin K. & Martiskainen, Mari & Furszyfer Del Rio, Dylan D., 2021. "Knowledge, energy sustainability, and vulnerability in the demographics of smart home technology diffusion," Energy Policy, Elsevier, vol. 153(C).
    14. Furszyfer Del Rio, Dylan D. & Sovacool, Benjamin K. & Foley, Aoife M. & Griffiths, Steve & Bazilian, Morgan & Kim, Jinsoo & Rooney, David, 2022. "Decarbonizing the ceramics industry: A systematic and critical review of policy options, developments and sociotechnical systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    15. Yang Ou & Christopher Roney & Jameel Alsalam & Katherine Calvin & Jared Creason & Jae Edmonds & Allen A. Fawcett & Page Kyle & Kanishka Narayan & Patrick O’Rourke & Pralit Patel & Shaun Ragnauth & Ste, 2021. "Deep mitigation of CO2 and non-CO2 greenhouse gases toward 1.5 °C and 2 °C futures," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    16. Dan Tong & David J. Farnham & Lei Duan & Qiang Zhang & Nathan S. Lewis & Ken Caldeira & Steven J. Davis, 2021. "Geophysical constraints on the reliability of solar and wind power worldwide," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    17. Patange, Omkar S. & Garg, Amit & Jayaswal, Sachin, 2022. "An integrated bottom-up optimization to investigate the role of BECCS in transitioning towards a net-zero energy system: A case study from Gujarat, India," Energy, Elsevier, vol. 255(C).
    18. Qiu, Rui & Hou, Shuhua & Meng, Zhiyi, 2021. "Low carbon air transport development trends and policy implications based on a scientometrics-based data analysis system," Transport Policy, Elsevier, vol. 107(C), pages 1-10.
    19. Huizhen Zhang & Pengfei Sun & Xiaozhen Fei & Xuejiao Wu & Zongyi Huang & Wanfu Zhong & Qiaobin Gong & Yanping Zheng & Qinghong Zhang & Shunji Xie & Gang Fu & Ye Wang, 2024. "Unusual facet and co-catalyst effects in TiO2-based photocatalytic coupling of methane," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    20. Park, Heejin & Jung, Yoonju & Park, Chungi & Lee, Jaeseung & Ghasemi, Masoomeh & Alam, Afroz & Kim, Hyeonjin & Kim, Jinwook & Park, Sojin & Choi, Kyungshik & You, Hyunseok & Ju, Hyunchul, 2023. "Performance evaluation and economic feasibility of a PAFC-based multi-energy hub system in South Korea," Energy, Elsevier, vol. 278(PB).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50801-3. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.