IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-49164-6.html
   My bibliography  Save this article

The role of electrocatalytic materials for developing post-lithium metal||sulfur batteries

Author

Listed:
  • Chao Ye

    (The University of Adelaide)

  • Huan Li

    (The University of Adelaide)

  • Yujie Chen

    (The University of Adelaide)

  • Junnan Hao

    (The University of Adelaide)

  • Jiahao Liu

    (The University of Adelaide)

  • Jieqiong Shan

    (City University of Hong Kong)

  • Shi-Zhang Qiao

    (The University of Adelaide)

Abstract

The exploration of post-Lithium (Li) metals, such as Sodium (Na), Potassium (K), Magnesium (Mg), Calcium (Ca), Aluminum (Al), and Zinc (Zn), for electrochemical energy storage has been driven by the limited availability of Li and the higher theoretical specific energies compared to the state-of-the-art Li-ion batteries. Post-Li metal||S batteries have emerged as a promising system for practical applications. Yet, the insufficient understanding of quantitative cell parameters and the mechanisms of sulfur electrocatalytic conversion hinder the advancement of these battery technologies. This perspective offers a comprehensive analysis of electrode parameters, including S mass loading, S content, electrolyte/S ratio, and negative/positive electrode capacity ratio, in establishing the specific energy (Wh kg−1) of post-Li metal||S batteries. Additionally, we critically evaluate the progress in investigating electrochemical sulfur conversion via homogeneous and heterogeneous electrocatalytic approaches in both non-aqueous Na/K/Mg/Ca/Al||S and aqueous Zn||S batteries. Lastly, we provide a critical outlook on potential research directions for designing practical post-Li metal||S batteries.

Suggested Citation

  • Chao Ye & Huan Li & Yujie Chen & Junnan Hao & Jiahao Liu & Jieqiong Shan & Shi-Zhang Qiao, 2024. "The role of electrocatalytic materials for developing post-lithium metal||sulfur batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49164-6
    DOI: 10.1038/s41467-024-49164-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-49164-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-49164-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Shuya Wei & Shaomao Xu & Akanksha Agrawral & Snehashis Choudhury & Yingying Lu & Zhengyuan Tu & Lin Ma & Lynden A. Archer, 2016. "A stable room-temperature sodium–sulfur battery," Nature Communications, Nature, vol. 7(1), pages 1-10, September.
    2. Mengyao Tang & Shuai Dong & Jiawei Wang & Liwei Cheng & Qiaonan Zhu & Yanmei Li & Xiuyi Yang & Lin Guo & Hua Wang, 2023. "Low-temperature anode-free potassium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Zhirong Zhao-Karger & Yanlei Xiu & Zhenyou Li & Adam Reupert & Thomas Smok & Maximilian Fichtner, 2022. "Calcium-tin alloys as anodes for rechargeable non-aqueous calcium-ion batteries at room temperature," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Quanquan Pang & Jiashen Meng & Saransh Gupta & Xufeng Hong & Chun Yuen Kwok & Ji Zhao & Yingxia Jin & Like Xu & Ozlem Karahan & Ziqi Wang & Spencer Toll & Liqiang Mai & Linda F. Nazar & Mahalingam Bal, 2022. "Fast-charging aluminium–chalcogen batteries resistant to dendritic shorting," Nature, Nature, vol. 608(7924), pages 704-711, August.
    5. Guangmin Zhou & Hao Chen & Yi Cui, 2022. "Formulating energy density for designing practical lithium–sulfur batteries," Nature Energy, Nature, vol. 7(4), pages 312-319, April.
    6. Xiaofu Xu & Dong Zhou & Xianying Qin & Kui Lin & Feiyu Kang & Baohua Li & Devaraj Shanmukaraj & Teofilo Rojo & Michel Armand & Guoxiu Wang, 2018. "A room-temperature sodium–sulfur battery with high capacity and stable cycling performance," Nature Communications, Nature, vol. 9(1), pages 1-12, December.
    7. Quan Pang & Abhinandan Shyamsunder & Badri Narayanan & Chun Yuen Kwok & Larry A. Curtiss & Linda F. Nazar, 2018. "Tuning the electrolyte network structure to invoke quasi-solid state sulfur conversion and suppress lithium dendrite formation in Li–S batteries," Nature Energy, Nature, vol. 3(9), pages 783-791, September.
    8. Yanliang Liang & Hui Dong & Doron Aurbach & Yan Yao, 2020. "Publisher Correction: Current status and future directions of multivalent metal-ion batteries," Nature Energy, Nature, vol. 5(10), pages 822-822, October.
    9. Jiashen Meng & Xufeng Hong & Zhitong Xiao & Linhan Xu & Lujun Zhu & Yongfeng Jia & Fang Liu & Liqiang Mai & Quanquan Pang, 2024. "Rapid-charging aluminium-sulfur batteries operated at 85 °C with a quaternary molten salt electrolyte," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    10. Yanliang Liang & Hui Dong & Doron Aurbach & Yan Yao, 2020. "Current status and future directions of multivalent metal-ion batteries," Nature Energy, Nature, vol. 5(9), pages 646-656, September.
    11. Siyuan Li & Jiahui Zhang & Shichao Zhang & Qilei Liu & Hao Cheng & Lei Fan & Weidong Zhang & Xinyang Wang & Qian Wu & Yingying Lu, 2024. "Cation replacement method enables high-performance electrolytes for multivalent metal batteries," Nature Energy, Nature, vol. 9(3), pages 285-297, March.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jiashen Meng & Xufeng Hong & Zhitong Xiao & Linhan Xu & Lujun Zhu & Yongfeng Jia & Fang Liu & Liqiang Mai & Quanquan Pang, 2024. "Rapid-charging aluminium-sulfur batteries operated at 85 °C with a quaternary molten salt electrolyte," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Jiashen Meng & Xuhui Yao & Xufeng Hong & Lujun Zhu & Zhitong Xiao & Yongfeng Jia & Fang Liu & Huimin Song & Yunlong Zhao & Quanquan Pang, 2023. "A solution-to-solid conversion chemistry enables ultrafast-charging and long-lived molten salt aluminium batteries," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Zhirong Zhao-Karger & Yanlei Xiu & Zhenyou Li & Adam Reupert & Thomas Smok & Maximilian Fichtner, 2022. "Calcium-tin alloys as anodes for rechargeable non-aqueous calcium-ion batteries at room temperature," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Qingyuan Li & Jen-Hung Fang & Wenyuan Li & Xingbo Liu, 2022. "Novel Materials and Advanced Characterization for Energy Storage and Conversion," Energies, MDPI, vol. 15(20), pages 1-3, October.
    5. Yao-Jie Lei & Xinxin Lu & Hirofumi Yoshikawa & Daiju Matsumura & Yameng Fan & Lingfei Zhao & Jiayang Li & Shijian Wang & Qinfen Gu & Hua-Kun Liu & Shi-Xue Dou & Shanmukaraj Devaraj & Teofilo Rojo & We, 2024. "Understanding the charge transfer effects of single atoms for boosting the performance of Na-S batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    6. Enze Hu & Huifang Li & Yizhou Zhang & Xiaojun Wang & Zhiming Liu, 2023. "Recent Progresses on Vanadium Sulfide Cathodes for Aqueous Zinc-Ion Batteries," Energies, MDPI, vol. 16(2), pages 1-18, January.
    7. Elena G. Tolstopyatova & Mikhail A. Kamenskii & Veniamin V. Kondratiev, 2022. "Vanadium Oxide–Conducting Polymers Composite Cathodes for Aqueous Zinc-Ion Batteries: Interfacial Design and Enhancement of Electrochemical Performance," Energies, MDPI, vol. 15(23), pages 1-26, November.
    8. Chao Ye & Huanyu Jin & Jieqiong Shan & Yan Jiao & Huan Li & Qinfen Gu & Kenneth Davey & Haihui Wang & Shi-Zhang Qiao, 2021. "A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    9. Ana Sanz Matias & Fabrice Roncoroni & Siddharth Sundararaman & David Prendergast, 2024. "Ca-dimers, solvent layering, and dominant electrochemically active species in Ca(BH4)2 in THF," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    10. Ze Chen & Tairan Wang & Zhuoxi Wu & Yue Hou & Ao Chen & Yanbo Wang & Zhaodong Huang & Oliver G. Schmidt & Minshen Zhu & Jun Fan & Chunyi Zhi, 2024. "Polymer hetero-electrolyte enabled solid-state 2.4-V Zn/Li hybrid batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    11. Yuruo Qi & Qing-Jie Li & Yuanke Wu & Shu-juan Bao & Changming Li & Yuming Chen & Guoxiu Wang & Maowen Xu, 2021. "A Fe3N/carbon composite electrocatalyst for effective polysulfides regulation in room-temperature Na-S batteries," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    12. Jelena Popovic, 2021. "The importance of electrode interfaces and interphases for rechargeable metal batteries," Nature Communications, Nature, vol. 12(1), pages 1-5, December.
    13. Feifei Wang & Jipeng Zhang & Haotian Lu & Hanbing Zhu & Zihui Chen & Lu Wang & Jinyang Yu & Conghui You & Wenhao Li & Jianwei Song & Zhe Weng & Chunpeng Yang & Quan-Hong Yang, 2023. "Production of gas-releasing electrolyte-replenishing Ah-scale zinc metal pouch cells with aqueous gel electrolyte," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    14. F. Degen & M. Winter & D. Bendig & J. Tübke, 2023. "Energy consumption of current and future production of lithium-ion and post lithium-ion battery cells," Nature Energy, Nature, vol. 8(11), pages 1284-1295, November.
    15. Shitao Geng & Xiaoju Zhao & Qiuchen Xu & Bin Yuan & Yan Wang & Meng Liao & Lei Ye & Shuo Wang & Zhaofeng Ouyang & Liang Wu & Yongyang Wang & Chenyan Ma & Xiaojuan Zhao & Hao Sun, 2024. "A rechargeable Ca/Cl2 battery," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    16. Liu, Ying & Lee, Dong Jun & Ahn, Hyo-Jun & Nam, Sang Yong & Cho, Kwon-Koo & Ahn, Jou-Hyeon, 2023. "Waste coffee grounds-derived carbon: Nanoarchitectured pore-structure regulation for sustainable room-temperature sodium–sulfur batteries," Renewable Energy, Elsevier, vol. 212(C), pages 865-874.
    17. Dong, Ao & Ma, Ruifei & Deng, Yelin, 2023. "Optimization on charging of the direct hybrid lithium-ion battery and supercapacitor for high power application through resistance balancing," Energy, Elsevier, vol. 273(C).
    18. Ananyo Roy & Mohsen Sotoudeh & Sirshendu Dinda & Yushu Tang & Christian Kübel & Axel Groß & Zhirong Zhao-Karger & Maximilian Fichtner & Zhenyou Li, 2024. "Improving rechargeable magnesium batteries through dual cation co-intercalation strategy," Nature Communications, Nature, vol. 15(1), pages 1-16, December.
    19. Guanjun Ji & Di Tang & Junxiong Wang & Zheng Liang & Haocheng Ji & Jun Ma & Zhaofeng Zhuang & Song Liu & Guangmin Zhou & Hui-Ming Cheng, 2024. "Sustainable upcycling of mixed spent cathodes to a high-voltage polyanionic cathode material," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    20. Shuo Wang & Jiamin Fu & Yunsheng Liu & Ramanuja Srinivasan Saravanan & Jing Luo & Sixu Deng & Tsun-Kong Sham & Xueliang Sun & Yifei Mo, 2023. "Design principles for sodium superionic conductors," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49164-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.