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Solid-state cooling by elastocaloric polymer with uniform chain-lengths

Author

Listed:
  • Shixian Zhang

    (Wuhan University of Technology)

  • Quanling Yang

    (Wuhan University of Technology)

  • Chenjian Li

    (Wuhan University of Technology)

  • Yuheng Fu

    (Wuhan University of Technology)

  • Huaqing Zhang

    (Wuhan University of Technology)

  • Zhiwei Ye

    (Wuhan University of Technology)

  • Xingnan Zhou

    (Wuhan University of Technology)

  • Qi Li

    (Tsinghua University)

  • Tao Wang

    (Wuhan University of Technology)

  • Shan Wang

    (Wuhan University of Technology)

  • Wenqing Zhang

    (Wuhan Optics Valley United Property Rights Exchange)

  • Chuanxi Xiong

    (Wuhan University of Technology)

  • Qing Wang

    (The Pennsylvania State University)

Abstract

Although the elastocaloric effect was found in natural rubber as early as 160 years ago, commercial elastocaloric refrigeration based on polymer elastomers has stagnated owing to their deficient elastocaloric effects and large extension ratios. Herein, we demonstrate that polymer elastomers with uniform molecular chain-lengths exhibit enormous elastocaloric effects through reversible conformational changes. An adiabatic temperature change of −15.3 K and an isothermal entropy change of 145 J kg−1 K−1, obtained from poly(styrene-b-ethylene-co-butylene-b-styrene) near room temperature, exceed those of previously reported elastocaloric polymers. A rotary-motion cooling device is tailored to high-strains characteristics of rubbers, which effectively discharges the cooling energy of polymer elastomers. Our work provides a strategy for the enhancement of elastocaloric effects and could promote the commercialization of solid-state cooling devices based on polymer elastomers.

Suggested Citation

  • Shixian Zhang & Quanling Yang & Chenjian Li & Yuheng Fu & Huaqing Zhang & Zhiwei Ye & Xingnan Zhou & Qi Li & Tao Wang & Shan Wang & Wenqing Zhang & Chuanxi Xiong & Qing Wang, 2022. "Solid-state cooling by elastocaloric polymer with uniform chain-lengths," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-021-27746-y
    DOI: 10.1038/s41467-021-27746-y
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    References listed on IDEAS

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    1. Bing Li & Yukinobu Kawakita & Seiko Ohira-Kawamura & Takeshi Sugahara & Hui Wang & Jingfan Wang & Yanna Chen & Saori I. Kawaguchi & Shogo Kawaguchi & Koji Ohara & Kuo Li & Dehong Yu & Richard Mole & T, 2019. "Colossal barocaloric effects in plastic crystals," Nature, Nature, vol. 567(7749), pages 506-510, March.
    2. Klinar, K. & Kitanovski, A., 2020. "Thermal control elements for caloric energy conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
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    Cited by:

    1. Sijia Yao & Pengfei Dang & Yiming Li & Yao Wang & Xi Zhang & Ye Liu & Suxin Qian & Dezhen Xue & Ya-Ling He, 2024. "Efficient roller-driven elastocaloric refrigerator," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Xueshi Li & Peng Hua & Qingping Sun, 2023. "Continuous and efficient elastocaloric air cooling by coil-bending," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Klara Lünser & Eyüp Kavak & Kübra Gürpinar & Baris Emre & Orhan Atakol & Enric Stern-Taulats & Marcel Porta & Antoni Planes & Pol Lloveras & Josep-Lluís Tamarit & Lluís Mañosa, 2024. "Elastocaloric, barocaloric and magnetocaloric effects in spin crossover polymer composite films," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Shixian Zhang & Yuheng Fu & Xinxing Nie & Chenjian Li & Youshuang Zhou & Yaqi Wang & Juan Yi & Wenlai Xia & Yiheng Song & Qi Li & Chuanxi Xiong & Suxin Qian & Quanling Yang & Qing Wang, 2024. "Shearo-caloric effect enhances elastocaloric responses in polymer composites for solid-state cooling," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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