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Lamellar carbon nitride membrane for enhanced ion sieving and water desalination

Author

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  • Yang Wang

    (Max Planck Institute of Colloids and Interfaces)

  • Tingting Lian

    (Max Planck Institute of Colloids and Interfaces)

  • Nadezda V. Tarakina

    (Max Planck Institute of Colloids and Interfaces)

  • Jiayin Yuan

    (Stockholm University)

  • Markus Antonietti

    (Max Planck Institute of Colloids and Interfaces)

Abstract

Membrane-based water treatment processes offer possibility to alleviate the water scarcity dilemma in energy-efficient and sustainable ways, this has been exemplified in filtration membranes assembled from two-dimensional (2D) materials for water desalination purposes. Most representatives however tend to swell or disintegrate in a hydrated state, making precise ionic or molecular sieving a tough challenge. Here we report that the chemically robust 2D carbon nitride can be activated using aluminum polycations as pillars to modulate the interlayer spacing of the conjugated framework, the noncovalent interaction concomitantly affords a well-interlinked lamellar structure, to be carefully distinguished from random stacking patterns in conventional carbon nitride membranes. The conformally packed membrane is characterized by adaptive subnanochannel and structure integrity to allow excellent swelling resistance, and breaks permeability-selectivity trade-off limit in forward osmosis due to progressively regulated transport passage, achieving high salt rejection (>99.5%) and water flux (6 L m−2 h−1), along with tunable permeation behavior that enables water gating in acidic and alkaline environments. These findings position carbon nitride a rising building block to functionally expand the 2D membrane library for applications in water desalination and purification scenarios.

Suggested Citation

  • Yang Wang & Tingting Lian & Nadezda V. Tarakina & Jiayin Yuan & Markus Antonietti, 2022. "Lamellar carbon nitride membrane for enhanced ion sieving and water desalination," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35120-9
    DOI: 10.1038/s41467-022-35120-9
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    References listed on IDEAS

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    1. Jiani Qin & Jesús Barrio & Guiming Peng & Jonathan Tzadikov & Liel Abisdris & Michael Volokh & Menny Shalom, 2020. "Direct growth of uniform carbon nitride layers with extended optical absorption towards efficient water-splitting photoanodes," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    2. Yang Wang & Niannian Wu & Yan Wang & Huan Ma & Junxiang Zhang & Lili Xu & Mohamed K. Albolkany & Bo Liu, 2019. "Graphite phase carbon nitride based membrane for selective permeation," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    3. Liang Chen & Guosheng Shi & Jie Shen & Bingquan Peng & Bowu Zhang & Yuzhu Wang & Fenggang Bian & Jiajun Wang & Deyuan Li & Zhe Qian & Gang Xu & Gongping Liu & Jianrong Zeng & Lijuan Zhang & Yizhou Yan, 2017. "Ion sieving in graphene oxide membranes via cationic control of interlayer spacing," Nature, Nature, vol. 550(7676), pages 380-383, October.
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    1. Ri-Jian Mo & Shuang Chen & Li-Qiu Huang & Xin-Lei Ding & Saima Rafique & Xing-Hua Xia & Zhong-Qiu Li, 2024. "Regulating ion affinity and dehydration of metal-organic framework sub-nanochannels for high-precision ion separation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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