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Unraveling chirality transfer mechanism by structural isomer-derived hydrogen bonding interaction in 2D chiral perovskite

Author

Listed:
  • Jaehyun Son

    (Yonsei University)

  • Sunihl Ma

    (Yonsei University
    University of Michigan)

  • Young-Kwang Jung

    (Yonsei University)

  • Jeiwan Tan

    (Yonsei University)

  • Gyumin Jang

    (Yonsei University)

  • Hyungsoo Lee

    (Yonsei University)

  • Chan Uk Lee

    (Yonsei University)

  • Junwoo Lee

    (Yonsei University)

  • Subin Moon

    (Yonsei University)

  • Wooyong Jeong

    (Yonsei University)

  • Aron Walsh

    (Imperial College London)

  • Jooho Moon

    (Yonsei University)

Abstract

In principle, the induced chirality of hybrid perovskites results from symmetry-breaking within inorganic frameworks. However, the detailed mechanism behind the chirality transfer remains unknown due to the lack of systematic studies. Here, using the structural isomer with different functional group location, we deduce the effect of hydrogen-bonding interaction between two building blocks on the degree of chirality transfer in inorganic frameworks. The effect of asymmetric hydrogen-bonding interaction on chirality transfer was clearly demonstrated by thorough experimental analysis. Systematic studies of crystallography parameters confirm that the different asymmetric hydrogen-bonding interactions derived from different functional group location play a key role in chirality transfer phenomena and the resulting spin-related properties of chiral perovskites. The methodology to control the asymmetry of hydrogen-bonding interaction through the small structural difference of structure isomer cation can provide rational design paradigm for unprecedented spin-related properties of chiral perovskite.

Suggested Citation

  • Jaehyun Son & Sunihl Ma & Young-Kwang Jung & Jeiwan Tan & Gyumin Jang & Hyungsoo Lee & Chan Uk Lee & Junwoo Lee & Subin Moon & Wooyong Jeong & Aron Walsh & Jooho Moon, 2023. "Unraveling chirality transfer mechanism by structural isomer-derived hydrogen bonding interaction in 2D chiral perovskite," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38927-2
    DOI: 10.1038/s41467-023-38927-2
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    References listed on IDEAS

    as
    1. Jun Hu & Iain W. H. Oswald & Samuel J. Stuard & Masrur Morshed Nahid & Ninghao Zhou & Olivia F. Williams & Zhenkun Guo & Liang Yan & Huamin Hu & Zheng Chen & Xun Xiao & Yun Lin & Zhibin Yang & Jinsong, 2019. "Synthetic control over orientational degeneracy of spacer cations enhances solar cell efficiency in two-dimensional perovskites," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    2. Manoj K. Jana & Ruyi Song & Haoliang Liu & Dipak Raj Khanal & Svenja M. Janke & Rundong Zhao & Chi Liu & Z. Valy Vardeny & Volker Blum & David B. Mitzi, 2020. "Organic-to-inorganic structural chirality transfer in a 2D hybrid perovskite and impact on Rashba-Dresselhaus spin-orbit coupling," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    3. Manoj K. Jana & Ruyi Song & Yi Xie & Rundong Zhao & Peter C. Sercel & Volker Blum & David B. Mitzi, 2021. "Structural descriptor for enhanced spin-splitting in 2D hybrid perovskites," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    4. Sunihl Ma & Young-Kwang Jung & Jihoon Ahn & Jihoon Kyhm & Jeiwan Tan & Hyungsoo Lee & Gyumin Jang & Chan Uk Lee & Aron Walsh & Jooho Moon, 2022. "Elucidating the origin of chiroptical activity in chiral 2D perovskites through nano-confined growth," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
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    Cited by:

    1. Qi Liu & Qi Wei & Hui Ren & Luwei Zhou & Yifan Zhou & Pengzhi Wang & Chenghao Wang & Jun Yin & Mingjie Li, 2023. "Circular polarization-resolved ultraviolet photonic artificial synapse based on chiral perovskite," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Lei Zhang & Guoqun Zhao & Zhiping Chen & Xianhang Yan, 2024. "Chirality hierarchical transfer in homochiral polymer crystallization under high-pressure CO2," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Hyungsoo Lee & Chan Uk Lee & Juwon Yun & Chang-Seop Jeong & Wooyong Jeong & Jaehyun Son & Young Sun Park & Subin Moon & Soobin Lee & Jun Hwan Kim & Jooho Moon, 2024. "A dual spin-controlled chiral two-/three-dimensional perovskite artificial leaf for efficient overall photoelectrochemical water splitting," Nature Communications, Nature, vol. 15(1), pages 1-15, December.

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