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Engineering chirality at wafer scale with ordered carbon nanotube architectures

Author

Listed:
  • Jacques Doumani

    (Rice University
    Rice University
    The University of Utah)

  • Minhan Lou

    (The University of Utah)

  • Oliver Dewey

    (Rice University
    Rice University)

  • Nina Hong

    (J.A. Woollam Co., Inc.)

  • Jichao Fan

    (The University of Utah)

  • Andrey Baydin

    (Rice University
    Rice University)

  • Keshav Zahn

    (Rice University)

  • Yohei Yomogida

    (Tokyo Metropolitan University)

  • Kazuhiro Yanagi

    (Tokyo Metropolitan University)

  • Matteo Pasquali

    (Rice University
    Rice University
    Rice University
    Rice University)

  • Riichiro Saito

    (Tokyo Metropolitan University
    Tohoku University
    National Taiwan Normal University)

  • Junichiro Kono

    (Rice University
    Rice University
    Rice University
    Rice University)

  • Weilu Gao

    (The University of Utah
    Rice University)

Abstract

Creating artificial matter with controllable chirality in a simple and scalable manner brings new opportunities to diverse areas. Here we show two such methods based on controlled vacuum filtration - twist stacking and mechanical rotation - for fabricating wafer-scale chiral architectures of ordered carbon nanotubes (CNTs) with tunable and large circular dichroism (CD). By controlling the stacking angle and handedness in the twist-stacking approach, we maximize the CD response and achieve a high deep-ultraviolet ellipticity of 40 ± 1 mdeg nm−1. Our theoretical simulations using the transfer matrix method reproduce the experimentally observed CD spectra and further predict that an optimized film of twist-stacked CNTs can exhibit an ellipticity as high as 150 mdeg nm−1, corresponding to a g factor of 0.22. Furthermore, the mechanical rotation method not only accelerates the fabrication of twisted structures but also produces both chiralities simultaneously in a single sample, in a single run, and in a controllable manner. The created wafer-scale objects represent an alternative type of synthetic chiral matter consisting of ordered quantum wires whose macroscopic properties are governed by nanoscopic electronic signatures and can be used to explore chiral phenomena and develop chiral photonic and optoelectronic devices.

Suggested Citation

  • Jacques Doumani & Minhan Lou & Oliver Dewey & Nina Hong & Jichao Fan & Andrey Baydin & Keshav Zahn & Yohei Yomogida & Kazuhiro Yanagi & Matteo Pasquali & Riichiro Saito & Junichiro Kono & Weilu Gao, 2023. "Engineering chirality at wafer scale with ordered carbon nanotube architectures," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-43199-x
    DOI: 10.1038/s41467-023-43199-x
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    References listed on IDEAS

    as
    1. Kazuhiro Yanagi & Ryotaro Okada & Yota Ichinose & Yohei Yomogida & Fumiya Katsutani & Weilu Gao & Junichiro Kono, 2018. "Intersubband plasmons in the quantum limit in gated and aligned carbon nanotubes," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
    2. Y. Zhao & M.A. Belkin & A. Alù, 2012. "Twisted optical metamaterials for planarized ultrathin broadband circular polarizers," Nature Communications, Nature, vol. 3(1), pages 1-7, January.
    3. Huaping Liu & Daisuke Nishide & Takeshi Tanaka & Hiromichi Kataura, 2011. "Large-scale single-chirality separation of single-wall carbon nanotubes by simple gel chromatography," Nature Communications, Nature, vol. 2(1), pages 1-8, September.
    4. Peter Lodahl & Sahand Mahmoodian & Søren Stobbe & Arno Rauschenbeutel & Philipp Schneeweiss & Jürgen Volz & Hannes Pichler & Peter Zoller, 2017. "Chiral quantum optics," Nature, Nature, vol. 541(7638), pages 473-480, January.
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