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Layered-rocksalt intergrown cathode for high-capacity zero-strain battery operation

Author

Listed:
  • Ning Li

    (Lawrence Berkeley National Laboratory)

  • Meiling Sun

    (Lawrence Berkeley National Laboratory)

  • Wang Hay Kan

    (Dongguan Neutron Science Center)

  • Zengqing Zhuo

    (Advanced Light Source, Lawrence Berkeley National Laboratory)

  • Sooyeon Hwang

    (Center for Functional Nanomaterials, Brookhaven National Laboratory)

  • Sara E. Renfrew

    (University of California)

  • Maxim Avdeev

    (Australian Nuclear Science and Technology Organisation (ANSTO))

  • Ashfia Huq

    (Neutron Scattering Science Directorate, Oak Ridge National Laboratory)

  • Bryan D. McCloskey

    (Lawrence Berkeley National Laboratory
    University of California)

  • Dong Su

    (Center for Functional Nanomaterials, Brookhaven National Laboratory)

  • Wanli Yang

    (Advanced Light Source, Lawrence Berkeley National Laboratory)

  • Wei Tong

    (Lawrence Berkeley National Laboratory)

Abstract

The dependence on lithium-ion batteries leads to a pressing demand for advanced cathode materials. We demonstrate a new concept of layered-rocksalt intergrown structure that harnesses the combined figures of merit from each phase, including high capacity of layered and rocksalt phases, good kinetics of layered oxide and structural advantage of rocksalt. Based on this concept, lithium nickel ruthenium oxide of a main layered structure (R $$\bar{3}$$ 3 ¯ m) with intergrown rocksalt (Fm $$\bar{3}$$ 3 ¯ m) is developed, which delivers a high capacity with good rate performance. The interwoven rocksalt structure successfully prevents the anisotropic structural change that is typical for layered oxide, enabling a nearly zero-strain operation upon high-capacity cycling. Furthermore, a design principle is successfully extrapolated and experimentally verified in a series of compositions. Here, we show the success of such layered-rocksalt intergrown structure exemplifies a new battery electrode design concept and opens up a vast space of compositions to develop high-performance intergrown cathode materials.

Suggested Citation

  • Ning Li & Meiling Sun & Wang Hay Kan & Zengqing Zhuo & Sooyeon Hwang & Sara E. Renfrew & Maxim Avdeev & Ashfia Huq & Bryan D. McCloskey & Dong Su & Wanli Yang & Wei Tong, 2021. "Layered-rocksalt intergrown cathode for high-capacity zero-strain battery operation," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-22527-z
    DOI: 10.1038/s41467-021-22527-z
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    Cited by:

    1. Ke Chen & Pallab Barai & Ozgenur Kahvecioglu & Lijun Wu & Krzysztof Z. Pupek & Mingyuan Ge & Lu Ma & Steven N. Ehrlich & Hui Zhong & Yimei Zhu & Venkat Srinivasan & Jianming Bai & Feng Wang, 2024. "Cobalt-free composite-structured cathodes with lithium-stoichiometry control for sustainable lithium-ion batteries," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Tianwei Cui & Jialiang Xu & Xin Wang & Longxiang Liu & Yuxuan Xiang & Hong Zhu & Xiang Li & Yongzhu Fu, 2024. "Highly reversible transition metal migration in superstructure-free Li-rich oxide boosting voltage stability and redox symmetry," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    3. Yi Pei & Qing Chen & Meiyu Wang & Pengjun Zhang & Qingyong Ren & Jingkai Qin & Penghao Xiao & Li Song & Yu Chen & Wen Yin & Xin Tong & Liang Zhen & Peng Wang & Cheng-Yan Xu, 2022. "A medium-entropy transition metal oxide cathode for high-capacity lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-13, December.

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