IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-33150-x.html
   My bibliography  Save this article

Interface engineering breaks both stability and activity limits of RuO2 for sustainable water oxidation

Author

Listed:
  • Kun Du

    (Tianjin University)

  • Lifu Zhang

    (Nankai University)

  • Jieqiong Shan

    (The University of Adelaide)

  • Jiaxin Guo

    (Tianjin University)

  • Jing Mao

    (Tianjin University)

  • Chueh-Cheng Yang

    (National Synchrotron Radiation Research Center
    National Yang Ming Chiao Tung University)

  • Chia-Hsin Wang

    (National Synchrotron Radiation Research Center)

  • Zhenpeng Hu

    (Nankai University)

  • Tao Ling

    (Tianjin University)

Abstract

Designing catalytic materials with enhanced stability and activity is crucial for sustainable electrochemical energy technologies. RuO2 is the most active material for oxygen evolution reaction (OER) in electrolysers aiming at producing ‘green’ hydrogen, however it encounters critical electrochemical oxidation and dissolution issues during reaction. It remains a grand challenge to achieve stable and active RuO2 electrocatalyst as the current strategies usually enhance one of the two properties at the expense of the other. Here, we report breaking the stability and activity limits of RuO2 in neutral and alkaline environments by constructing a RuO2/CoOx interface. We demonstrate that RuO2 can be greatly stabilized on the CoOx substrate to exceed the Pourbaix stability limit of bulk RuO2. This is realized by the preferential oxidation of CoOx during OER and the electron gain of RuO2 through the interface. Besides, a highly active Ru/Co dual-atom site can be generated around the RuO2/CoOx interface to synergistically adsorb the oxygen intermediates, leading to a favourable reaction path. The as-designed RuO2/CoOx catalyst provides an avenue to achieve stable and active materials for sustainable electrochemical energy technologies.

Suggested Citation

  • Kun Du & Lifu Zhang & Jieqiong Shan & Jiaxin Guo & Jing Mao & Chueh-Cheng Yang & Chia-Hsin Wang & Zhenpeng Hu & Tao Ling, 2022. "Interface engineering breaks both stability and activity limits of RuO2 for sustainable water oxidation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33150-x
    DOI: 10.1038/s41467-022-33150-x
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-33150-x
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-33150-x?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Pengsong Li & Maoyu Wang & Xinxuan Duan & Lirong Zheng & Xiaopeng Cheng & Yuefei Zhang & Yun Kuang & Yaping Li & Qing Ma & Zhenxing Feng & Wen Liu & Xiaoming Sun, 2019. "Boosting oxygen evolution of single-atomic ruthenium through electronic coupling with cobalt-iron layered double hydroxides," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    2. Tao Ling & Dong-Yang Yan & Yan Jiao & Hui Wang & Yao Zheng & Xueli Zheng & Jing Mao & Xi-Wen Du & Zhenpeng Hu & Mietek Jaroniec & Shi-Zhang Qiao, 2016. "Engineering surface atomic structure of single-crystal cobalt (II) oxide nanorods for superior electrocatalysis," Nature Communications, Nature, vol. 7(1), pages 1-8, November.
    3. Linlin Cao & Qiquan Luo & Jiajia Chen & Lan Wang & Yue Lin & Huijuan Wang & Xiaokang Liu & Xinyi Shen & Wei Zhang & Wei Liu & Zeming Qi & Zheng Jiang & Jinlong Yang & Tao Yao, 2019. "Dynamic oxygen adsorption on single-atomic Ruthenium catalyst with high performance for acidic oxygen evolution reaction," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    4. Sandra Haschke & Michael Mader & Stefanie Schlicht & André M. Roberts & Alfredo M. Angeles-Boza & Johannes A. C. Barth & Julien Bachmann, 2018. "Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    5. Tao Ling & Dong-Yang Yan & Hui Wang & Yan Jiao & Zhenpeng Hu & Yao Zheng & Lirong Zheng & Jing Mao & Hui Liu & Xi-Wen Du & Mietek Jaroniec & Shi-Zhang Qiao, 2017. "Activating cobalt(II) oxide nanorods for efficient electrocatalysis by strain engineering," Nature Communications, Nature, vol. 8(1), pages 1-7, December.
    6. Yichao Lin & Ziqi Tian & Linjuan Zhang & Jingyuan Ma & Zheng Jiang & Benjamin J. Deibert & Ruixiang Ge & Liang Chen, 2019. "Chromium-ruthenium oxide solid solution electrocatalyst for highly efficient oxygen evolution reaction in acidic media," Nature Communications, Nature, vol. 10(1), pages 1-13, December.
    7. Seo Hyoung Chang & Nemanja Danilovic & Kee-Chul Chang & Ram Subbaraman & Arvydas P. Paulikas & Dillon D. Fong & Matthew J. Highland & Peter M. Baldo & Vojislav R. Stamenkovic & John W. Freeland & Jeff, 2014. "Functional links between stability and reactivity of strontium ruthenate single crystals during oxygen evolution," Nature Communications, Nature, vol. 5(1), pages 1-9, September.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ding Chen & Ruohan Yu & Kesong Yu & Ruihu Lu & Hongyu Zhao & Jixiang Jiao & Youtao Yao & Jiawei Zhu & Jinsong Wu & Shichun Mu, 2024. "Bicontinuous RuO2 nanoreactors for acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Yanrong Xue & Jiwu Zhao & Liang Huang & Ying-Rui Lu & Abdul Malek & Ge Gao & Zhongbin Zhuang & Dingsheng Wang & Cafer T. Yavuz & Xu Lu, 2023. "Stabilizing ruthenium dioxide with cation-anchored sulfate for durable oxygen evolution in proton-exchange membrane water electrolyzers," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    3. Sheng Zhao & Sung-Fu Hung & Liming Deng & Wen-Jing Zeng & Tian Xiao & Shaoxiong Li & Chun-Han Kuo & Han-Yi Chen & Feng Hu & Shengjie Peng, 2024. "Constructing regulable supports via non-stoichiometric engineering to stabilize ruthenium nanoparticles for enhanced pH-universal water splitting," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Lingxi Zhou & Yangfan Shao & Fang Yin & Jia Li & Feiyu Kang & Ruitao Lv, 2023. "Stabilizing non-iridium active sites by non-stoichiometric oxide for acidic water oxidation at high current density," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Dmitry Galyamin & Jorge Torrero & Isabel Rodríguez & Manuel J. Kolb & Pilar Ferrer & Laura Pascual & Mohamed Abdel Salam & Diego Gianolio & Verónica Celorrio & Mohamed Mokhtar & Daniel Garcia Sanchez , 2023. "Active and durable R2MnRuO7 pyrochlores with low Ru content for acidic oxygen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Lingyou Zeng & Zhonglong Zhao & Fan Lv & Zhonghong Xia & Shi-Yu Lu & Jiong Li & Kaian Sun & Kai Wang & Yingjun Sun & Qizheng Huang & Yan Chen & Qinghua Zhang & Lin Gu & Gang Lu & Shaojun Guo, 2022. "Anti-dissolution Pt single site with Pt(OH)(O3)/Co(P) coordination for efficient alkaline water splitting electrolyzer," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Xinyu Ping & Yongduo Liu & Lixia Zheng & Yang Song & Lin Guo & Siguo Chen & Zidong Wei, 2024. "Locking the lattice oxygen in RuO2 to stabilize highly active Ru sites in acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Jie Wei & Hua Tang & Li Sheng & Ruyang Wang & Minghui Fan & Jiale Wan & Yuheng Wu & Zhirong Zhang & Shiming Zhou & Jie Zeng, 2024. "Site-specific metal-support interaction to switch the activity of Ir single atoms for oxygen evolution reaction," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    5. Jiao Lan & Zengxi Wei & Ying-Rui Lu & DeChao Chen & Shuangliang Zhao & Ting-Shan Chan & Yongwen Tan, 2023. "Efficient electrosynthesis of formamide from carbon monoxide and nitrite on a Ru-dispersed Cu nanocluster catalyst," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Yi Wang & Rong Yang & Yajun Ding & Bo Zhang & Hao Li & Bing Bai & Mingrun Li & Yi Cui & Jianping Xiao & Zhong-Shuai Wu, 2023. "Unraveling oxygen vacancy site mechanism of Rh-doped RuO2 catalyst for long-lasting acidic water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Che Lah, Nurul Akmal, 2021. "Late transition metal nanocomplexes: Applications for renewable energy conversion and storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    8. Min Xu & Jinjun Qu & Mai Li, 2022. "National Policies, Recent Research Hotspots, and Application of Sustainable Energy: Case of China, USA, and European Countries," Sustainability, MDPI, vol. 14(16), pages 1-30, August.
    9. Qianbao Wu & Junwu Liang & Mengjun Xiao & Chang Long & Lei Li & Zhenhua Zeng & Andraž Mavrič & Xia Zheng & Jing Zhu & Hai-Wei Liang & Hongfei Liu & Matjaz Valant & Wei Wang & Zhengxing Lv & Jiong Li &, 2023. "Non-covalent ligand-oxide interaction promotes oxygen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Nihat Ege Sahin & W. J. Pech-Rodríguez & P. C. Meléndez-González & Juan Lopez Hernández & E. Rocha-Rangel, 2023. "Water Splitting as an Alternative for Electrochemical Hydrogen and Oxygen Generation: Current Status, Trends, and Challenges," Energies, MDPI, vol. 16(13), pages 1-25, June.
    11. Jiaqi Zhao & Jinjia Liu & Zhenhua Li & Kaiwen Wang & Run Shi & Pu Wang & Qing Wang & Geoffrey I. N. Waterhouse & Xiaodong Wen & Tierui Zhang, 2023. "Ruthenium-cobalt single atom alloy for CO photo-hydrogenation to liquid fuels at ambient pressures," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    12. Zhe Chen & Jili Li & Lingshen Meng & Jianan Li & Yaming Hao & Tao Jiang & Xuejing Yang & Yefei Li & Zhi-Pan Liu & Ming Gong, 2023. "Ligand vacancy channels in pillared inorganic-organic hybrids for electrocatalytic organic oxidation with enzyme-like activities," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    13. Gang Zhou & Peifang Wang & Bin Hu & Xinyue Shen & Chongchong Liu & Weixiang Tao & Peilin Huang & Lizhe Liu, 2022. "Spin-related symmetry breaking induced by half-disordered hybridization in BixEr2-xRu2O7 pyrochlores for acidic oxygen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    14. Chun-Kuo Peng & Yu-Chang Lin & Chao‐Lung Chiang & Zhengxin Qian & Yu-Cheng Huang & Chung-Li Dong & Jian‐Feng Li & Chien-Te Chen & Zhiwei Hu & San-Yuan Chen & Yan-Gu Lin, 2023. "Zhang-Rice singlets state formed by two-step oxidation for triggering water oxidation under operando conditions," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    15. Zhaoping Shi & Ji Li & Yibo Wang & Shiwei Liu & Jianbing Zhu & Jiahao Yang & Xian Wang & Jing Ni & Zheng Jiang & Lijuan Zhang & Ying Wang & Changpeng Liu & Wei Xing & Junjie Ge, 2023. "Customized reaction route for ruthenium oxide towards stabilized water oxidation in high-performance PEM electrolyzers," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    16. Yixin Hao & Sung-Fu Hung & Luqi Wang & Liming Deng & Wen-Jing Zeng & Chenchen Zhang & Zih-Yi Lin & Chun-Han Kuo & Ye Wang & Ying Zhang & Han-Yi Chen & Feng Hu & Linlin Li & Shengjie Peng, 2024. "Designing neighboring-site activation of single atom via tunnel ions for boosting acidic oxygen evolution," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    17. Lingxi Zhou & Yangfan Shao & Fang Yin & Jia Li & Feiyu Kang & Ruitao Lv, 2023. "Stabilizing non-iridium active sites by non-stoichiometric oxide for acidic water oxidation at high current density," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    18. Achim Füngerlings & Marcus Wohlgemuth & Denis Antipin & Emma Minne & Ellen Marijn Kiens & Javier Villalobos & Marcel Risch & Felix Gunkel & Rossitza Pentcheva & Christoph Baeumer, 2023. "Crystal-facet-dependent surface transformation dictates the oxygen evolution reaction activity in lanthanum nickelate," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    19. Yangyang Liu & Can Li & Chunhui Tan & Zengxia Pei & Tao Yang & Shuzhen Zhang & Qianwei Huang & Yihan Wang & Zheng Zhou & Xiaozhou Liao & Juncai Dong & Hao Tan & Wensheng Yan & Huajie Yin & Zhao-Qing L, 2023. "Electrosynthesis of chlorine from seawater-like solution through single-atom catalysts," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    20. Siliu Lyu & Chenxi Guo & Jianing Wang & Zhongjian Li & Bin Yang & Lecheng Lei & Liping Wang & Jianping Xiao & Tao Zhang & Yang Hou, 2022. "Exceptional catalytic activity of oxygen evolution reaction via two-dimensional graphene multilayer confined metal-organic frameworks," Nature Communications, Nature, vol. 13(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33150-x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.