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Effect of KOH Pretreatment on Lignocellulosic Waste for the Reduction of Nitrobenzene to Aniline without Metal

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  • Sarra Tadrent

    (Centre de Recherches de Royallieu, Sorbonne Universités, Université de Technologie de Compiègne, CS 60319, CEDEX, F-60203 Compiègne, France)

  • Anissa Khelfa

    (Ecole Supérieure de Chimie Organique et Minérale, 1 allée du Réseau Jean-Marie Buckmaster, CEDEX, F-60200 Compiègne, France)

  • Christophe Len

    (Centre de Recherches de Royallieu, Sorbonne Universités, Université de Technologie de Compiègne, CS 60319, CEDEX, F-60203 Compiègne, France
    Institute for Chemistry in Life and Health Sciences, PSL Research University, Chimie ParisTech, CNRS, 11 rue Pierre et Marie Curie, CEDEX 05, F-75231 Paris, France)

Abstract

A green reduction of nitrobenzene to aniline was carried out using lignocellulosic biomass as a hydrogen source in a subcritical polar protic solvent, such as water and alcohol. The method is simple to implement, inexpensive, and easily applicable on a larger scale. The present method does not demand elaborated experimental conditions nor any metal catalyst. Optimal conditions provided aniline with a 90% yield by reduction of nitrobenzene in the presence of sawdust impregnated by KOH in subcritical methanol at 240 °C for 6 h.

Suggested Citation

  • Sarra Tadrent & Anissa Khelfa & Christophe Len, 2020. "Effect of KOH Pretreatment on Lignocellulosic Waste for the Reduction of Nitrobenzene to Aniline without Metal," Sustainability, MDPI, vol. 12(11), pages 1-10, June.
    • Handle: RePEc:gam:jsusta:v:12:y:2020:i:11:p:4665-:d:368533
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    References listed on IDEAS

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    1. R. D. Cortright & R. R. Davda & J. A. Dumesic, 2002. "Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water," Nature, Nature, vol. 418(6901), pages 964-967, August.
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    1. Tamara Tadić & Bojana Marković & Jelena Radulović & Jelena Lukić & Ljiljana Suručić & Aleksandra Nastasović & Antonije Onjia, 2022. "A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline," Sustainability, MDPI, vol. 14(15), pages 1-15, July.

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