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Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation

Author

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  • Huayu Qiu

    (Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences
    Qingdao University of Science and Technology)

  • Xiaofan Du

    (Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences)

  • Jingwen Zhao

    (Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences)

  • Yantao Wang

    (Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences)

  • Jiangwei Ju

    (Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences)

  • Zheng Chen

    (Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences)

  • Zhenglin Hu

    (Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences)

  • Dongpeng Yan

    (Beijing Normal University, Beijing Key Laboratory of Energy Conversion and Storage Materials)

  • Xinhong Zhou

    (Qingdao University of Science and Technology)

  • Guanglei Cui

    (Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences)

Abstract

The surface chemistry of solid electrolyte interphase is one of the critical factors that govern the cycling life of rechargeable batteries. However, this chemistry is less explored for zinc anodes, owing to their relatively high redox potential and limited choices in electrolyte. Here, we report the observation of a zinc fluoride-rich organic/inorganic hybrid solid electrolyte interphase on zinc anode, based on an acetamide-Zn(TFSI)2 eutectic electrolyte. A combination of experimental and modeling investigations reveals that the presence of anion-complexing zinc species with markedly lowered decomposition energies contributes to the in situ formation of an interphase. The as-protected anode enables reversible (~100% Coulombic efficiency) and dendrite-free zinc plating/stripping even at high areal capacities (>2.5 mAh cm‒2), endowed by the fast ion migration coupled with high mechanical strength of the protective interphase. With this interphasial design the assembled zinc batteries exhibit excellent cycling stability with negligible capacity loss at both low and high rates.

Suggested Citation

  • Huayu Qiu & Xiaofan Du & Jingwen Zhao & Yantao Wang & Jiangwei Ju & Zheng Chen & Zhenglin Hu & Dongpeng Yan & Xinhong Zhou & Guanglei Cui, 2019. "Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-019-13436-3
    DOI: 10.1038/s41467-019-13436-3
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    Cited by:

    1. Wenyao Zhang & Muyao Dong & Keren Jiang & Diling Yang & Xuehai Tan & Shengli Zhai & Renfei Feng & Ning Chen & Graham King & Hao Zhang & Hongbo Zeng & Hui Li & Markus Antonietti & Zhi Li, 2022. "Self-repairing interphase reconstructed in each cycle for highly reversible aqueous zinc batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    2. Songshan Bi & Shuai Wang & Fang Yue & Zhiwei Tie & Zhiqiang Niu, 2021. "A rechargeable aqueous manganese-ion battery based on intercalation chemistry," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    3. Feifei Wang & Jipeng Zhang & Haotian Lu & Hanbing Zhu & Zihui Chen & Lu Wang & Jinyang Yu & Conghui You & Wenhao Li & Jianwei Song & Zhe Weng & Chunpeng Yang & Quan-Hong Yang, 2023. "Production of gas-releasing electrolyte-replenishing Ah-scale zinc metal pouch cells with aqueous gel electrolyte," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    4. Jinrong Luo & Liang Xu & Yinan Yang & Song Huang & Yijing Zhou & Yanyan Shao & Tianheng Wang & Jiaming Tian & Shaohua Guo & Jianqing Zhao & Xiaoxu Zhao & Tao Cheng & Yuanlong Shao & Jin Zhang, 2024. "Stable zinc anode solid electrolyte interphase via inner Helmholtz plane engineering," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    5. Yu Wang & Tairan Wang & Shuyu Bu & Jiaxiong Zhu & Yanbo Wang & Rong Zhang & Hu Hong & Wenjun Zhang & Jun Fan & Chunyi Zhi, 2023. "Sulfolane-containing aqueous electrolyte solutions for producing efficient ampere-hour-level zinc metal battery pouch cells," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    6. Ze Chen & Tairan Wang & Zhuoxi Wu & Yue Hou & Ao Chen & Yanbo Wang & Zhaodong Huang & Oliver G. Schmidt & Minshen Zhu & Jun Fan & Chunyi Zhi, 2024. "Polymer hetero-electrolyte enabled solid-state 2.4-V Zn/Li hybrid batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    7. Al-Farsi, Raiyan & Hayyan, Maan, 2023. "Paving the way for advancement of renewable energy technologies using deep eutectic solvents: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    8. Xin Shi & Jinhao Xie & Jin Wang & Shilei Xie & Zujin Yang & Xihong Lu, 2024. "A weakly solvating electrolyte towards practical rechargeable aqueous zinc-ion batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    9. Song Chen & Deluo Ji & Qianwu Chen & Jizhen Ma & Shaoqi Hou & Jintao Zhang, 2023. "Coordination modulation of hydrated zinc ions to enhance redox reversibility of zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Qing Li & Ao Chen & Donghong Wang & Yuwei Zhao & Xiaoqi Wang & Xu Jin & Bo Xiong & Chunyi Zhi, 2022. "Tailoring the metal electrode morphology via electrochemical protocol optimization for long-lasting aqueous zinc batteries," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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