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Poly(heptazine imide) ligand exchange enables remarkable low catalyst loadings in heterogeneous metallaphotocatalysis

Author

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  • Liuzhuang Xing

    (School of Chemistry and Chemical Engineering, Chongqing University)

  • Qian Yang

    (School of Chemistry and Chemical Engineering, Chongqing University)

  • Chen Zhu

    (KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST))

  • Yilian Bai

    (School of Chemistry and Chemical Engineering, Chongqing University)

  • Yurong Tang

    (School of Chemistry and Chemical Engineering, Chongqing University)

  • Magnus Rueping

    (KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST))

  • Yunfei Cai

    (School of Chemistry and Chemical Engineering, Chongqing University)

Abstract

The development of heterogeneous metallaphotocatalysis is of great interest for sustainable organic synthesis. The rational design and controllable preparation of well-defined (site-isolated) metal/photo bifunctional solid catalysts to meet such goal remains a critical challenge. Herein, we demonstrate the incorporation of privileged homogeneous bipyridyl-based Ni-catalysts into highly ordered and crystalline potassium poly(heptazine imide) (K-PHI). A variety of PHI-supported cationic bipyridyl-based Ni-catalysts (LnNi-PHI) have been prepared and fully characterized by various techniques including NMR, ICP-OES, XPS, HAADF-STEM and XAS. The LnNi-PHI catalysts exhibit exceptional chemical stability and recyclability in diverse C−P, C−S, C−O and C−N cross-coupling reactions. The proximity and cooperativity effects in LnNi-PHI significantly enhances the photo/Ni dual catalytic activity, thus resulting in low catalyst loadings and high turnover numbers.

Suggested Citation

  • Liuzhuang Xing & Qian Yang & Chen Zhu & Yilian Bai & Yurong Tang & Magnus Rueping & Yunfei Cai, 2023. "Poly(heptazine imide) ligand exchange enables remarkable low catalyst loadings in heterogeneous metallaphotocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37113-8
    DOI: 10.1038/s41467-023-37113-8
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    References listed on IDEAS

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    2. Xiaolin Zhu & Yixiong Lin & Jovan San Martin & Yue Sun & Dian Zhu & Yong Yan, 2019. "Lead halide perovskites for photocatalytic organic synthesis," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    3. Sarah Z. Tasker & Eric A. Standley & Timothy F. Jamison, 2014. "Erratum: Recent advances in homogeneous nickel catalysis," Nature, Nature, vol. 510(7503), pages 176-176, June.
    4. Hong Bin Yang & Sung-Fu Hung & Song Liu & Kaidi Yuan & Shu Miao & Liping Zhang & Xiang Huang & Hsin-Yi Wang & Weizheng Cai & Rong Chen & Jiajian Gao & Xiaofeng Yang & Wei Chen & Yanqiang Huang & Hao M, 2018. "Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction," Nature Energy, Nature, vol. 3(2), pages 140-147, February.
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    Cited by:

    1. Taoda Shi & Tianyuan Zhang & Jiying Yang & Yukai Li & Jirong Shu & Jingyu Zhao & Mengchu Zhang & Dan Zhang & Wenhao Hu, 2023. "Bifunctionality of dirhodium tetracarboxylates in metallaphotocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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