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Recycling lead and transparent conductors from perovskite solar modules

Author

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  • Bo Chen

    (University of North Carolina at Chapel Hill)

  • Chengbin Fei

    (University of North Carolina at Chapel Hill)

  • Shangshang Chen

    (University of North Carolina at Chapel Hill)

  • Hangyu Gu

    (University of North Carolina at Chapel Hill)

  • Xun Xiao

    (University of North Carolina at Chapel Hill)

  • Jinsong Huang

    (University of North Carolina at Chapel Hill)

Abstract

Perovskite photovoltaics are gaining increasing common ground to partner with or compete with silicon photovoltaics to reduce cost of solar energy. However, a cost-effective waste management for toxic lead (Pb), which might determine the fate of this technology, has not been developed yet. Here, we report an end-of-life material management for perovskite solar modules to recycle toxic lead and valuable transparent conductors to protect the environment and create dramatic economic benefits from recycled materials. Lead is separated from decommissioned modules by weakly acidic cation exchange resin, which could be released as soluble Pb(NO3)2 followed by precipitation as PbI2 for reuse, with a recycling efficiency of 99.2%. Thermal delamination disassembles the encapsulated modules with intact transparent conductors and cover glasses. The refabricated devices based on recycled lead iodide and recycled transparent conductors show comparable performance as devices based on fresh raw materials. Cost analysis shows this recycling technology is economically attractive.

Suggested Citation

  • Bo Chen & Chengbin Fei & Shangshang Chen & Hangyu Gu & Xun Xiao & Jinsong Huang, 2021. "Recycling lead and transparent conductors from perovskite solar modules," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26121-1
    DOI: 10.1038/s41467-021-26121-1
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    1. So Yeon Park & Ji-Sang Park & Byeong Jo Kim & Hyemin Lee & Aron Walsh & Kai Zhu & Dong Hoe Kim & Hyun Suk Jung, 2020. "Sustainable lead management in halide perovskite solar cells," Nature Sustainability, Nature, vol. 3(12), pages 1044-1051, December.
    2. Shangshang Chen & Yehao Deng & Hangyu Gu & Shuang Xu & Shen Wang & Zhenhua Yu & Volker Blum & Jinsong Huang, 2020. "Trapping lead in perovskite solar modules with abundant and low-cost cation-exchange resins," Nature Energy, Nature, vol. 5(12), pages 1003-1011, December.
    3. Garvin A. Heath & Timothy J. Silverman & Michael Kempe & Michael Deceglie & Dwarakanath Ravikumar & Timothy Remo & Hao Cui & Parikhit Sinha & Cara Libby & Stephanie Shaw & Keiichi Komoto & Karsten Wam, 2020. "Research and development priorities for silicon photovoltaic module recycling to support a circular economy," Nature Energy, Nature, vol. 5(7), pages 502-510, July.
    4. Andy Extance, 2019. "The reality behind solar power’s next star material," Nature, Nature, vol. 570(7762), pages 429-432, June.
    5. Deng, Rong & Chang, Nathan L. & Ouyang, Zi & Chong, Chee Mun, 2019. "A techno-economic review of silicon photovoltaic module recycling," Renewable and Sustainable Energy Reviews, Elsevier, vol. 109(C), pages 532-550.
    6. Eui Hyuk Jung & Nam Joong Jeon & Eun Young Park & Chan Su Moon & Tae Joo Shin & Tae-Youl Yang & Jun Hong Noh & Jangwon Seo, 2019. "Efficient, stable and scalable perovskite solar cells using poly(3-hexylthiophene)," Nature, Nature, vol. 567(7749), pages 511-515, March.
    7. Xun Li & Fei Zhang & Haiying He & Joseph J. Berry & Kai Zhu & Tao Xu, 2020. "On-device lead sequestration for perovskite solar cells," Nature, Nature, vol. 578(7796), pages 555-558, February.
    8. Byeong Jo Kim & Dong Hoe Kim & Seung Lee Kwon & So Yeon Park & Zhen Li & Kai Zhu & Hyun Suk Jung, 2016. "Selective dissolution of halide perovskites as a step towards recycling solar cells," Nature Communications, Nature, vol. 7(1), pages 1-9, September.
    9. Shangshang Chen & Yehao Deng & Xun Xiao & Shuang Xu & Peter N. Rudd & Jinsong Huang, 2021. "Preventing lead leakage with built-in resin layers for sustainable perovskite solar cells," Nature Sustainability, Nature, vol. 4(7), pages 636-643, July.
    10. Yan Jiang & Longbin Qiu & Emilio J. Juarez-Perez & Luis K. Ono & Zhanhao Hu & Zonghao Liu & Zhifang Wu & Lingqiang Meng & Qijing Wang & Yabing Qi, 2019. "Reduction of lead leakage from damaged lead halide perovskite solar modules using self-healing polymer-based encapsulation," Nature Energy, Nature, vol. 4(7), pages 585-593, July.
    11. Xianyuan Jiang & Fei Wang & Qi Wei & Hansheng Li & Yuequn Shang & Wenjia Zhou & Cheng Wang & Peihong Cheng & Qi Chen & Liwei Chen & Zhijun Ning, 2020. "Ultra-high open-circuit voltage of tin perovskite solar cells via an electron transporting layer design," Nature Communications, Nature, vol. 11(1), pages 1-7, December.
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    3. Huaiqing Luo & Pengwei Li & Junjie Ma & Xue Li & He Zhu & Yajie Cheng & Qin Li & Qun Xu & Yiqiang Zhang & Yanlin Song, 2023. "Bioinspired “cage traps” for closed-loop lead management of perovskite solar cells under real-world contamination assessment," Nature Communications, Nature, vol. 14(1), pages 1-14, December.

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