IDEAS home Printed from https://ideas.repec.org/a/nat/nature/v617y2023i7962d10.1038_s41586-023-05918-8.html
   My bibliography  Save this article

Constrained C2 adsorbate orientation enables CO-to-acetate electroreduction

Author

Listed:
  • Jian Jin

    (Huazhong University of Science and Technology
    Huazhong University of Science and Technology)

  • Joshua Wicks

    (University of Toronto)

  • Qiuhong Min

    (Huazhong University of Science and Technology)

  • Jun Li

    (Shanghai Jiao Tong University)

  • Yongfeng Hu

    (University of Saskatchewan)

  • Jingyuan Ma

    (Chinese Academy of Sciences
    Chinese Academy of Sciences)

  • Yu Wang

    (Chinese Academy of Sciences
    Chinese Academy of Sciences)

  • Zheng Jiang

    (Chinese Academy of Sciences
    Chinese Academy of Sciences)

  • Yi Xu

    (University of Toronto)

  • Ruihu Lu

    (Huazhong University of Science and Technology
    The University of Auckland)

  • Gangzheng Si

    (Huazhong University of Science and Technology)

  • Panagiotis Papangelakis

    (University of Toronto)

  • Mohsen Shakouri

    (University of Saskatchewan)

  • Qunfeng Xiao

    (University of Saskatchewan)

  • Pengfei Ou

    (University of Toronto)

  • Xue Wang

    (University of Toronto)

  • Zhu Chen

    (University of Toronto)

  • Wei Zhang

    (Wuhan University of Technology)

  • Kesong Yu

    (Wuhan University of Technology)

  • Jiayang Song

    (Huazhong University of Science and Technology)

  • Xiaohang Jiang

    (Huazhong University of Science and Technology)

  • Peng Qiu

    (Huazhong University of Science and Technology)

  • Yuanhao Lou

    (Huazhong University of Science and Technology)

  • Dan Wu

    (Huazhong University of Science and Technology)

  • Yu Mao

    (The University of Auckland)

  • Adnan Ozden

    (University of Toronto)

  • Chundong Wang

    (Huazhong University of Science and Technology)

  • Bao Yu Xia

    (Huazhong University of Science and Technology)

  • Xiaobing Hu

    (Northwestern University
    Northwestern University)

  • Vinayak P. Dravid

    (Northwestern University
    Northwestern University)

  • Yun-Mui Yiu

    (Western University)

  • Tsun-Kong Sham

    (Western University)

  • Ziyun Wang

    (The University of Auckland)

  • David Sinton

    (University of Toronto)

  • Liqiang Mai

    (Wuhan University of Technology)

  • Edward H. Sargent

    (University of Toronto
    Northwestern University
    Northwestern University)

  • Yuanjie Pang

    (Huazhong University of Science and Technology)

Abstract

The carbon dioxide and carbon monoxide electroreduction reactions, when powered using low-carbon electricity, offer pathways to the decarbonization of chemical manufacture1,2. Copper (Cu) is relied on today for carbon–carbon coupling, in which it produces mixtures of more than ten C2+ chemicals3–6: a long-standing challenge lies in achieving selectivity to a single principal C2+ product7–9. Acetate is one such C2 compound on the path to the large but fossil-derived acetic acid market. Here we pursued dispersing a low concentration of Cu atoms in a host metal to favour the stabilization of ketenes10—chemical intermediates that are bound in monodentate fashion to the electrocatalyst. We synthesize Cu-in-Ag dilute (about 1 atomic per cent of Cu) alloy materials that we find to be highly selective for acetate electrosynthesis from CO at high *CO coverage, implemented at 10 atm pressure. Operando X-ray absorption spectroscopy indicates in situ-generated Cu clusters consisting of

Suggested Citation

  • Jian Jin & Joshua Wicks & Qiuhong Min & Jun Li & Yongfeng Hu & Jingyuan Ma & Yu Wang & Zheng Jiang & Yi Xu & Ruihu Lu & Gangzheng Si & Panagiotis Papangelakis & Mohsen Shakouri & Qunfeng Xiao & Pengfe, 2023. "Constrained C2 adsorbate orientation enables CO-to-acetate electroreduction," Nature, Nature, vol. 617(7962), pages 724-729, May.
    • Handle: RePEc:nat:nature:v:617:y:2023:i:7962:d:10.1038_s41586-023-05918-8
    DOI: 10.1038/s41586-023-05918-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41586-023-05918-8
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.
    File URL: https://libkey.io/10.1038/s41586-023-05918-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Nannan Meng & Zhitan Wu & Yanmei Huang & Jie Zhang & Maoxin Chen & Haibin Ma & Hongjiao Li & Shibo Xi & Ming Lin & Wenya Wu & Shuhe Han & Yifu Yu & Quan-Hong Yang & Bin Zhang & Kian Ping Loh, 2024. "High yield electrosynthesis of oxygenates from CO using a relay Cu-Ag co-catalyst system," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Xinyue Wang & Yuanjun Chen & Feng Li & Rui Kai Miao & Jianan Erick Huang & Zilin Zhao & Xiao-Yan Li & Roham Dorakhan & Senlin Chu & Jinhong Wu & Sixing Zheng & Weiyan Ni & Dongha Kim & Sungjin Park & , 2024. "Site-selective protonation enables efficient carbon monoxide electroreduction to acetate," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    3. Hefei Li & Pengfei Wei & Tianfu Liu & Mingrun Li & Chao Wang & Rongtan Li & Jinyu Ye & Zhi-You Zhou & Shi-Gang Sun & Qiang Fu & Dunfeng Gao & Guoxiong Wang & Xinhe Bao, 2024. "CO electrolysis to multicarbon products over grain boundary-rich Cu nanoparticles in membrane electrode assembly electrolyzers," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Yangyang Zhang & Yanxu Chen & Xiaowen Wang & Yafei Feng & Zechuan Dai & Mingyu Cheng & Genqiang Zhang, 2024. "Low-coordinated copper facilitates the *CH2CO affinity at enhanced rectifying interface of Cu/Cu2O for efficient CO2-to-multicarbon alcohols conversion," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    5. Laihao Luo & Xinyan Liu & Xinyu Zhao & Xinyan Zhang & Hong-Jie Peng & Ke Ye & Kun Jiang & Qiu Jiang & Jie Zeng & Tingting Zheng & Chuan Xia, 2024. "Pressure-induced generation of heterogeneous electrocatalytic metal hydride surfaces for sustainable hydrogen transfer," Nature Communications, Nature, vol. 15(1), pages 1-15, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:nature:v:617:y:2023:i:7962:d:10.1038_s41586-023-05918-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.