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Ce-mediated molecular tailoring on gigantic polyoxometalate {Mo132} into half-closed {Ce11Mo96} for high proton conduction

Author

Listed:
  • Xue-Xin Li

    (Northeast Normal University)

  • Cai-Hong Li

    (Northeast Normal University)

  • Ming-Jun Hou

    (Northeast Normal University)

  • Bo Zhu

    (Northeast Normal University)

  • Wei-Chao Chen

    (Northeast Normal University)

  • Chun-Yi Sun

    (Northeast Normal University)

  • Ye Yuan

    (Northeast Normal University)

  • Wei Guan

    (Northeast Normal University)

  • Chao Qin

    (Northeast Normal University)

  • Kui-Zhan Shao

    (Northeast Normal University)

  • Xin-Long Wang

    (Northeast Normal University)

  • Zhong-Min Su

    (Northeast Normal University
    Jilin University)

Abstract

Precise synthesis of polyoxometalates (POMs) is important for the fundamental understanding of the relationship between the structure and function of each building motif. However, it is a great challenge to realize the atomic-level tailoring of specific sites in POMs without altering the major framework. Herein, we report the case of Ce-mediated molecular tailoring on gigantic {Mo132}, which has a closed structural motif involving a never seen {Mo110} decamer. Such capped wheel {Mo132} undergoes a quasi-isomerism with known {Mo132} ball displaying different optical behaviors. Experiencing an ‘Inner-On-Outer’ binding process with the substituent of {Mo2} reactive sites in {Mo132}, the site-specific Ce ions drive the dissociation of {Mo2*} clipping sites and finally give rise to a predictable half-closed product {Ce11Mo96}. By virtue of the tailor-made open cavity, the {Ce11Mo96} achieves high proton conduction, nearly two orders of magnitude than that of {Mo132}. This work offers a significant step toward the controllable assembly of POM clusters through a Ce-mediated molecular tailoring process for desirable properties.

Suggested Citation

  • Xue-Xin Li & Cai-Hong Li & Ming-Jun Hou & Bo Zhu & Wei-Chao Chen & Chun-Yi Sun & Ye Yuan & Wei Guan & Chao Qin & Kui-Zhan Shao & Xin-Long Wang & Zhong-Min Su, 2023. "Ce-mediated molecular tailoring on gigantic polyoxometalate {Mo132} into half-closed {Ce11Mo96} for high proton conduction," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40685-0
    DOI: 10.1038/s41467-023-40685-0
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    References listed on IDEAS

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    1. Shubo Tian & Yi-Zhi Li & Man-Bo Li & Jinyun Yuan & Jinlong Yang & Zhikun Wu & Rongchao Jin, 2015. "Erratum: Structural isomerism in gold nanoparticles revealed by X-ray crystallography," Nature Communications, Nature, vol. 6(1), pages 1-1, December.
    2. Benbing Shi & Xiao Pang & Shunning Li & Hong Wu & Jianliang Shen & Xiaoyao Wang & Chunyang Fan & Li Cao & Tianhao Zhu & Ming Qiu & Zhuoyu Yin & Yan Kong & Yiqin Liu & Mingzheng Zhang & Yawei Liu & Fen, 2022. "Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Tianbo Liu & Ekkehard Diemann & Huilin Li & Andreas W. M. Dress & Achim Müller, 2003. "Self-assembly in aqueous solution of wheel-shaped Mo154 oxide clusters into vesicles," Nature, Nature, vol. 426(6962), pages 59-62, November.
    4. Shubo Tian & Yi-Zhi Li & Man-Bo Li & Jinyun Yuan & Jinlong Yang & Zhikun Wu & Rongchao Jin, 2015. "Structural isomerism in gold nanoparticles revealed by X-ray crystallography," Nature Communications, Nature, vol. 6(1), pages 1-7, December.
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