IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-29800-9.html
   My bibliography  Save this article

Colossal barocaloric effects with ultralow hysteresis in two-dimensional metal–halide perovskites

Author

Listed:
  • Jinyoung Seo

    (Harvard University)

  • Ryan D. McGillicuddy

    (Harvard University)

  • Adam H. Slavney

    (Harvard University)

  • Selena Zhang

    (Harvard University)

  • Rahil Ukani

    (Harvard University)

  • Andrey A. Yakovenko

    (Argonne National Laboratory)

  • Shao-Liang Zheng

    (Harvard University)

  • Jarad A. Mason

    (Harvard University)

Abstract

Pressure-induced thermal changes in solids—barocaloric effects—can be used to drive cooling cycles that offer a promising alternative to traditional vapor-compression technologies. Efficient barocaloric cooling requires materials that undergo reversible phase transitions with large entropy changes, high sensitivity to hydrostatic pressure, and minimal hysteresis, the combination of which has been challenging to achieve in existing barocaloric materials. Here, we report a new mechanism for achieving colossal barocaloric effects that leverages the large volume and conformational entropy changes of hydrocarbon order–disorder transitions within the organic bilayers of select two-dimensional metal–halide perovskites. Significantly, we show how the confined nature of these order–disorder phase transitions and the synthetic tunability of layered perovskites can be leveraged to reduce phase transition hysteresis through careful control over the inorganic–organic interface. The combination of ultralow hysteresis and high pressure sensitivity leads to colossal reversible isothermal entropy changes (>200 J kg−1 K−1) at record-low pressures (

Suggested Citation

  • Jinyoung Seo & Ryan D. McGillicuddy & Adam H. Slavney & Selena Zhang & Rahil Ukani & Andrey A. Yakovenko & Shao-Liang Zheng & Jarad A. Mason, 2022. "Colossal barocaloric effects with ultralow hysteresis in two-dimensional metal–halide perovskites," Nature Communications, Nature, vol. 13(1), pages 1-15, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29800-9
    DOI: 10.1038/s41467-022-29800-9
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-29800-9
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-022-29800-9?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. B. Nair & T. Usui & S. Crossley & S. Kurdi & G. G. Guzmán-Verri & X. Moya & S. Hirose & N. D. Mathur, 2019. "Large electrocaloric effects in oxide multilayer capacitors over a wide temperature range," Nature, Nature, vol. 575(7783), pages 468-472, November.
    2. P. Lloveras & E. Stern-Taulats & M. Barrio & J.-Ll. Tamarit & S. Crossley & W. Li & V. Pomjakushin & A. Planes & Ll. Mañosa & N. D. Mathur & X. Moya, 2015. "Giant barocaloric effects at low pressure in ferrielectric ammonium sulphate," Nature Communications, Nature, vol. 6(1), pages 1-6, December.
    3. Bing Li & Yukinobu Kawakita & Seiko Ohira-Kawamura & Takeshi Sugahara & Hui Wang & Jingfan Wang & Yanna Chen & Saori I. Kawaguchi & Shogo Kawaguchi & Koji Ohara & Kuo Li & Dehong Yu & Richard Mole & T, 2019. "Colossal barocaloric effects in plastic crystals," Nature, Nature, vol. 567(7749), pages 506-510, March.
    4. P. Lloveras & A. Aznar & M. Barrio & Ph. Negrier & C. Popescu & A. Planes & L. Mañosa & E. Stern-Taulats & A. Avramenko & N. D. Mathur & X. Moya & J.-Ll. Tamarit, 2019. "Colossal barocaloric effects near room temperature in plastic crystals of neopentylglycol," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    5. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Shin-ichi Ohkoshi & Kosuke Nakagawa & Marie Yoshikiyo & Asuka Namai & Kenta Imoto & Yugo Nagane & Fangda Jia & Olaf Stefanczyk & Hiroko Tokoro & Junhao Wang & Takeshi Sugahara & Kouji Chiba & Kazuhiko, 2023. "Giant adiabatic temperature change and its direct measurement of a barocaloric effect in a charge-transfer solid," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Dai, Zhaofeng & She, Xiaohui & Wang, Chen & Ding, Yulong & Li, Yongliang & Zhang, Xiaosong & Zhao, Dongliang, 2024. "Dynamic simulation and performance analysis of a solid-state barocaloric refrigeration system," Energy, Elsevier, vol. 294(C).
    2. Shin-ichi Ohkoshi & Kosuke Nakagawa & Marie Yoshikiyo & Asuka Namai & Kenta Imoto & Yugo Nagane & Fangda Jia & Olaf Stefanczyk & Hiroko Tokoro & Junhao Wang & Takeshi Sugahara & Kouji Chiba & Kazuhiko, 2023. "Giant adiabatic temperature change and its direct measurement of a barocaloric effect in a charge-transfer solid," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Klara Lünser & Eyüp Kavak & Kübra Gürpinar & Baris Emre & Orhan Atakol & Enric Stern-Taulats & Marcel Porta & Antoni Planes & Pol Lloveras & Josep-Lluís Tamarit & Lluís Mañosa, 2024. "Elastocaloric, barocaloric and magnetocaloric effects in spin crossover polymer composite films," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Qiang Li & Luqi Wei & Ni Zhong & Xiaoming Shi & Donglin Han & Shanyu Zheng & Feihong Du & Junye Shi & Jiangping Chen & Houbing Huang & Chungang Duan & Xiaoshi Qian, 2024. "Low-k nano-dielectrics facilitate electric-field induced phase transition in high-k ferroelectric polymers for sustainable electrocaloric refrigeration," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    5. Yi-Hong Gao & Dong-Hui Wang & Feng-Xia Hu & Qing-Zhen Huang & You-Ting Song & Shuai-Kang Yuan & Zheng-Ying Tian & Bing-Jie Wang & Zi-Bing Yu & Hou-Bo Zhou & Yue Kan & Yuan Lin & Jing Wang & Yun-liang , 2024. "Low pressure reversibly driving colossal barocaloric effect in two-dimensional vdW alkylammonium halides," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    6. Sijia Yao & Pengfei Dang & Yiming Li & Yao Wang & Xi Zhang & Ye Liu & Suxin Qian & Dezhen Xue & Ya-Ling He, 2024. "Efficient roller-driven elastocaloric refrigerator," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Qingyong Ren & Ji Qi & Dehong Yu & Zhe Zhang & Ruiqi Song & Wenli Song & Bao Yuan & Tianhao Wang & Weijun Ren & Zhidong Zhang & Xin Tong & Bing Li, 2022. "Ultrasensitive barocaloric material for room-temperature solid-state refrigeration," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    8. Sharif, M.K. Anuar & Al-Abidi, A.A. & Mat, S. & Sopian, K. & Ruslan, M.H. & Sulaiman, M.Y. & Rosli, M.A.M., 2015. "Review of the application of phase change material for heating and domestic hot water systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 557-568.
    9. Nallapaneni Manoj Kumar & Aneesh A. Chand & Maria Malvoni & Kushal A. Prasad & Kabir A. Mamun & F.R. Islam & Shauhrat S. Chopra, 2020. "Distributed Energy Resources and the Application of AI, IoT, and Blockchain in Smart Grids," Energies, MDPI, vol. 13(21), pages 1-42, November.
    10. Dutil, Yvan & Rousse, Daniel R. & Salah, Nizar Ben & Lassue, Stéphane & Zalewski, Laurent, 2011. "A review on phase-change materials: Mathematical modeling and simulations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 112-130, January.
    11. Gholamibozanjani, Gohar & Farid, Mohammed, 2020. "A comparison between passive and active PCM systems applied to buildings," Renewable Energy, Elsevier, vol. 162(C), pages 112-123.
    12. Hu, Nan & Li, Zi-Rui & Xu, Zhe-Wen & Fan, Li-Wu, 2022. "Rapid charging for latent heat thermal energy storage: A state-of-the-art review of close-contact melting," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    13. Jiang, Fuyun & Wang, Xiaodong & Wu, Dezhen, 2016. "Magnetic microencapsulated phase change materials with an organo-silica shell: Design, synthesis and application for electromagnetic shielding and thermal regulating polyimide films," Energy, Elsevier, vol. 98(C), pages 225-239.
    14. Thi Kim Tuoi, Truong & Van Toan, Nguyen & Ono, Takahito, 2022. "Self-powered wireless sensing system driven by daily ambient temperature energy harvesting," Applied Energy, Elsevier, vol. 311(C).
    15. Bąk, Agnieszka & Pławecka, Kinga & Bazan, Patrycja & Łach, Michał, 2023. "Influence of the addition of phase change materials on thermal insulation properties of foamed geopolymer structures based on fly ash," Energy, Elsevier, vol. 278(C).
    16. Bal, Lalit M. & Satya, Santosh & Naik, S.N., 2010. "Solar dryer with thermal energy storage systems for drying agricultural food products: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(8), pages 2298-2314, October.
    17. Gunjo, Dawit Gudeta & Jena, Smruti Ranjan & Mahanta, Pinakeswar & Robi, P.S., 2018. "Melting enhancement of a latent heat storage with dispersed Cu, CuO and Al2O3 nanoparticles for solar thermal application," Renewable Energy, Elsevier, vol. 121(C), pages 652-665.
    18. Li, Zhenpeng & Ma, Tao & Zhao, Jiaxin & Song, Aotian & Cheng, Yuanda, 2019. "Experimental study and performance analysis on solar photovoltaic panel integrated with phase change material," Energy, Elsevier, vol. 178(C), pages 471-486.
    19. Yuan, Yanping & Zhang, Nan & Li, Tianyu & Cao, Xiaoling & Long, Weiyue, 2016. "Thermal performance enhancement of palmitic-stearic acid by adding graphene nanoplatelets and expanded graphite for thermal energy storage: A comparative study," Energy, Elsevier, vol. 97(C), pages 488-497.
    20. Ikutegbe, Charles A. & Farid, Mohammed M., 2020. "Application of phase change material foam composites in the built environment: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29800-9. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.