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Ultrathin bismuth nanosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate

Author

Listed:
  • Na Han

    (Soochow University)

  • Yu Wang

    (Nanjing Normal University)

  • Hui Yang

    (Soochow University)

  • Jun Deng

    (Soochow University)

  • Jinghua Wu

    (Soochow University)

  • Yafei Li

    (Nanjing Normal University)

  • Yanguang Li

    (Soochow University)

Abstract

Electrocatalytic carbon dioxide reduction to formate is desirable but challenging. Current attention is mostly focused on tin-based materials, which, unfortunately, often suffer from limited Faradaic efficiency. The potential of bismuth in carbon dioxide reduction has been suggested but remained understudied. Here, we report that ultrathin bismuth nanosheets are prepared from the in situ topotactic transformation of bismuth oxyiodide nanosheets. They process single crystallinity and enlarged surface areas. Such an advantageous nanostructure affords the material with excellent electrocatalytic performance for carbon dioxide reduction to formate. High selectivity (~100%) and large current density are measured over a broad potential, as well as excellent durability for >10 h. Its selectivity for formate is also understood by density functional theory calculations. In addition, bismuth nanosheets were coupled with an iridium-based oxygen evolution electrocatalyst to achieve efficient full-cell electrolysis. When powered by two AA-size alkaline batteries, the full cell exhibits impressive Faradaic efficiency and electricity-to-formate conversion efficiency.

Suggested Citation

  • Na Han & Yu Wang & Hui Yang & Jun Deng & Jinghua Wu & Yafei Li & Yanguang Li, 2018. "Ultrathin bismuth nanosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-03712-z
    DOI: 10.1038/s41467-018-03712-z
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    Cited by:

    1. Bohua Ren & Guobin Wen & Rui Gao & Dan Luo & Zhen Zhang & Weibin Qiu & Qianyi Ma & Xin Wang & Yi Cui & Luis Ricardez–Sandoval & Aiping Yu & Zhongwei Chen, 2022. "Nano-crumples induced Sn-Bi bimetallic interface pattern with moderate electron bank for highly efficient CO2 electroreduction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Junyuan Duan & Tianyang Liu & Yinghe Zhao & Ruoou Yang & Yang Zhao & Wenbin Wang & Youwen Liu & Huiqiao Li & Yafei Li & Tianyou Zhai, 2022. "Active and conductive layer stacked superlattices for highly selective CO2 electroreduction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Young-Jin Ko & Jun-Yong Kim & Woong Hee Lee & Min Gyu Kim & Tae-Yeon Seong & Jongkil Park & YeonJoo Jeong & Byoung Koun Min & Wook-Seong Lee & Dong Ki Lee & Hyung-Suk Oh, 2022. "Exploring dopant effects in stannic oxide nanoparticles for CO2 electro-reduction to formate," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Jiexin Zhu & Jiantao Li & Ruihu Lu & Ruohan Yu & Shiyong Zhao & Chengbo Li & Lei Lv & Lixue Xia & Xingbao Chen & Wenwei Cai & Jiashen Meng & Wei Zhang & Xuelei Pan & Xufeng Hong & Yuhang Dai & Yu Mao , 2023. "Surface passivation for highly active, selective, stable, and scalable CO2 electroreduction," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    5. Bilawal Khan & M. Bilal Faheem & Karthik Peramaiah & Jinlan Nie & Hao Huang & Zhongxiao Li & Chen Liu & Kuo-Wei Huang & Jr-Hau He, 2024. "Unassisted photoelectrochemical CO2-to-liquid fuel splitting over 12% solar conversion efficiency," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    6. Lei Chen & Junmei Chen & Weiwei Fu & Jiayi Chen & Di Wang & Yukun Xiao & Shibo Xi & Yongfei Ji & Lei Wang, 2024. "Energy-efficient CO(2) conversion to multicarbon products at high rates on CuGa bimetallic catalyst," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    7. An, Xiaowei & Li, Shasha & Hao, Xiaoqiong & Xie, Zhengkun & Du, Xiao & Wang, Zhongde & Hao, Xiaogang & Abudula, Abuliti & Guan, Guoqing, 2021. "Common strategies for improving the performances of tin and bismuth-based catalysts in the electrocatalytic reduction of CO2 to formic acid/formate," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    8. Cong Liu & Bingbao Mei & Zhaoping Shi & Zheng Jiang & Junjie Ge & Wei Xing & Ping Song & Weilin Xu, 2024. "Operando formation of highly efficient electrocatalysts induced by heteroatom leaching," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    9. Subhabrata Mukhopadhyay & Muhammad Saad Naeem & G. Shiva Shanker & Arnab Ghatak & Alagar R. Kottaichamy & Ran Shimoni & Liat Avram & Itamar Liberman & Rotem Balilty & Raya Ifraemov & Illya Rozenberg &, 2024. "Local CO2 reservoir layer promotes rapid and selective electrochemical CO2 reduction," Nature Communications, Nature, vol. 15(1), pages 1-14, December.

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