IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-44954-4.html
   My bibliography  Save this article

Pt-doped Ru nanoparticles loaded on ‘black gold’ plasmonic nanoreactors as air stable reduction catalysts

Author

Listed:
  • Gunjan Sharma

    (Tata Institute of Fundamental Research)

  • Rishi Verma

    (Tata Institute of Fundamental Research)

  • Shinya Masuda

    (The University of Tokyo)

  • Khaled Mohamed Badawy

    (Khalifa University)

  • Nirpendra Singh

    (Khalifa University)

  • Tatsuya Tsukuda

    (The University of Tokyo)

  • Vivek Polshettiwar

    (Tata Institute of Fundamental Research)

Abstract

This study introduces a plasmonic reduction catalyst, stable only in the presence of air, achieved by integrating Pt-doped Ru nanoparticles on black gold. This innovative black gold/RuPt catalyst showcases good efficiency in acetylene semi-hydrogenation, attaining over 90% selectivity with an ethene production rate of 320 mmol g−1 h−1. Its stability, evident in 100 h of operation with continuous air flow, is attributed to the synergy of co-existing metal oxide and metal phases. The catalyst’s stability is further enhanced by plasmon-mediated concurrent reduction and oxidation of the active sites. Finite-difference time-domain simulations reveal a five-fold electric field intensification near the RuPt nanoparticles, crucial for activating acetylene and hydrogen. Kinetic isotope effect analysis indicates the contribution from the plasmonic non-thermal effects along with the photothermal. Spectroscopic and in-situ Fourier transform infrared studies, combined with quantum chemical calculations, elucidate the molecular reaction mechanism, emphasizing the cooperative interaction between Ru and Pt in optimizing ethene production and selectivity.

Suggested Citation

  • Gunjan Sharma & Rishi Verma & Shinya Masuda & Khaled Mohamed Badawy & Nirpendra Singh & Tatsuya Tsukuda & Vivek Polshettiwar, 2024. "Pt-doped Ru nanoparticles loaded on ‘black gold’ plasmonic nanoreactors as air stable reduction catalysts," Nature Communications, Nature, vol. 15(1), pages 1-16, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-44954-4
    DOI: 10.1038/s41467-024-44954-4
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-44954-4
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-44954-4?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Shihui Zou & Baohui Lou & Kunran Yang & Wentao Yuan & Chongzhi Zhu & Yihan Zhu & Yonghua Du & Linfang Lu & Juanjuan Liu & Weixin Huang & Bo Yang & Zhongmiao Gong & Yi Cui & Yong Wang & Lu Ma & Jingyua, 2021. "Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Canyu Hu & Xing Chen & Jingxiang Low & Yaw-Wen Yang & Hao Li & Di Wu & Shuangming Chen & Jianbo Jin & He Li & Huanxin Ju & Chia-Hsin Wang & Zhou Lu & Ran Long & Li Song & Yujie Xiong, 2023. "Publisher Correction: Near-infrared-featured broadband CO2 reduction with water to hydrocarbons by surface plasmon," Nature Communications, Nature, vol. 14(1), pages 1-1, December.
    3. Canyu Hu & Xing Chen & Jingxiang Low & Yaw-Wen Yang & Hao Li & Di Wu & Shuangming Chen & Jianbo Jin & He Li & Huanxin Ju & Chia-Hsin Wang & Zhou Lu & Ran Long & Li Song & Yujie Xiong, 2023. "Near-infrared-featured broadband CO2 reduction with water to hydrocarbons by surface plasmon," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Saideep Singh & Rishi Verma & Nidhi Kaul & Jacinto Sa & Ajinkya Punjal & Shriganesh Prabhu & Vivek Polshettiwar, 2023. "Surface plasmon-enhanced photo-driven CO2 hydrogenation by hydroxy-terminated nickel nitride nanosheets," Nature Communications, Nature, vol. 14(1), pages 1-18, December.
    5. Linan Zhou & John Mark P. Martirez & Jordan Finzel & Chao Zhang & Dayne F. Swearer & Shu Tian & Hossein Robatjazi & Minhan Lou & Liangliang Dong & Luke Henderson & Phillip Christopher & Emily A. Carte, 2020. "Light-driven methane dry reforming with single atomic site antenna-reactor plasmonic photocatalysts," Nature Energy, Nature, vol. 5(1), pages 61-70, January.
    6. Emiliano Cortés & Wei Xie & Javier Cambiasso & Adam S. Jermyn & Ravishankar Sundararaman & Prineha Narang & Sebastian Schlücker & Stefan A. Maier, 2017. "Plasmonic hot electron transport drives nano-localized chemistry," Nature Communications, Nature, vol. 8(1), pages 1-10, April.
    7. Xiao Zhang & Xueqian Li & Du Zhang & Neil Qiang Su & Weitao Yang & Henry O. Everitt & Jie Liu, 2017. "Product selectivity in plasmonic photocatalysis for carbon dioxide hydrogenation," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xueying Wan & Yifan Li & Yihong Chen & Jun Ma & Ying-Ao Liu & En-Dian Zhao & Yadi Gu & Yilin Zhao & Yi Cui & Rongtan Li & Dong Liu & Ran Long & Kim Meow Liew & Yujie Xiong, 2024. "A nonmetallic plasmonic catalyst for photothermal CO2 flow conversion with high activity, selectivity and durability," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Yalin Guo & Yike Huang & Bin Zeng & Bing Han & Mohcin AKRI & Ming Shi & Yue Zhao & Qinghe Li & Yang Su & Lin Li & Qike Jiang & Yi-Tao Cui & Lei Li & Rengui Li & Botao Qiao & Tao Zhang, 2022. "Photo-thermo semi-hydrogenation of acetylene on Pd1/TiO2 single-atom catalyst," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Yingrui Zhang & Ziwei Ye & Chunchun Li & Qinglu Chen & Wafaa Aljuhani & Yiming Huang & Xin Xu & Chunfei Wu & Steven E. J. Bell & Yikai Xu, 2023. "General approach to surface-accessible plasmonic Pickering emulsions for SERS sensing and interfacial catalysis," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Jiaqi Zhao & Jinjia Liu & Zhenhua Li & Kaiwen Wang & Run Shi & Pu Wang & Qing Wang & Geoffrey I. N. Waterhouse & Xiaodong Wen & Tierui Zhang, 2023. "Ruthenium-cobalt single atom alloy for CO photo-hydrogenation to liquid fuels at ambient pressures," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Canyu Hu & Xing Chen & Jingxiang Low & Yaw-Wen Yang & Hao Li & Di Wu & Shuangming Chen & Jianbo Jin & He Li & Huanxin Ju & Chia-Hsin Wang & Zhou Lu & Ran Long & Li Song & Yujie Xiong, 2023. "Near-infrared-featured broadband CO2 reduction with water to hydrocarbons by surface plasmon," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Alexandra Tavasoli & Abdelaziz Gouda & Till Zähringer & Young Feng Li & Humayra Quaid & Camilo J. Viasus Perez & Rui Song & Mohini Sain & Geoffrey Ozin, 2023. "Enhanced hybrid photocatalytic dry reforming using a phosphated Ni-CeO2 nanorod heterostructure," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    7. Saideep Singh & Rishi Verma & Nidhi Kaul & Jacinto Sa & Ajinkya Punjal & Shriganesh Prabhu & Vivek Polshettiwar, 2023. "Surface plasmon-enhanced photo-driven CO2 hydrogenation by hydroxy-terminated nickel nitride nanosheets," Nature Communications, Nature, vol. 14(1), pages 1-18, December.
    8. Xin, Yanbin & Wang, Quanli & Sun, Jiabao & Sun, Bing, 2022. "Plasma in aqueous methanol: Influence of plasma initiation mechanism on hydrogen production," Applied Energy, Elsevier, vol. 325(C).
    9. Wenqing Zhang & Dawei Xi & Yihong Chen & Aobo Chen & Yawen Jiang & Hengjie Liu & Zeyu Zhou & Hui Zhang & Zhi Liu & Ran Long & Yujie Xiong, 2023. "Light-driven flow synthesis of acetic acid from methane with chemical looping," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Khandelwal, Akshat & Maarisetty, Dileep & Baral, Saroj Sundar, 2022. "Fundamentals and application of single-atom photocatalyst in sustainable energy and environmental applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    11. Liu, Xianglei & Cheng, Bo & Zhu, Qibin & Gao, Ke & Sun, Nan & Tian, Cheng & Wang, Jiaqi & Zheng, Hangbin & Wang, Xinrui & Dang, Chunzhuo & Xuan, Yimin, 2022. "Highly efficient solar-driven CO2 reforming of methane via concave foam reactors," Energy, Elsevier, vol. 261(PB).
    12. Tang Yang & Xinnan Mao & Ying Zhang & Xiaoping Wu & Lu Wang & Mingyu Chu & Chih-Wen Pao & Shize Yang & Yong Xu & Xiaoqing Huang, 2021. "Coordination tailoring of Cu single sites on C3N4 realizes selective CO2 hydrogenation at low temperature," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    13. Yao-Jie Lei & Xinxin Lu & Hirofumi Yoshikawa & Daiju Matsumura & Yameng Fan & Lingfei Zhao & Jiayang Li & Shijian Wang & Qinfen Gu & Hua-Kun Liu & Shi-Xue Dou & Shanmukaraj Devaraj & Teofilo Rojo & We, 2024. "Understanding the charge transfer effects of single atoms for boosting the performance of Na-S batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    14. Aby Cheruvathoor Poulose & Miroslav Medveď & Vasudeva Rao Bakuru & Akashdeep Sharma & Deepika Singh & Suresh Babu Kalidindi & Hugo Bares & Michal Otyepka & Kolleboyina Jayaramulu & Aristides Bakandrit, 2023. "Acidic graphene organocatalyst for the superior transformation of wastes into high-added-value chemicals," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    15. Guo, Yang & Li, Tengfei & Li, Dan & Cheng, Jiahui, 2024. "Efficient reduction of CO2 to high value-added compounds via photo-thermal catalysis: Mechanisms, catalysts and apparatuses," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    16. Jiaqi Yu & Tien Le & Dapeng Jing & Eli Stavitski & Nicholas Hunter & Kanika Lalit & Denis Leshchev & Daniel E. Resasco & Edward H. Sargent & Bin Wang & Wenyu Huang, 2023. "Balancing elementary steps enables coke-free dry reforming of methane," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-44954-4. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.