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Multiple Melting Temperatures in Glass-Forming Melts

Author

Listed:
  • Robert F. Tournier

    (UPR 3228 Centre National de la Recherche Scientifique, Laboratoire National des Champs Magnétiques Intenses, European Magnetic Field Laboratory, Institut National des Sciences Appliquées de Toulouse, Université Grenoble Alpes, F-31400 Toulouse, France)

  • Michael I. Ojovan

    (Department of Materials, Imperial College London, London SW7 2AZ, UK
    Department of Radiochemistry, Lomonosov Moscow State University, 119991 Moscow, Russia)

Abstract

All materials are vitrified by fast quenching even monoatomic substances. Second melting temperatures accompanied by weak exothermic or endothermic heat are often observed at T n+ after remelting them above the equilibrium thermodynamic melting transition at T m . These temperatures, T n+ , are due to the breaking of bonds (configurons formation) or antibonds depending on the thermal history, which is explained by using a nonclassical nucleation equation. Their multiple existence in monoatomic elements is now demonstrated by molecular dynamics simulations and still predicted. Proposed equations show that crystallization enthalpy is reduced at the temperature T x due to new vitrification of noncrystallized parts and their melting at T n+ . These glassy parts, being equal above T x to singular values or to their sum, are melted at various temperatures T n+ and attain 100% in Cu 46 Zr 46 Al 8 and 86.7% in bismuth. These first order transitions at T n+ are either reversible or irreversible, depending on the formation of super atoms, either solid or liquid.

Suggested Citation

  • Robert F. Tournier & Michael I. Ojovan, 2022. "Multiple Melting Temperatures in Glass-Forming Melts," Sustainability, MDPI, vol. 14(4), pages 1-18, February.
    • Handle: RePEc:gam:jsusta:v:14:y:2022:i:4:p:2351-:d:752963
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    References listed on IDEAS

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