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Current status and future directions of multivalent metal-ion batteries

Author

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  • Yanliang Liang

    (University of Houston
    Texas Center for Superconductivity at the University of Houston (TcSUH))

  • Hui Dong

    (University of Houston
    Texas Center for Superconductivity at the University of Houston (TcSUH))

  • Doron Aurbach

    (Bar-Ilan University)

  • Yan Yao

    (University of Houston
    Texas Center for Superconductivity at the University of Houston (TcSUH))

Abstract

Batteries based on multivalent metals have the potential to meet the future needs of large-scale energy storage, due to the relatively high abundance of elements such as magnesium, calcium, aluminium and zinc in the Earth’s crust. However, the complexity of multivalent metal-ion chemistries has led to rampant confusions, technical challenges, and eventually doubts and uncertainties about the future of these technologies. In this Review, we clarify the key strengths as well as common misconceptions of multivalent metal-based batteries. We then examine the growth behaviour of metal anodes, which is crucial for their safety promises but hitherto unestablished. We further discuss scrutiny of anode efficiency and cathode storage mechanism pertaining to complications arising from electrolyte solutions. Finally, we critically review existing cathode materials and discuss design strategies to enable genuine multivalent metal-ion-based energy storage materials with competitive performance.

Suggested Citation

  • Yanliang Liang & Hui Dong & Doron Aurbach & Yan Yao, 2020. "Current status and future directions of multivalent metal-ion batteries," Nature Energy, Nature, vol. 5(9), pages 646-656, September.
    • Handle: RePEc:nat:natene:v:5:y:2020:i:9:d:10.1038_s41560-020-0655-0
    DOI: 10.1038/s41560-020-0655-0
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    1. Shitao Geng & Xiaoju Zhao & Qiuchen Xu & Bin Yuan & Yan Wang & Meng Liao & Lei Ye & Shuo Wang & Zhaofeng Ouyang & Liang Wu & Yongyang Wang & Chenyan Ma & Xiaojuan Zhao & Hao Sun, 2024. "A rechargeable Ca/Cl2 battery," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    2. Elena G. Tolstopyatova & Mikhail A. Kamenskii & Veniamin V. Kondratiev, 2022. "Vanadium Oxide–Conducting Polymers Composite Cathodes for Aqueous Zinc-Ion Batteries: Interfacial Design and Enhancement of Electrochemical Performance," Energies, MDPI, vol. 15(23), pages 1-26, November.
    3. Jiashen Meng & Xufeng Hong & Zhitong Xiao & Linhan Xu & Lujun Zhu & Yongfeng Jia & Fang Liu & Liqiang Mai & Quanquan Pang, 2024. "Rapid-charging aluminium-sulfur batteries operated at 85 °C with a quaternary molten salt electrolyte," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Feifei Wang & Jipeng Zhang & Haotian Lu & Hanbing Zhu & Zihui Chen & Lu Wang & Jinyang Yu & Conghui You & Wenhao Li & Jianwei Song & Zhe Weng & Chunpeng Yang & Quan-Hong Yang, 2023. "Production of gas-releasing electrolyte-replenishing Ah-scale zinc metal pouch cells with aqueous gel electrolyte," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Qiannan Zhao & Kaiqi Zhao & Gao-Feng Han & Ming Huang & Ronghua Wang & Zhiqiao Wang & Wang Zhou & Yue Ma & Jilei Liu & Zhongting Wang & Chaohe Xu & Guangsheng Huang & Jingfeng Wang & Fusheng Pan & Jon, 2024. "High-capacity, fast-charging and long-life magnesium/black phosphorous composite negative electrode for non-aqueous magnesium battery," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    6. Enze Hu & Huifang Li & Yizhou Zhang & Xiaojun Wang & Zhiming Liu, 2023. "Recent Progresses on Vanadium Sulfide Cathodes for Aqueous Zinc-Ion Batteries," Energies, MDPI, vol. 16(2), pages 1-18, January.
    7. Zhirong Zhao-Karger & Yanlei Xiu & Zhenyou Li & Adam Reupert & Thomas Smok & Maximilian Fichtner, 2022. "Calcium-tin alloys as anodes for rechargeable non-aqueous calcium-ion batteries at room temperature," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    8. Jiashen Meng & Xuhui Yao & Xufeng Hong & Lujun Zhu & Zhitong Xiao & Yongfeng Jia & Fang Liu & Huimin Song & Yunlong Zhao & Quanquan Pang, 2023. "A solution-to-solid conversion chemistry enables ultrafast-charging and long-lived molten salt aluminium batteries," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    9. Ana Sanz Matias & Fabrice Roncoroni & Siddharth Sundararaman & David Prendergast, 2024. "Ca-dimers, solvent layering, and dominant electrochemically active species in Ca(BH4)2 in THF," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    10. Qingyuan Li & Jen-Hung Fang & Wenyuan Li & Xingbo Liu, 2022. "Novel Materials and Advanced Characterization for Energy Storage and Conversion," Energies, MDPI, vol. 15(20), pages 1-3, October.
    11. Ze Chen & Tairan Wang & Zhuoxi Wu & Yue Hou & Ao Chen & Yanbo Wang & Zhaodong Huang & Oliver G. Schmidt & Minshen Zhu & Jun Fan & Chunyi Zhi, 2024. "Polymer hetero-electrolyte enabled solid-state 2.4-V Zn/Li hybrid batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    12. Chao Ye & Huan Li & Yujie Chen & Junnan Hao & Jiahao Liu & Jieqiong Shan & Shi-Zhang Qiao, 2024. "The role of electrocatalytic materials for developing post-lithium metal||sulfur batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    13. Dong, Ao & Ma, Ruifei & Deng, Yelin, 2023. "Optimization on charging of the direct hybrid lithium-ion battery and supercapacitor for high power application through resistance balancing," Energy, Elsevier, vol. 273(C).
    14. Jelena Popovic, 2021. "The importance of electrode interfaces and interphases for rechargeable metal batteries," Nature Communications, Nature, vol. 12(1), pages 1-5, December.
    15. Ananyo Roy & Mohsen Sotoudeh & Sirshendu Dinda & Yushu Tang & Christian Kübel & Axel Groß & Zhirong Zhao-Karger & Maximilian Fichtner & Zhenyou Li, 2024. "Improving rechargeable magnesium batteries through dual cation co-intercalation strategy," Nature Communications, Nature, vol. 15(1), pages 1-16, December.
    16. F. Degen & M. Winter & D. Bendig & J. Tübke, 2023. "Energy consumption of current and future production of lithium-ion and post lithium-ion battery cells," Nature Energy, Nature, vol. 8(11), pages 1284-1295, November.

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