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A recyclable biomass electrolyte towards green zinc-ion batteries

Author

Listed:
  • Hongyu Lu

    (Tsinghua University
    Harbin Institute of Technology)

  • Jisong Hu

    (Huazhong University of Science and Technology)

  • Xijun Wei

    (Tsinghua University)

  • Kaiqi Zhang

    (Harbin Institute of Technology (Weihai))

  • Xiao Xiao

    (Tsinghua University)

  • Jingxin Zhao

    (The Hong Kong Polytechnic University, Hung Hom)

  • Qiang Hu

    (University of Electronic Science and Technology of China)

  • Jing Yu

    (School of Physics, Harbin Institute of Technology)

  • Guangmin Zhou

    (Tsinghua University)

  • Bingang Xu

    (The Hong Kong Polytechnic University, Hung Hom)

Abstract

The operation of traditional aqueous-electrolyte zinc-ion batteries is adversely affected by the uncontrollable growth of zinc dendrites and the occurrence of side reactions. These problems can be avoided by the development of functional hydrogel electrolytes as replacements for aqueous electrolytes. However, the mechanism by which most hydrogel electrolytes inhibit the growth of zinc dendrites on a zinc anode has not been investigated in detail, and there is a lack of a large-scale recovery method for mainstream hydrogel electrolytes. In this paper, we describe the development of a recyclable and biodegradable hydrogel electrolyte based on natural biomaterials, namely chitosan and polyaspartic acid. The distinctive adsorptivity and inducibility of chitosan and polyaspartic acid in the hydrogel electrolyte triggers a double coupling network and an associated synergistic inhibition mechanism, thereby effectively inhibiting the side reactions on the zinc anode. In addition, this hydrogel electrolyte played a crucial role in an aqueous acid-based Zinc/MnO2 battery, by maintaining its interior two-electron redox reaction and inhibiting the formation of zinc dendrites. Furthermore, the sustainable biomass-based hydrogel electrolyte is biodegradable, and could be recovered from the Zinc/MnO2 battery for subsequent recycling.

Suggested Citation

  • Hongyu Lu & Jisong Hu & Xijun Wei & Kaiqi Zhang & Xiao Xiao & Jingxin Zhao & Qiang Hu & Jing Yu & Guangmin Zhou & Bingang Xu, 2023. "A recyclable biomass electrolyte towards green zinc-ion batteries," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40178-0
    DOI: 10.1038/s41467-023-40178-0
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    1. Chongyin Yang & Jiale Xia & Chunyu Cui & Travis P. Pollard & Jenel Vatamanu & Antonio Faraone & Joseph A. Dura & Madhusudan Tyagi & Alex Kattan & Elijah Thimsen & Jijian Xu & Wentao Song & Enyuan Hu &, 2023. "All-temperature zinc batteries with high-entropy aqueous electrolyte," Nature Sustainability, Nature, vol. 6(3), pages 325-335, March.
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    3. Kwan Woo Nam & Sarah S. Park & Roberto dos Reis & Vinayak P. Dravid & Heejin Kim & Chad A. Mirkin & J. Fraser Stoddart, 2019. "Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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