IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v12y2020i4p1619-d323472.html
   My bibliography  Save this article

Absorptive Desulfurization of Model Biogas Stream Using Choline Chloride-Based Deep Eutectic Solvents

Author

Listed:
  • Edyta Słupek

    (Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, G. Narutowicza St. 11/12, 80–233 Gdańsk, Poland)

  • Patrycja Makoś

    (Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, G. Narutowicza St. 11/12, 80–233 Gdańsk, Poland)

Abstract

The paper presents a synthesis of deep eutectic solvents (DESs) based on choline chloride (ChCl) as hydrogen bond acceptor and phenol (Ph), glycol ethylene (EG), and levulinic acid (Lev) as hydrogen bond donors in 1:2 molar ratio. DESs were successfully used as absorption solvents for removal of dimethyl disulfide (DMDS) from model biogas steam. Several parameters affecting the absorption capacity and absorption rate have been optimized including kinds of DES, temperature, the volume of absorbent, model biogas flow rate, and initial concentration of DMDS. Furthermore, reusability and regeneration of DESs by means of adsorption and nitrogen barbotage followed by the mechanism of absorptive desulfurization by means of density functional theory (DFT) as well as FT-IR analysis were investigated. Experimental results indicate that the most promising DES for biogas purification is ChCl:Ph, due to high absorption capacity, relatively long absorption rate, and easy regeneration. The research on the absorption mechanism revealed that van der Waal interaction is the main driving force for DMDS removal from model biogas.

Suggested Citation

  • Edyta Słupek & Patrycja Makoś, 2020. "Absorptive Desulfurization of Model Biogas Stream Using Choline Chloride-Based Deep Eutectic Solvents," Sustainability, MDPI, vol. 12(4), pages 1-16, February.
    • Handle: RePEc:gam:jsusta:v:12:y:2020:i:4:p:1619-:d:323472
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/12/4/1619/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/2071-1050/12/4/1619/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Tippayawong, N. & Thanompongchart, P., 2010. "Biogas quality upgrade by simultaneous removal of CO2 and H2S in a packed column reactor," Energy, Elsevier, vol. 35(12), pages 4531-4535.
    2. Sun, Qie & Li, Hailong & Yan, Jinying & Liu, Longcheng & Yu, Zhixin & Yu, Xinhai, 2015. "Selection of appropriate biogas upgrading technology-a review of biogas cleaning, upgrading and utilisation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 521-532.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Edyta Słupek & Patrycja Makoś & Jacek Gębicki, 2020. "Theoretical and Economic Evaluation of Low-Cost Deep Eutectic Solvents for Effective Biogas Upgrading to Bio-Methane," Energies, MDPI, vol. 13(13), pages 1-19, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Khan, Muhammad Usman & Lee, Jonathan Tian En & Bashir, Muhammad Aamir & Dissanayake, Pavani Dulanja & Ok, Yong Sik & Tong, Yen Wah & Shariati, Mohammad Ali & Wu, Sarah & Ahring, Birgitte Kiaer, 2021. "Current status of biogas upgrading for direct biomethane use: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    2. Muhamed Rasit Atelge & Halil Senol & Mohammed Djaafri & Tulin Avci Hansu & David Krisa & Abdulaziz Atabani & Cigdem Eskicioglu & Hamdi Muratçobanoğlu & Sebahattin Unalan & Slimane Kalloum & Nuri Azbar, 2021. "A Critical Overview of the State-of-the-Art Methods for Biogas Purification and Utilization Processes," Sustainability, MDPI, vol. 13(20), pages 1-39, October.
    3. Mulu, Elshaday & M'Arimi, Milton M. & Ramkat, Rose C., 2021. "A review of recent developments in application of low cost natural materials in purification and upgrade of biogas," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    4. Leme, Rodrigo Marcelo & Seabra, Joaquim E.A., 2017. "Technical-economic assessment of different biogas upgrading routes from vinasse anaerobic digestion in the Brazilian bioethanol industry," Energy, Elsevier, vol. 119(C), pages 754-766.
    5. Tabatabaei, Meisam & Aghbashlo, Mortaza & Valijanian, Elena & Kazemi Shariat Panahi, Hamed & Nizami, Abdul-Sattar & Ghanavati, Hossein & Sulaiman, Alawi & Mirmohamadsadeghi, Safoora & Karimi, Keikhosr, 2020. "A comprehensive review on recent biological innovations to improve biogas production, Part 2: Mainstream and downstream strategies," Renewable Energy, Elsevier, vol. 146(C), pages 1392-1407.
    6. Jemni, Mohamed Ali & Kantchev, Gueorgui & Abid, Mohamed Salah, 2011. "Influence of intake manifold design on in-cylinder flow and engine performances in a bus diesel engine converted to LPG gas fuelled, using CFD analyses and experimental investigations," Energy, Elsevier, vol. 36(5), pages 2701-2715.
    7. Abdeshahian, Peyman & Lim, Jeng Shiun & Ho, Wai Shin & Hashim, Haslenda & Lee, Chew Tin, 2016. "Potential of biogas production from farm animal waste in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 714-723.
    8. Huang, Haiping & Zhang, Hong & Han, Denglin, 2021. "Ferrocene addition for suppression of hydrogen sulfide formation during thermal recovery of oil sand bitumen," Energy, Elsevier, vol. 230(C).
    9. Carolinne Secco & Maria Eduarda Kounaris Fuziki & Angelo Marcelo Tusset & Giane Gonçalves Lenzi, 2023. "Reactive Processes for H 2 S Removal," Energies, MDPI, vol. 16(4), pages 1-14, February.
    10. Lane, Blake & Kinnon, Michael Mac & Shaffer, Brendan & Samuelsen, Scott, 2022. "Deployment planning tool for environmentally sensitive heavy-duty vehicles and fueling infrastructure," Energy Policy, Elsevier, vol. 171(C).
    11. Pellegrino, Sandro & Lanzini, Andrea & Leone, Pierluigi, 2017. "Greening the gas network – The need for modelling the distributed injection of alternative fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 266-286.
    12. Luo, Erga & Yan, Ru & He, Yaping & Han, Zhen & Feng, Yiyu & Qian, Wenrong & Li, Jinkai, 2024. "Does biogas industrial policy promote the industrial transformation?," Resources Policy, Elsevier, vol. 88(C).
    13. Yan, Cheng & Zheng, Zheng, 2014. "Performance of mixed LED light wavelengths on biogas upgrade and biogas fluid removal by microalga Chlorella sp," Applied Energy, Elsevier, vol. 113(C), pages 1008-1014.
    14. Zhang, Yuyao & Kawasaki, Yu & Oshita, Kazuyuki & Takaoka, Masaki & Minami, Daisuke & Inoue, Go & Tanaka, Toshihiro, 2021. "Economic assessment of biogas purification systems for removal of both H2S and siloxane from biogas," Renewable Energy, Elsevier, vol. 168(C), pages 119-130.
    15. Kwon, Gihoon & Tsang, Daniel C.W. & Oh, Jeong-Ik & Kwon, Eilhann E. & Song, Hocheol, 2019. "Pyrolysis of aquatic carbohydrates using CO2 as reactive gas medium: A case study of chitin," Energy, Elsevier, vol. 177(C), pages 136-143.
    16. Baena-Moreno, Francisco M. & Pastor-Pérez, Laura & Zhang, Zhien & Reina, T.R., 2020. "Stepping towards a low-carbon economy. Formic acid from biogas as case of study," Applied Energy, Elsevier, vol. 268(C).
    17. Rasheed, Rizwan & Tahir, Fizza & Yasar, Abdullah & Sharif, Faiza & Tabinda, Amtul Bari & Ahmad, Sajid Rashid & Wang, Yubo & Su, Yuehong, 2022. "Environmental life cycle analysis of a modern commercial-scale fibreglass composite-based biogas scrubbing system," Renewable Energy, Elsevier, vol. 185(C), pages 1261-1271.
    18. Barbera, Elena & Menegon, Silvia & Banzato, Donatella & D'Alpaos, Chiara & Bertucco, Alberto, 2019. "From biogas to biomethane: A process simulation-based techno-economic comparison of different upgrading technologies in the Italian context," Renewable Energy, Elsevier, vol. 135(C), pages 663-673.
    19. Yuhan Zhang & Yongbin Wang & Zhibin Chen & Chengzhi Hu & Jiuhui Qu, 2024. "Recovering nutrients and unblocking the cake layer of an electrochemical anaerobic membrane bioreactor," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    20. Silverman, Rochelle E. & Flores, Robert J. & Brouwer, Jack, 2020. "Energy and economic assessment of distributed renewable gas and electricity generation in a small disadvantaged urban community," Applied Energy, Elsevier, vol. 280(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:12:y:2020:i:4:p:1619-:d:323472. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.