IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-33000-w.html
   My bibliography  Save this article

Enhanced oxygen evolution over dual corner-shared cobalt tetrahedra

Author

Listed:
  • Yubo Chen

    (Nanyang Technological University
    The Cambridge Centre for Advanced Research and Education in Singapore
    Nanyang Technological University
    Energy Research Institute @ Nanyang Technological University)

  • Joon Kyo Seo

    (University of California San Diego
    University of California San Diego
    Korea Institute of Energy Research)

  • Yuanmiao Sun

    (Nanyang Technological University)

  • Thomas A. Wynn

    (University of California San Diego
    University of California San Diego)

  • Marco Olguin

    (University of California San Diego
    University of California San Diego)

  • Minghao Zhang

    (University of California San Diego
    University of California San Diego)

  • Jingxian Wang

    (Nanyang Technological University)

  • Shibo Xi

    (Institute of Chemical and Engineering Sciences, A*STAR)

  • Yonghua Du

    (Institute of Chemical and Engineering Sciences, A*STAR)

  • Kaidi Yuan

    (National University of Singapore)

  • Wei Chen

    (National University of Singapore)

  • Adrian C. Fisher

    (The Cambridge Centre for Advanced Research and Education in Singapore
    University of Cambridge)

  • Maoyu Wang

    (Oregon State University)

  • Zhenxing Feng

    (Oregon State University)

  • Jose Gracia

    (MagnetoCat SL, General Polavieja 9 3I)

  • Li Huang

    (Chinese Academy of Science)

  • Shixuan Du

    (Chinese Academy of Science)

  • Hong-Jun Gao

    (Chinese Academy of Science)

  • Ying Shirley Meng

    (University of California San Diego
    University of California San Diego
    University of Chicago)

  • Zhichuan J. Xu

    (Nanyang Technological University
    The Cambridge Centre for Advanced Research and Education in Singapore
    Nanyang Technological University
    Energy Research Institute @ Nanyang Technological University)

Abstract

Developing efficient catalysts is of paramount importance to oxygen evolution, a sluggish anodic reaction that provides essential electrons and protons for various electrochemical processes, such as hydrogen generation. Here, we report that the oxygen evolution reaction (OER) can be efficiently catalyzed by cobalt tetrahedra, which are stabilized over the surface of a Swedenborgite-type YBCo4O7 material. We reveal that the surface of YBaCo4O7 possesses strong resilience towards structural amorphization during OER, which originates from its distinctive structural evolution toward electrochemical oxidation. The bulk of YBaCo4O7 composes of corner-sharing only CoO4 tetrahedra, which can flexibly alter their positions to accommodate the insertion of interstitial oxygen ions and mediate the stress during the electrochemical oxidation. The density functional theory calculations demonstrate that the OER is efficiently catalyzed by a binuclear active site of dual corner-shared cobalt tetrahedra, which have a coordination number switching between 3 and 4 during the reaction. We expect that the reported active structural motif of dual corner-shared cobalt tetrahedra in this study could enable further development of compounds for catalyzing the OER.

Suggested Citation

  • Yubo Chen & Joon Kyo Seo & Yuanmiao Sun & Thomas A. Wynn & Marco Olguin & Minghao Zhang & Jingxian Wang & Shibo Xi & Yonghua Du & Kaidi Yuan & Wei Chen & Adrian C. Fisher & Maoyu Wang & Zhenxing Feng , 2022. "Enhanced oxygen evolution over dual corner-shared cobalt tetrahedra," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33000-w
    DOI: 10.1038/s41467-022-33000-w
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-33000-w
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-022-33000-w?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Hyunah Kim & Jimin Park & Inchul Park & Kyoungsuk Jin & Sung Eun Jerng & Sun Hee Kim & Ki Tae Nam & Kisuk Kang, 2015. "Coordination tuning of cobalt phosphates towards efficient water oxidation catalyst," Nature Communications, Nature, vol. 6(1), pages 1-11, November.
    2. Mihail Bogojeski & Leslie Vogt-Maranto & Mark E. Tuckerman & Klaus-Robert Müller & Kieron Burke, 2020. "Quantum chemical accuracy from density functional approximations via machine learning," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    3. Arno Bergmann & Elias Martinez-Moreno & Detre Teschner & Petko Chernev & Manuel Gliech & Jorge Ferreira de Araújo & Tobias Reier & Holger Dau & Peter Strasser, 2015. "Reversible amorphization and the catalytically active state of crystalline Co3O4 during oxygen evolution," Nature Communications, Nature, vol. 6(1), pages 1-9, December.
    4. Yubo Chen & Haiyan Li & Jingxian Wang & Yonghua Du & Shibo Xi & Yuanmiao Sun & Matthew Sherburne & Joel W. Ager & Adrian C. Fisher & Zhichuan J. Xu, 2019. "Exceptionally active iridium evolved from a pseudo-cubic perovskite for oxygen evolution in acid," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    5. Shenlong Zhao & Yun Wang & Juncai Dong & Chun-Ting He & Huajie Yin & Pengfei An & Kun Zhao & Xiaofei Zhang & Chao Gao & Lijuan Zhang & Jiawei Lv & Jinxin Wang & Jianqi Zhang & Abdul Muqsit Khattak & N, 2016. "Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution," Nature Energy, Nature, vol. 1(12), pages 1-10, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Shujiao Yang & Kaihang Yue & Xiaohan Liu & Sisi Li & Haoquan Zheng & Ya Yan & Rui Cao & Wei Zhang, 2024. "Electrocatalytic water oxidation with manganese phosphates," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shouwei Zuo & Zhi-Peng Wu & Deting Xu & Rafia Ahmad & Lirong Zheng & Jing Zhang & Lina Zhao & Wenhuan Huang & Hassan Al Qahtani & Yu Han & Luigi Cavallo & Huabin Zhang, 2024. "Local compressive strain-induced anti-corrosion over isolated Ru-decorated Co3O4 for efficient acidic oxygen evolution," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    2. Che Lah, Nurul Akmal, 2021. "Late transition metal nanocomplexes: Applications for renewable energy conversion and storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    3. Felix T. Haase & Arno Bergmann & Travis E. Jones & Janis Timoshenko & Antonia Herzog & Hyo Sang Jeon & Clara Rettenmaier & Beatriz Roldan Cuenya, 2022. "Size effects and active state formation of cobalt oxide nanoparticles during the oxygen evolution reaction," Nature Energy, Nature, vol. 7(8), pages 765-773, August.
    4. Lili Zhang & Ning Zhang & Huishan Shang & Zhiyi Sun & Zihao Wei & Jingtao Wang & Yuanting Lei & Xiaochen Wang & Dan Wang & Yafei Zhao & Zhongti Sun & Fang Zhang & Xu Xiang & Bing Zhang & Wenxing Chen, 2024. "High-density asymmetric iron dual-atom sites for efficient and stable electrochemical water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    5. Yun Fan & Yu Shen & Jia Zhang & Xinglong Zhang & Zeqi Zhang & Hongfeng Li & Yong Peng & Jiena Weng & Ruijie Xie & Wenlei Zhang & Yu Han & Yawen Xiao & Suoying Zhang & Bing Zheng & Hao-Li Zhang & Sheng, 2024. "Wedging crystals to fabricate crystalline framework nanosheets via mechanochemistry," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    6. Zilong Wu & Xiangyu Liu & Haijing Li & Zhiyi Sun & Maosheng Cao & Zezhou Li & Chaohe Fang & Jihan Zhou & Chuanbao Cao & Juncai Dong & Shenlong Zhao & Zhuo Chen, 2023. "A semiconductor-electrocatalyst nano interface constructed for successive photoelectrochemical water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    7. Qianbao Wu & Junwu Liang & Mengjun Xiao & Chang Long & Lei Li & Zhenhua Zeng & Andraž Mavrič & Xia Zheng & Jing Zhu & Hai-Wei Liang & Hongfei Liu & Matjaz Valant & Wei Wang & Zhengxing Lv & Jiong Li &, 2023. "Non-covalent ligand-oxide interaction promotes oxygen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    8. Shangheng Liu & Shize Geng & Ling Li & Ying Zhang & Guomian Ren & Bolong Huang & Zhiwei Hu & Jyh-Fu Lee & Yu-Hong Lai & Ying-Hao Chu & Yong Xu & Qi Shao & Xiaoqing Huang, 2022. "A top-down strategy for amorphization of hydroxyl compounds for electrocatalytic oxygen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    9. Xinyu Ping & Yongduo Liu & Lixia Zheng & Yang Song & Lin Guo & Siguo Chen & Zidong Wei, 2024. "Locking the lattice oxygen in RuO2 to stabilize highly active Ru sites in acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    10. Subhabrata Mukhopadhyay & Muhammad Saad Naeem & G. Shiva Shanker & Arnab Ghatak & Alagar R. Kottaichamy & Ran Shimoni & Liat Avram & Itamar Liberman & Rotem Balilty & Raya Ifraemov & Illya Rozenberg &, 2024. "Local CO2 reservoir layer promotes rapid and selective electrochemical CO2 reduction," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    11. Pengcheng Ye & Keqing Fang & Haiyan Wang & Yahao Wang & Hao Huang & Chenbin Mo & Jiqiang Ning & Yong Hu, 2024. "Lattice oxygen activation and local electric field enhancement by co-doping Fe and F in CoO nanoneedle arrays for industrial electrocatalytic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    12. Gang Zhou & Peifang Wang & Bin Hu & Xinyue Shen & Chongchong Liu & Weixiang Tao & Peilin Huang & Lizhe Liu, 2022. "Spin-related symmetry breaking induced by half-disordered hybridization in BixEr2-xRu2O7 pyrochlores for acidic oxygen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    13. Hui Su & Chenyu Yang & Meihuan Liu & Xu Zhang & Wanlin Zhou & Yuhao Zhang & Kun Zheng & Shixun Lian & Qinghua Liu, 2024. "Tensile straining of iridium sites in manganese oxides for proton-exchange membrane water electrolysers," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    14. Lingxin Luo & Lingxiang Hou & Xueping Cui & Pengxin Zhan & Ping He & Chuying Dai & Ruian Li & Jichen Dong & Ye Zou & Guoming Liu & Yanpeng Liu & Jian Zheng, 2024. "Self-condensation-assisted chemical vapour deposition growth of atomically two-dimensional MOF single-crystals," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    15. María Retuerto & Laura Pascual & Jorge Torrero & Mohamed Abdel Salam & Álvaro Tolosana-Moranchel & Diego Gianolio & Pilar Ferrer & Paula Kayser & Vincent Wilke & Svenja Stiber & Verónica Celorrio & Mo, 2022. "Highly active and stable OER electrocatalysts derived from Sr2MIrO6 for proton exchange membrane water electrolyzers," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    16. Yuanming Bai & Leslie Vogt-Maranto & Mark E. Tuckerman & William J. Glover, 2022. "Machine learning the Hohenberg-Kohn map for molecular excited states," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    17. Yang, Gaoqiang & Mo, Jingke & Kang, Zhenye & Dohrmann, Yeshi & List, Frederick A. & Green, Johney B. & Babu, Sudarsanam S. & Zhang, Feng-Yuan, 2018. "Fully printed and integrated electrolyzer cells with additive manufacturing for high-efficiency water splitting," Applied Energy, Elsevier, vol. 215(C), pages 202-210.
    18. Jaianth Vijayakumar & Tatiana M. Savchenko & David M. Bracher & Gunnar Lumbeeck & Armand Béché & Jo Verbeeck & Štefan Vajda & Frithjof Nolting & C.A.F. Vaz & Armin Kleibert, 2023. "Absence of a pressure gap and atomistic mechanism of the oxidation of pure Co nanoparticles," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    19. Shiyi Chen & Shishi Zhang & Lei Guo & Lun Pan & Chengxiang Shi & Xiangwen Zhang & Zhen-Feng Huang & Guidong Yang & Ji-Jun Zou, 2023. "Reconstructed Ir‒O‒Mo species with strong Brønsted acidity for acidic water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    20. Dmitry Galyamin & Jorge Torrero & Isabel Rodríguez & Manuel J. Kolb & Pilar Ferrer & Laura Pascual & Mohamed Abdel Salam & Diego Gianolio & Verónica Celorrio & Mohamed Mokhtar & Daniel Garcia Sanchez , 2023. "Active and durable R2MnRuO7 pyrochlores with low Ru content for acidic oxygen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33000-w. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.