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Tuning ferroelectric phase transition temperature by enantiomer fraction

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  • Chang-Chun Fan

    (Southeast University)

  • Cheng-Dong Liu

    (Southeast University)

  • Bei-Dou Liang

    (Southeast University)

  • Wei Wang

    (Southeast University)

  • Ming-Liang Jin

    (Southeast University)

  • Chao-Yang Chai

    (Southeast University)

  • Chang-Qing Jing

    (Southeast University)

  • Tong-Yu Ju

    (Southeast University)

  • Xiang-Bin Han

    (Southeast University)

  • Wen Zhang

    (Southeast University)

Abstract

Tuning phase transition temperature is one of the central issues in phase transition materials. Herein, we report a case study of using enantiomer fraction engineering as a promising strategy to tune the Curie temperature (TC) and related properties of ferroelectrics. A series of metal-halide perovskite ferroelectrics (S−3AMP)x(R−3AMP)1−xPbBr4 was synthesized where 3AMP is the 3-(aminomethyl)piperidine divalent cation and enantiomer fraction x varies between 0 and 1 (0 and 1 = enantiomers; 0.5 = racemate). With the change of the enantiomer fraction, the TC, second-harmonic generation intensity, degree of circular polarization of photoluminescence, and photoluminescence intensity of the materials have been tuned. Particularly, when x = 0.70 − 1, a continuously linear tuning of the TC is achieved, showing a tunable temperature range of about 73 K. This strategy provides an effective means and insights for regulating the phase transition temperature and chiroptical properties of functional materials.

Suggested Citation

  • Chang-Chun Fan & Cheng-Dong Liu & Bei-Dou Liang & Wei Wang & Ming-Liang Jin & Chao-Yang Chai & Chang-Qing Jing & Tong-Yu Ju & Xiang-Bin Han & Wen Zhang, 2024. "Tuning ferroelectric phase transition temperature by enantiomer fraction," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45986-6
    DOI: 10.1038/s41467-024-45986-6
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