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Unraveling oxygen vacancy site mechanism of Rh-doped RuO2 catalyst for long-lasting acidic water oxidation

Author

Listed:
  • Yi Wang

    (Chinese Academy of Sciences
    Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Rong Yang

    (Chinese Academy of Sciences
    Chinese Academy of Sciences
    Tianjin University)

  • Yajun Ding

    (Chinese Academy of Sciences
    Chinese Academy of Sciences)

  • Bo Zhang

    (Dalian Institute of Chemical Physics Chinese Academy of Sciences)

  • Hao Li

    (Chinese Academy of Sciences
    School of Nano Technology and Nano Bionics University of Science and Technology of China)

  • Bing Bai

    (Chinese Academy of Sciences
    Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Mingrun Li

    (Chinese Academy of Sciences
    Chinese Academy of Sciences)

  • Yi Cui

    (Chinese Academy of Sciences
    School of Nano Technology and Nano Bionics University of Science and Technology of China)

  • Jianping Xiao

    (Chinese Academy of Sciences
    Chinese Academy of Sciences)

  • Zhong-Shuai Wu

    (Chinese Academy of Sciences
    Chinese Academy of Sciences)

Abstract

Exploring durable electrocatalysts with high activity for oxygen evolution reaction (OER) in acidic media is of paramount importance for H2 production via polymer electrolyte membrane electrolyzers, yet it remains urgently challenging. Herein, we report a synergistic strategy of Rh doping and surface oxygen vacancies to precisely regulate unconventional OER reaction path via the Ru–O–Rh active sites of Rh-RuO2, simultaneously boosting intrinsic activity and stability. The stabilized low-valent catalyst exhibits a remarkable performance, with an overpotential of 161 mV at 10 mA cm−2 and activity retention of 99.2% exceeding 700 h at 50 mA cm−2. Quasi in situ/operando characterizations demonstrate the recurrence of reversible oxygen species under working potentials for enhanced activity and durability. It is theoretically revealed that Rh-RuO2 passes through a more optimal reaction path of lattice oxygen mediated mechanism-oxygen vacancy site mechanism induced by the synergistic interaction of defects and Ru–O–Rh active sites with the rate-determining step of *O formation, breaking the barrier limitation (*OOH) of the traditional adsorption evolution mechanism.

Suggested Citation

  • Yi Wang & Rong Yang & Yajun Ding & Bo Zhang & Hao Li & Bing Bai & Mingrun Li & Yi Cui & Jianping Xiao & Zhong-Shuai Wu, 2023. "Unraveling oxygen vacancy site mechanism of Rh-doped RuO2 catalyst for long-lasting acidic water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37008-8
    DOI: 10.1038/s41467-023-37008-8
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    References listed on IDEAS

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    1. Jiankang Zhang & Zhe Gao & Sen Wang & Guofu Wang & Xiaofeng Gao & Baiyan Zhang & Shuangfeng Xing & Shichao Zhao & Yong Qin, 2019. "Origin of synergistic effects in bicomponent cobalt oxide-platinum catalysts for selective hydrogenation reaction," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    2. Daqin Guan & Gihun Ryu & Zhiwei Hu & Jing Zhou & Chung-Li Dong & Yu-Cheng Huang & Kaifeng Zhang & Yijun Zhong & Alexander C. Komarek & Ming Zhu & Xinhao Wu & Chih-Wen Pao & Chung-Kai Chang & Hong-Ji L, 2020. "Utilizing ion leaching effects for achieving high oxygen-evolving performance on hybrid nanocomposite with self-optimized behaviors," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    3. Linlin Cao & Qiquan Luo & Jiajia Chen & Lan Wang & Yue Lin & Huijuan Wang & Xiaokang Liu & Xinyi Shen & Wei Zhang & Wei Liu & Zeming Qi & Zheng Jiang & Jinlong Yang & Tao Yao, 2019. "Dynamic oxygen adsorption on single-atomic Ruthenium catalyst with high performance for acidic oxygen evolution reaction," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    4. Yichao Lin & Ziqi Tian & Linjuan Zhang & Jingyuan Ma & Zheng Jiang & Benjamin J. Deibert & Ruixiang Ge & Liang Chen, 2019. "Chromium-ruthenium oxide solid solution electrocatalyst for highly efficient oxygen evolution reaction in acidic media," Nature Communications, Nature, vol. 10(1), pages 1-13, December.
    5. Zhen-Feng Huang & Jiajia Song & Yonghua Du & Shibo Xi & Shuo Dou & Jean Marie Vianney Nsanzimana & Cheng Wang & Zhichuan J. Xu & Xin Wang, 2019. "Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts," Nature Energy, Nature, vol. 4(4), pages 329-338, April.
    6. Zhiping Zeng & Li Yong Gan & Hong Yang & Xiaozhi Su & Jiajian Gao & Wei Liu & Hiroaki Matsumoto & Jun Gong & Junming Zhang & Weizhen Cai & Zheye Zhang & Yibo Yan & Bin Liu & Peng Chen, 2021. "Orbital coupling of hetero-diatomic nickel-iron site for bifunctional electrocatalysis of CO2 reduction and oxygen evolution," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
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    Cited by:

    1. Hongnan Jia & Na Yao & Yiming Jin & Liqing Wu & Juan Zhu & Wei Luo, 2024. "Stabilizing atomic Ru species in conjugated sp2 carbon-linked covalent organic framework for acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    2. Haoyin Zhong & Qi Zhang & Junchen Yu & Xin Zhang & Chao Wu & Hang An & Yifan Ma & Hao Wang & Jun Zhang & Yong-Wei Zhang & Caozheng Diao & Zhi Gen Yu & Shibo Xi & Xiaopeng Wang & Junmin Xue, 2023. "Key role of eg* band broadening in nickel-based oxyhydroxides on coupled oxygen evolution mechanism," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Yu Shen & Xiao-Long Zhang & Ming-Rong Qu & Jie Ma & Sheng Zhu & Yu-Lin Min & Min-Rui Gao & Shu-Hong Yu, 2024. "Cr dopant mediates hydroxyl spillover on RuO2 for high-efficiency proton exchange membrane electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Lingxi Zhou & Yangfan Shao & Fang Yin & Jia Li & Feiyu Kang & Ruitao Lv, 2023. "Stabilizing non-iridium active sites by non-stoichiometric oxide for acidic water oxidation at high current density," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    5. Yizhen Lu & Bixuan Li & Na Xu & Zhihua Zhou & Yu Xiao & Yu Jiang & Teng Li & Sheng Hu & Yongji Gong & Yang Cao, 2023. "One-atom-thick hexagonal boron nitride co-catalyst for enhanced oxygen evolution reactions," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    6. Lu Li & Gengwei Zhang & Chenhui Zhou & Fan Lv & Yingjun Tan & Ying Han & Heng Luo & Dawei Wang & Youxing Liu & Changshuai Shang & Lingyou Zeng & Qizheng Huang & Ruijin Zeng & Na Ye & Mingchuan Luo & S, 2024. "Lanthanide-regulating Ru-O covalency optimizes acidic oxygen evolution electrocatalysis," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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