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Intermittent cluster dynamics and temporal fractional diffusion in a bulk metallic glass

Author

Listed:
  • Birte Riechers

    (Federal Institute of Materials Research and Testing (BAM))

  • Amlan Das

    (University of Illinois at Urbana-Champaign
    Cornell University)

  • Eric Dufresne

    (Argonne National Laboratory)

  • Peter M. Derlet

    (Paul-Scherrer-Institute)

  • Robert Maaß

    (Federal Institute of Materials Research and Testing (BAM)
    University of Illinois at Urbana-Champaign
    Technical University of Munich)

Abstract

Glassy solids evolve towards lower-energy structural states by physical aging. This can be characterized by structural relaxation times, the assessment of which is essential for understanding the glass’ time-dependent property changes. Conducted over short times, a continuous increase of relaxation times with time is seen, suggesting a time-dependent dissipative transport mechanism. By focusing on micro-structural rearrangements at the atomic-scale, we demonstrate the emergence of sub-diffusive anomalous transport and therefore temporal fractional diffusion in a metallic glass, which we track via coherent x-ray scattering conducted over more than 300,000 s. At the longest probed decorrelation times, a transition from classical stretched exponential to a power-law behavior occurs, which in concert with atomistic simulations reveals collective and intermittent atomic motion. Our observations give a physical basis for classical stretched exponential relaxation behavior, uncover a new power-law governed collective transport regime for metallic glasses at long and practically relevant time-scales, and demonstrate a rich and highly non-monotonous aging response in a glassy solid, thereby challenging the common framework of homogeneous aging and atomic scale diffusion.

Suggested Citation

  • Birte Riechers & Amlan Das & Eric Dufresne & Peter M. Derlet & Robert Maaß, 2024. "Intermittent cluster dynamics and temporal fractional diffusion in a bulk metallic glass," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50758-3
    DOI: 10.1038/s41467-024-50758-3
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    References listed on IDEAS

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    2. Amlan Das & Peter M. Derlet & Chaoyang Liu & Eric M. Dufresne & Robert Maaß, 2019. "Stress breaks universal aging behavior in a metallic glass," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
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