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Polymer hetero-electrolyte enabled solid-state 2.4-V Zn/Li hybrid batteries

Author

Listed:
  • Ze Chen

    (City University of Hong Kong)

  • Tairan Wang

    (City University of Hong Kong)

  • Zhuoxi Wu

    (City University of Hong Kong)

  • Yue Hou

    (City University of Hong Kong)

  • Ao Chen

    (City University of Hong Kong)

  • Yanbo Wang

    (City University of Hong Kong)

  • Zhaodong Huang

    (City University of Hong Kong)

  • Oliver G. Schmidt

    (TU Chemnitz
    Material Systems for Nanoelectronics)

  • Minshen Zhu

    (TU Chemnitz
    Material Systems for Nanoelectronics)

  • Jun Fan

    (City University of Hong Kong)

  • Chunyi Zhi

    (City University of Hong Kong
    Hong Kong Center for Cerebro-Cardiovascular Health Engineering (COCHE)
    City University of Hong Kong)

Abstract

The high redox potential of Zn0/2+ leads to low voltage of Zn batteries and therefore low energy density, plaguing deployment of Zn batteries in many energy-demanding applications. Though employing high-voltage cathode like spinel LiNi0.5Mn1.5O4 can increase the voltages of Zn batteries, Zn2+ ions will be immobilized in LiNi0.5Mn1.5O4 once intercalated, resulting in irreversibility. Here, we design a polymer hetero-electrolyte consisting of an anode layer with Zn2+ ions as charge carriers and a cathode layer that blocks the Zn2+ ion shuttle, which allows separated Zn and Li reversibility. As such, the Zn‖LNMO cell exhibits up to 2.4 V discharge voltage and 450 stable cycles with high reversible capacity, which are also attained in a scale-up pouch cell. The pouch cell shows a low self-discharge after resting for 28 days. The designed electrolyte paves the way to develop high-voltage Zn batteries based on reversible lithiated cathodes.

Suggested Citation

  • Ze Chen & Tairan Wang & Zhuoxi Wu & Yue Hou & Ao Chen & Yanbo Wang & Zhaodong Huang & Oliver G. Schmidt & Minshen Zhu & Jun Fan & Chunyi Zhi, 2024. "Polymer hetero-electrolyte enabled solid-state 2.4-V Zn/Li hybrid batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-47950-w
    DOI: 10.1038/s41467-024-47950-w
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    References listed on IDEAS

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    1. Lin Ma & Marshall A. Schroeder & Oleg Borodin & Travis P. Pollard & Michael S. Ding & Chunsheng Wang & Kang Xu, 2020. "Realizing high zinc reversibility in rechargeable batteries," Nature Energy, Nature, vol. 5(10), pages 743-749, October.
    2. Yanliang Liang & Hui Dong & Doron Aurbach & Yan Yao, 2020. "Publisher Correction: Current status and future directions of multivalent metal-ion batteries," Nature Energy, Nature, vol. 5(10), pages 822-822, October.
    3. Yanliang Liang & Hui Dong & Doron Aurbach & Yan Yao, 2020. "Current status and future directions of multivalent metal-ion batteries," Nature Energy, Nature, vol. 5(9), pages 646-656, September.
    4. Huayu Qiu & Xiaofan Du & Jingwen Zhao & Yantao Wang & Jiangwei Ju & Zheng Chen & Zhenglin Hu & Dongpeng Yan & Xinhong Zhou & Guanglei Cui, 2019. "Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
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