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Pt-induced atomic-level tailoring towards paracrystalline high-entropy alloy

Author

Listed:
  • Xingjia He

    (Jilin University)

  • Yu Zhang

    (Jilin University)

  • Xinlei Gu

    (Jilin University)

  • Jiangwei Wang

    (Zhejiang University)

  • Jinlei Qi

    (Jilin University)

  • Jun Hao

    (Jilin University)

  • Longpeng Wang

    (Jilin University)

  • Hao Huang

    (AECC Beijing Institute of Aeronautical Materials)

  • Mao Wen

    (Jilin University)

  • Kan Zhang

    (Jilin University)

  • Weitao Zheng

    (Jilin University)

Abstract

Paracrystalline state achieved in the diamond system guides a direction to explore the missing link between amorphous and crystalline states. However, such a state is still challenging to reach in alloy systems in a controlled manner. Here, based on the vast composition space and the complex atomic interactions in the high-entropy alloys (HEAs), we present an “atomic-level tailoring” strategy to create the paracrystalline HEA. The addition of atomic-level Pt with the large and negative mixing enthalpy induces the local atomic reshuffling around Pt atoms for the well-targeted local amorphization, which separates severe-distorted crystalline Zr-Nb-Hf-Ta-Mo HEA into the high-density crystalline MRO motifs on atomic-level. The paracrystalline HEA exhibits high hardness (16.6 GPa) and high yield strength (8.37 GPa) and deforms by nanoscale shear-banding and nanocrystallization modes. Such an enthalpy-guided strategy in HEAs can provide the atomic-level tailoring ability to purposefully regulate structural characteristics and desirable properties.

Suggested Citation

  • Xingjia He & Yu Zhang & Xinlei Gu & Jiangwei Wang & Jinlei Qi & Jun Hao & Longpeng Wang & Hao Huang & Mao Wen & Kan Zhang & Weitao Zheng, 2023. "Pt-induced atomic-level tailoring towards paracrystalline high-entropy alloy," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36423-1
    DOI: 10.1038/s41467-023-36423-1
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