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CO electrolysis to multicarbon products over grain boundary-rich Cu nanoparticles in membrane electrode assembly electrolyzers

Author

Listed:
  • Hefei Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Pengfei Wei

    (Chinese Academy of Sciences)

  • Tianfu Liu

    (Chinese Academy of Sciences)

  • Mingrun Li

    (Chinese Academy of Sciences)

  • Chao Wang

    (Chinese Academy of Sciences)

  • Rongtan Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Jinyu Ye

    (Xiamen University)

  • Zhi-You Zhou

    (Xiamen University)

  • Shi-Gang Sun

    (Xiamen University)

  • Qiang Fu

    (Chinese Academy of Sciences)

  • Dunfeng Gao

    (Chinese Academy of Sciences)

  • Guoxiong Wang

    (Chinese Academy of Sciences)

  • Xinhe Bao

    (Chinese Academy of Sciences)

Abstract

Producing valuable chemicals like ethylene via catalytic carbon monoxide conversion is an important nonpetroleum route. Here we demonstrate an electrochemical route for highly efficient synthesis of multicarbon (C2+) chemicals from CO. We achieve a C2+ partial current density as high as 4.35 ± 0.07 A cm−2 at a low cell voltage of 2.78 ± 0.01 V over a grain boundary-rich Cu nanoparticle catalyst in an alkaline membrane electrode assembly (MEA) electrolyzer, with a C2+ Faradaic efficiency of 87 ± 1% and a CO conversion of 85 ± 3%. Operando Raman spectroscopy and density functional theory calculations reveal that the grain boundaries of Cu nanoparticles facilitate CO adsorption and C − C coupling, thus rationalizing a qualitative trend between C2+ production and grain boundary density. A scale-up demonstration using an electrolyzer stack with five 100 cm2 MEAs achieves high C2+ and ethylene formation rates of 118.9 mmol min−1 and 1.2 L min−1, respectively, at a total current of 400 A (4 A cm−2) with a C2+ Faradaic efficiency of 64%.

Suggested Citation

  • Hefei Li & Pengfei Wei & Tianfu Liu & Mingrun Li & Chao Wang & Rongtan Li & Jinyu Ye & Zhi-You Zhou & Shi-Gang Sun & Qiang Fu & Dunfeng Gao & Guoxiong Wang & Xinhe Bao, 2024. "CO electrolysis to multicarbon products over grain boundary-rich Cu nanoparticles in membrane electrode assembly electrolyzers," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49095-2
    DOI: 10.1038/s41467-024-49095-2
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    References listed on IDEAS

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