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An ionic vinylene-linked three-dimensional covalent organic framework for selective and efficient trapping of ReO4− or 99TcO4−

Author

Listed:
  • Cheng-Rong Zhang

    (Nanchang University)

  • Wei-Rong Cui

    (Nanchang University)

  • Shun-Mo Yi

    (Nanchang University)

  • Cheng-Peng Niu

    (Nanchang University)

  • Ru-Ping Liang

    (Nanchang University)

  • Jia-Xin Qi

    (Nanchang University)

  • Xiao-Juan Chen

    (Nanchang University)

  • Wei Jiang

    (Nanchang University)

  • Xin Liu

    (Nanchang University)

  • Qiu-Xia Luo

    (Nanchang University)

  • Jian-Ding Qiu

    (Nanchang University
    East China University of Technology)

Abstract

The synthesis of ionic olefin linked three-dimensional covalent organic frameworks (3D COFs) is greatly challenging given the hardness of the formation of stable carbon-carbon double bonds (–C = C–). Herein, we report a general strategy for designing porous positively charged sp2 carbon-linked 3D COFs through the Aldol condensation promoted by quaternization. The obtained 3D COFs, namely TFPM-PZI and TAPM-PZI, showed impressive chemical stability. Furthermore, the positively charged frameworks with regular porosity endow 3D ionic COFs with selective capture radioactive ReO4−/TcO4− and great removal efficiency in simulated Hanford waste. This research not only broadens the category of 3D COFs but also promotes the application of COFs as efficient functional materials.

Suggested Citation

  • Cheng-Rong Zhang & Wei-Rong Cui & Shun-Mo Yi & Cheng-Peng Niu & Ru-Ping Liang & Jia-Xin Qi & Xiao-Juan Chen & Wei Jiang & Xin Liu & Qiu-Xia Luo & Jian-Ding Qiu, 2022. "An ionic vinylene-linked three-dimensional covalent organic framework for selective and efficient trapping of ReO4− or 99TcO4−," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35435-7
    DOI: 10.1038/s41467-022-35435-7
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    References listed on IDEAS

    as
    1. Nannan Shen & Zaixing Yang & Shengtang Liu & Xing Dai & Chengliang Xiao & Kathryn Taylor-Pashow & Dien Li & Chuang Yang & Jie Li & Yugang Zhang & Mingxing Zhang & Ruhong Zhou & Zhifang Chai & Shuao Wa, 2020. "99TcO4− removal from legacy defense nuclear waste by an alkaline-stable 2D cationic metal organic framework," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
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