IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-31393-2.html
   My bibliography  Save this article

Fluorescence turn on amine detection in a cationic covalent organic framework

Author

Listed:
  • Gobinda Das

    (New York University Abu Dhabi (NYUAD))

  • Bikash Garai

    (New York University Abu Dhabi (NYUAD)
    New York University Abu Dhabi (NYUAD))

  • Thirumurugan Prakasam

    (New York University Abu Dhabi (NYUAD))

  • Farah Benyettou

    (New York University Abu Dhabi (NYUAD))

  • Sabu Varghese

    (CTP, New York University Abu Dhabi (NYUAD))

  • Sudhir Kumar Sharma

    (New York University Abu Dhabi (NYUAD))

  • Felipe Gándara

    (Materials Science Institute of Madrid – CSIC)

  • Renu Pasricha

    (CTP, New York University Abu Dhabi (NYUAD))

  • Maria Baias

    (New York University Abu Dhabi (NYUAD))

  • Ramesh Jagannathan

    (New York University Abu Dhabi (NYUAD))

  • Na’il Saleh

    (United Arab Emirates University
    United Arab Emirates University)

  • Mourad Elhabiri

    (Université de Strasbourg, Université de Haute-Alsace, CNRS, LIMA, UMR 7042, Equipe Chimie Bioorganique et Médicinale)

  • Mark A. Olson

    (Texas A&M University Corpus Christi)

  • Ali Trabolsi

    (New York University Abu Dhabi (NYUAD)
    New York University Abu Dhabi (NYUAD))

Abstract

Ionic covalent organic frameworks (iCOFs) are new examples of porous materials and have shown great potential for various applications. When functionalized with suitable emission sites, guest uptake via the ionic moieties of iCOFs can cause a significant change in luminescence, making them excellent candidates for chemosensors. In here, we present a luminescence sensor in the form of an ionic covalent organic framework (TGH+•PD) composed of guanidinium and phenanthroline moieties for the detection of ammonia and primary aliphatic amines. TGH+•PD exhibits strong emission enhancement in the presence of selective primary amines due to the suppression of intramolecular charge transfer (ICT) with an ultra-low detection limit of 1.2 × 10‒7 M for ammonia. The presence of ionic moieties makes TGH+•PD highly dispersible in water, while deprotonation of the guanidinium moiety by amines restricts its ICT process and signals their presence by enhanced fluorescence emission. The presence of ordered pore walls introduces size selectivity among analyte molecules, and the iCOF has been successfully used to monitor meat products that release biogenic amine vapors upon decomposition due to improper storage.

Suggested Citation

  • Gobinda Das & Bikash Garai & Thirumurugan Prakasam & Farah Benyettou & Sabu Varghese & Sudhir Kumar Sharma & Felipe Gándara & Renu Pasricha & Maria Baias & Ramesh Jagannathan & Na’il Saleh & Mourad El, 2022. "Fluorescence turn on amine detection in a cationic covalent organic framework," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31393-2
    DOI: 10.1038/s41467-022-31393-2
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-31393-2
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-31393-2?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Laura Ascherl & Emrys W. Evans & Matthias Hennemann & Daniele Di Nuzzo & Alexander G. Hufnagel & Michael Beetz & Richard H. Friend & Timothy Clark & Thomas Bein & Florian Auras, 2018. "Solvatochromic covalent organic frameworks," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    2. Feng Zhou & Peiyang Gu & Zhipu Luo & Hari Krishna Bisoyi & Yujin Ji & Youyong Li & Qingfeng Xu & Quan Li & Jianmei Lu, 2021. "Unexpected organic hydrate luminogens in the solid state," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    3. Wei-Rong Cui & Cheng-Rong Zhang & Wei Jiang & Fang-Fang Li & Ru-Ping Liang & Juewen Liu & Jian-Ding Qiu, 2020. "Regenerable and stable sp2 carbon-conjugated covalent organic frameworks for selective detection and extraction of uranium," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    4. Jinqiao Dong & Kang Zhang & Xu Li & Yuhong Qian & Hai Zhu & Daqiang Yuan & Qing-Hua Xu & Jianwen Jiang & Dan Zhao, 2017. "Ultrathin two-dimensional porous organic nanosheets with molecular rotors for chemical sensing," Nature Communications, Nature, vol. 8(1), pages 1-14, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shuang Tong & Jianhong Dai & Jiangman Sun & Yuanyuan Liu & Xiaoli Ma & Zhehong Liu & Teng Ma & Jiao Tan & Zhen Yao & Shanmin Wang & Haiyan Zheng & Kai Wang & Fang Hong & Xiaohui Yu & Chunxiao Gao & Xi, 2022. "Fluorescence-based monitoring of the pressure-induced aggregation microenvironment evolution for an AIEgen under multiple excitation channels," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Yangyang Xu & Tu Sun & Tengwu Zeng & Xiangyu Zhang & Xuan Yao & Shan Liu & Zhaolin Shi & Wen Wen & Yingbo Zhao & Shan Jiang & Yanhang Ma & Yue-Biao Zhang, 2023. "Symmetry-breaking dynamics in a tautomeric 3D covalent organic framework," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Qing Hao & Xiao-Rui Ren & Yichen Chen & Chao Zhao & Jingyi Xu & Dong Wang & Hong Liu, 2023. "A sweat-responsive covalent organic framework film for material-based liveness detection and sweat pore analysis," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    4. Xueqi Tian & Minzan Zuo & Yuhong Shen & Ni Mao & Kaiya Wang & Yanshan Sheng & Krishnasamy Velmurugan & Jianmin Jiao & Xiao-Yu Hu, 2024. "TPE-embedded butterfly bis-crown ether with controllable conformation and supramolecular chiroptical property," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Zhongshan Chen & Jingyi Wang & Mengjie Hao & Yinghui Xie & Xiaolu Liu & Hui Yang & Geoffrey I. N. Waterhouse & Xiangke Wang & Shengqian Ma, 2023. "Tuning excited state electronic structure and charge transport in covalent organic frameworks for enhanced photocatalytic performance," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    6. Cheng-Rong Zhang & Wei-Rong Cui & Shun-Mo Yi & Cheng-Peng Niu & Ru-Ping Liang & Jia-Xin Qi & Xiao-Juan Chen & Wei Jiang & Xin Liu & Qiu-Xia Luo & Jian-Ding Qiu, 2022. "An ionic vinylene-linked three-dimensional covalent organic framework for selective and efficient trapping of ReO4− or 99TcO4−," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    7. Rengan Luo & Haifeng Lv & Qiaobo Liao & Ningning Wang & Jiarui Yang & Yang Li & Kai Xi & Xiaojun Wu & Huangxian Ju & Jianping Lei, 2021. "Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworks," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    8. Cheng-Peng Niu & Cheng-Rong Zhang & Xin Liu & Ru-Ping Liang & Jian-Ding Qiu, 2023. "Synthesis of propenone-linked covalent organic frameworks via Claisen-Schmidt reaction for photocatalytic removal of uranium," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31393-2. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.