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Electrochemical-repaired porous graphene membranes for precise ion-ion separation

Author

Listed:
  • Zongyao Zhou

    (École Polytechnique Fédérale de Lausanne (EPFL)
    Harbin Institute of Technology)

  • Kangning Zhao

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Heng-Yu Chi

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Yueqing Shen

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Shuqing Song

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Kuang-Jung Hsu

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Mojtaba Chevalier

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Wenxiong Shi

    (Tianjin University of Technology)

  • Kumar Varoon Agrawal

    (École Polytechnique Fédérale de Lausanne (EPFL))

Abstract

The preparation of atom-thick porous lattice hosting Å-scale pores is attractive to achieve a large ion-ion selectivity in combination with a large ion flux. Graphene film is an ideal selective layer for this if high-precision pores can be incorporated, however, it is challenging to avoid larger non-selective pores at the tail-end of the pore size distribution which reduces ion-ion selectivity. Herein, we develop a strategy to overcome this challenge using an electrochemical repair strategy that successfully masks larger pores in large-area graphene. 10-nm-thick electropolymerized conjugated microporous polymer (CMP) layer is successfully deposited on graphene, thanks to a strong π-π interaction in these two materials. While the CMP layer itself is not selective, it effectively masks graphene pores, leading to a large Li+/Mg2+ selectivity from zero-dimensional pores reaching 300 with a high Li+ ion permeation rate surpassing the performance of reported materials for ion-ion separation. Overall, this scalable repair strategy enables the fabrication of monolayer graphene membranes with customizable pore sizes, limiting the contribution of nonselective pores, and offering graphene membranes a versatile platform for a broad spectrum of challenging separations.

Suggested Citation

  • Zongyao Zhou & Kangning Zhao & Heng-Yu Chi & Yueqing Shen & Shuqing Song & Kuang-Jung Hsu & Mojtaba Chevalier & Wenxiong Shi & Kumar Varoon Agrawal, 2024. "Electrochemical-repaired porous graphene membranes for precise ion-ion separation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48419-6
    DOI: 10.1038/s41467-024-48419-6
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    References listed on IDEAS

    as
    1. Zongyao Zhou & Xiang Li & Dong Guo & Digambar B. Shinde & Dongwei Lu & Long Chen & Xiaowei Liu & Li Cao & Ammar M. Aboalsaud & Yunxia Hu & Zhiping Lai, 2020. "Electropolymerization of robust conjugated microporous polymer membranes for rapid solvent transport and narrow molecular sieving," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    2. Shiqi Huang & Mostapha Dakhchoune & Wen Luo & Emad Oveisi & Guangwei He & Mojtaba Rezaei & Jing Zhao & Duncan T. L. Alexander & Andreas Züttel & Michael S. Strano & Kumar Varoon Agrawal, 2018. "Single-layer graphene membranes by crack-free transfer for gas mixture separation," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    3. Jannik C. Meyer & A. K. Geim & M. I. Katsnelson & K. S. Novoselov & T. J. Booth & S. Roth, 2007. "The structure of suspended graphene sheets," Nature, Nature, vol. 446(7131), pages 60-63, March.
    4. Liang Chen & Guosheng Shi & Jie Shen & Bingquan Peng & Bowu Zhang & Yuzhu Wang & Fenggang Bian & Jiajun Wang & Deyuan Li & Zhe Qian & Gang Xu & Gongping Liu & Jianrong Zeng & Lijuan Zhang & Yizhou Yan, 2017. "Ion sieving in graphene oxide membranes via cationic control of interlayer spacing," Nature, Nature, vol. 550(7676), pages 380-383, October.
    5. Ruoxin Wang & Jianhao Qian & Xiaofang Chen & Ze-Xian Low & Yu Chen & Hongyu Ma & Heng-An Wu & Cara M. Doherty & Durga Acharya & Zongli Xie & Matthew R. Hill & Wei Shen & Fengchao Wang & Huanting Wang, 2023. "Pyro-layered heterostructured nanosheet membrane for hydrogen separation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Jin Wang & Zhijie Zhang & Jiani Zhu & Mengtao Tian & Shuchang Zheng & Fudi Wang & Xudong Wang & Lei Wang, 2020. "Ion sieving by a two-dimensional Ti3C2Tx alginate lamellar membrane with stable interlayer spacing," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    7. Meidi Wang & Penghui Zhang & Xu Liang & Junyi Zhao & Yawei Liu & Yu Cao & Hongjian Wang & Yu Chen & Zhiming Zhang & Fusheng Pan & Zhenjie Zhang & Zhongyi Jiang, 2022. "Ultrafast seawater desalination with covalent organic framework membranes," Nature Sustainability, Nature, vol. 5(6), pages 518-526, June.
    8. Pengfei Wang & Mao Wang & Feng Liu & Siyuan Ding & Xue Wang & Guanghua Du & Jie Liu & Pavel Apel & Patrick Kluth & Christina Trautmann & Yugang Wang, 2018. "Ultrafast ion sieving using nanoporous polymeric membranes," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
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