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Low-k nano-dielectrics facilitate electric-field induced phase transition in high-k ferroelectric polymers for sustainable electrocaloric refrigeration

Author

Listed:
  • Qiang Li

    (Shanghai Jiao Tong University)

  • Luqi Wei

    (East China Normal University)

  • Ni Zhong

    (East China Normal University)

  • Xiaoming Shi

    (Beijing Institute of Technology)

  • Donglin Han

    (Shanghai Jiao Tong University)

  • Shanyu Zheng

    (Shanghai Jiao Tong University)

  • Feihong Du

    (Shanghai Jiao Tong University)

  • Junye Shi

    (Shanghai Jiao Tong University)

  • Jiangping Chen

    (Shanghai Jiao Tong University)

  • Houbing Huang

    (Beijing Institute of Technology)

  • Chungang Duan

    (East China Normal University)

  • Xiaoshi Qian

    (Shanghai Jiao Tong University
    Shanghai Jiao Tong University ZhongGuanCun Research Institute)

Abstract

Ferroelectric polymer-based electrocaloric effect may lead to sustainable heat pumps and refrigeration owing to the large electrocaloric-induced entropy changes, flexible, lightweight and zero-global warming potential. Herein, low-k nanodiamonds are served as extrinsic dielectric fillers to fabricate polymeric nanocomposites for electrocaloric refrigeration. As low-k nanofillers are naturally polar-inactive, hence they have been widely applied for consolidate electrical stability in dielectrics. Interestingly, we observe that the nanodiamonds markedly enhances the electrocaloric effect in relaxor ferroelectrics. Compared with their high-k counterparts that have been extensively studied in the field of electrocaloric nanocomposites, the nanodiamonds introduces the highest volumetric electrocaloric enhancement (~23%/vol%). The resulting polymeric nanocomposite exhibits concurrently improved electrocaloric effect (160%), thermal conductivity (175%) and electrical stability (125%), which allow a fluid-solid coupling-based electrocaloric refrigerator to exhibit an improved coefficient of performance from 0.8 to 5.3 (660%) while maintaining high cooling power (over 240 W) at a temperature span of 10 K.

Suggested Citation

  • Qiang Li & Luqi Wei & Ni Zhong & Xiaoming Shi & Donglin Han & Shanyu Zheng & Feihong Du & Junye Shi & Jiangping Chen & Houbing Huang & Chungang Duan & Xiaoshi Qian, 2024. "Low-k nano-dielectrics facilitate electric-field induced phase transition in high-k ferroelectric polymers for sustainable electrocaloric refrigeration," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-44926-8
    DOI: 10.1038/s41467-024-44926-8
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    References listed on IDEAS

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    1. B. Nair & T. Usui & S. Crossley & S. Kurdi & G. G. Guzmán-Verri & X. Moya & S. Hirose & N. D. Mathur, 2019. "Large electrocaloric effects in oxide multilayer capacitors over a wide temperature range," Nature, Nature, vol. 575(7783), pages 468-472, November.
    2. K. M. Stanley & D. Say & J. Mühle & C. M. Harth & P. B. Krummel & D. Young & S. J. O’Doherty & P. K. Salameh & P. G. Simmonds & R. F. Weiss & R. G. Prinn & P. J. Fraser & M. Rigby, 2020. "Increase in global emissions of HFC-23 despite near-total expected reductions," Nature Communications, Nature, vol. 11(1), pages 1-6, December.
    3. Yuan Meng & Ziyang Zhang & Hanxiang Wu & Ruiyi Wu & Jianghan Wu & Haolun Wang & Qibing Pei, 2020. "A cascade electrocaloric cooling device for large temperature lift," Nature Energy, Nature, vol. 5(12), pages 996-1002, December.
    4. Mark O. McLinden & J. Steven Brown & Riccardo Brignoli & Andrei F. Kazakov & Piotr A. Domanski, 2017. "Limited options for low-global-warming-potential refrigerants," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    5. Bing Li & Yukinobu Kawakita & Seiko Ohira-Kawamura & Takeshi Sugahara & Hui Wang & Jingfan Wang & Yanna Chen & Saori I. Kawaguchi & Shogo Kawaguchi & Koji Ohara & Kuo Li & Dehong Yu & Richard Mole & T, 2019. "Colossal barocaloric effects in plastic crystals," Nature, Nature, vol. 567(7749), pages 506-510, March.
    6. Xiaoshi Qian & Donglin Han & Lirong Zheng & Jie Chen & Madhusudan Tyagi & Qiang Li & Feihong Du & Shanyu Zheng & Xingyi Huang & Shihai Zhang & Junye Shi & Houbing Huang & Xiaoming Shi & Jiangping Chen, 2021. "High-entropy polymer produces a giant electrocaloric effect at low fields," Nature, Nature, vol. 600(7890), pages 664-669, December.
    7. Ming-Ding Li & Xiao-Quan Shen & Xin Chen & Jia-Ming Gan & Fang Wang & Jian Li & Xiao-Liang Wang & Qun-Dong Shen, 2022. "Thermal management of chips by a device prototype using synergistic effects of 3-D heat-conductive network and electrocaloric refrigeration," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
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