IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-35435-7.html
   My bibliography  Save this article

An ionic vinylene-linked three-dimensional covalent organic framework for selective and efficient trapping of ReO4− or 99TcO4−

Author

Listed:
  • Cheng-Rong Zhang

    (Nanchang University)

  • Wei-Rong Cui

    (Nanchang University)

  • Shun-Mo Yi

    (Nanchang University)

  • Cheng-Peng Niu

    (Nanchang University)

  • Ru-Ping Liang

    (Nanchang University)

  • Jia-Xin Qi

    (Nanchang University)

  • Xiao-Juan Chen

    (Nanchang University)

  • Wei Jiang

    (Nanchang University)

  • Xin Liu

    (Nanchang University)

  • Qiu-Xia Luo

    (Nanchang University)

  • Jian-Ding Qiu

    (Nanchang University
    East China University of Technology)

Abstract

The synthesis of ionic olefin linked three-dimensional covalent organic frameworks (3D COFs) is greatly challenging given the hardness of the formation of stable carbon-carbon double bonds (–C = C–). Herein, we report a general strategy for designing porous positively charged sp2 carbon-linked 3D COFs through the Aldol condensation promoted by quaternization. The obtained 3D COFs, namely TFPM-PZI and TAPM-PZI, showed impressive chemical stability. Furthermore, the positively charged frameworks with regular porosity endow 3D ionic COFs with selective capture radioactive ReO4−/TcO4− and great removal efficiency in simulated Hanford waste. This research not only broadens the category of 3D COFs but also promotes the application of COFs as efficient functional materials.

Suggested Citation

  • Cheng-Rong Zhang & Wei-Rong Cui & Shun-Mo Yi & Cheng-Peng Niu & Ru-Ping Liang & Jia-Xin Qi & Xiao-Juan Chen & Wei Jiang & Xin Liu & Qiu-Xia Luo & Jian-Ding Qiu, 2022. "An ionic vinylene-linked three-dimensional covalent organic framework for selective and efficient trapping of ReO4− or 99TcO4−," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35435-7
    DOI: 10.1038/s41467-022-35435-7
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-35435-7
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-35435-7?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Nannan Shen & Zaixing Yang & Shengtang Liu & Xing Dai & Chengliang Xiao & Kathryn Taylor-Pashow & Dien Li & Chuang Yang & Jie Li & Yugang Zhang & Mingxing Zhang & Ruhong Zhou & Zhifang Chai & Shuao Wa, 2020. "99TcO4− removal from legacy defense nuclear waste by an alkaline-stable 2D cationic metal organic framework," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    2. Wei-Rong Cui & Cheng-Rong Zhang & Wei Jiang & Fang-Fang Li & Ru-Ping Liang & Juewen Liu & Jian-Ding Qiu, 2020. "Regenerable and stable sp2 carbon-conjugated covalent organic frameworks for selective detection and extraction of uranium," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    3. Ya-Jie Li & Wei-Rong Cui & Qiao-Qiao Jiang & Qiong Wu & Ru-Ping Liang & Qiu-Xia Luo & Jian-Ding Qiu, 2021. "Author Correction: A general design approach toward covalent organic frameworks for highly efficient electrochemiluminescence," Nature Communications, Nature, vol. 12(1), pages 1-1, December.
    4. Qi Sun & Lin Zhu & Briana Aguila & Praveen K. Thallapally & Chao Xu & Jing Chen & Shuao Wang & David Rogers & Shengqian Ma, 2019. "Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    5. Enquan Jin & Juan Li & Keyu Geng & Qiuhong Jiang & Hong Xu & Qing Xu & Donglin Jiang, 2018. "Designed synthesis of stable light-emitting two-dimensional sp2 carbon-conjugated covalent organic frameworks," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    6. Shuai Bi & Can Yang & Wenbei Zhang & Junsong Xu & Lingmei Liu & Dongqing Wu & Xinchen Wang & Yu Han & Qifeng Liang & Fan Zhang, 2019. "Two-dimensional semiconducting covalent organic frameworks via condensation at arylmethyl carbon atoms," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    7. Ya-Jie Li & Wei-Rong Cui & Qiao-Qiao Jiang & Qiong Wu & Ru-Ping Liang & Qiu-Xia Luo & Jian-Ding Qiu, 2021. "A general design approach toward covalent organic frameworks for highly efficient electrochemiluminescence," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    8. Youshi Lan & Xianghao Han & Minman Tong & Hongliang Huang & Qingyuan Yang & Dahuan Liu & Xin Zhao & Chongli Zhong, 2018. "Materials genomics methods for high-throughput construction of COFs and targeted synthesis," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Cheng-Peng Niu & Cheng-Rong Zhang & Xin Liu & Ru-Ping Liang & Jian-Ding Qiu, 2023. "Synthesis of propenone-linked covalent organic frameworks via Claisen-Schmidt reaction for photocatalytic removal of uranium," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Zhongshan Chen & Jingyi Wang & Mengjie Hao & Yinghui Xie & Xiaolu Liu & Hui Yang & Geoffrey I. N. Waterhouse & Xiangke Wang & Shengqian Ma, 2023. "Tuning excited state electronic structure and charge transport in covalent organic frameworks for enhanced photocatalytic performance," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Maria-Anna Gatou & Panagiota Bika & Thomas Stergiopoulos & Panagiotis Dallas & Evangelia A. Pavlatou, 2021. "Recent Advances in Covalent Organic Frameworks for Heavy Metal Removal Applications," Energies, MDPI, vol. 14(11), pages 1-26, May.
    4. Zeyu Liu & Youshi Lan & Jianfeng Jia & Yiyun Geng & Xiaobin Dai & Litang Yan & Tongyang Hu & Jing Chen & Krzysztof Matyjaszewski & Gang Ye, 2022. "Multi-scale computer-aided design and photo-controlled macromolecular synthesis boosting uranium harvesting from seawater," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    5. Jingqi Wang & Jiapeng Liu & Hongshuai Wang & Musen Zhou & Guolin Ke & Linfeng Zhang & Jianzhong Wu & Zhifeng Gao & Diannan Lu, 2024. "A comprehensive transformer-based approach for high-accuracy gas adsorption predictions in metal-organic frameworks," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    6. Yannan Liu & Cheng-Hao Liu & Tushar Debnath & Yong Wang & Darius Pohl & Lucas V. Besteiro & Debora Motta Meira & Shengyun Huang & Fan Yang & Bernd Rellinghaus & Mohamed Chaker & Dmytro F. Perepichka &, 2023. "Silver nanoparticle enhanced metal-organic matrix with interface-engineering for efficient photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    7. Fuyang Liu & Peng Zhou & Yanghui Hou & Hao Tan & Yin Liang & Jialiang Liang & Qing Zhang & Shaojun Guo & Meiping Tong & Jinren Ni, 2023. "Covalent organic frameworks for direct photosynthesis of hydrogen peroxide from water, air and sunlight," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    8. Hui Li & Caikun Cheng & Zhijie Yang & Jingjing Wei, 2022. "Encapsulated CdSe/CdS nanorods in double-shelled porous nanocomposites for efficient photocatalytic CO2 reduction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    9. Yajun Zou & Sara Abednatanzi & Parviz Gohari Derakhshandeh & Stefano Mazzanti & Christoph M. Schüßlbauer & Daniel Cruz & Pascal Voort & Jian-Wen Shi & Markus Antonietti & Dirk M. Guldi & Aleksandr Sav, 2022. "Red edge effect and chromoselective photocatalysis with amorphous covalent triazine-based frameworks," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    10. Wang, Hui & Chen, Li & Qu, Zhiguo & Yin, Ying & Kang, Qinjun & Yu, Bo & Tao, Wen-Quan, 2020. "Modeling of multi-scale transport phenomena in shale gas production — A critical review," Applied Energy, Elsevier, vol. 262(C).
    11. Gobinda Das & Bikash Garai & Thirumurugan Prakasam & Farah Benyettou & Sabu Varghese & Sudhir Kumar Sharma & Felipe Gándara & Renu Pasricha & Maria Baias & Ramesh Jagannathan & Na’il Saleh & Mourad El, 2022. "Fluorescence turn on amine detection in a cationic covalent organic framework," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    12. Jian Li & Cong Lin & Tianqiong Ma & Junliang Sun, 2022. "Atomic-resolution structures from polycrystalline covalent organic frameworks with enhanced cryo-cRED," Nature Communications, Nature, vol. 13(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35435-7. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.