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Use of Ni-containing catalysts for synthetic olive mill wastewater steam reforming

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  • Rocha, Cláudio
  • Soria, M.A.
  • Madeira, Luís M.

Abstract

The olive oil mill wastewater (OMW) is a by-product (with a high organic load) derived from the production of the olive oil. The OMW steam reforming (OMWSR) process was studied herein, aiming to decrease the environmental damage of such effluents; simultaneously, the waste is economically and energetically valorized with the H2 production. Several Ni-containing catalysts were prepared and tested to compare their performances for the OMWSR using a synthetic OMW effluent; still, stability tests were also carried out. The materials were extensively characterized: thermogravimetric analysis, temperature-programmed oxidation/reduction, temperature-programmed desorption of CO2/NH3, chemisorption of H2, inductively coupled plasma optical emission spectrometry and physical adsorption-desorption of N2 at −196 °C. Amongst the materials tested, the Ni–Ru/SiO2 sample stood out, exhibiting high catalytic performance: at 400 °C, the H2 yield (>8 molH2·molOMW-1) and conversion of total organic carbon (≈75%) were high during all the 24 h of the long-term test, with only a small deactivation being noticed.

Suggested Citation

  • Rocha, Cláudio & Soria, M.A. & Madeira, Luís M., 2022. "Use of Ni-containing catalysts for synthetic olive mill wastewater steam reforming," Renewable Energy, Elsevier, vol. 185(C), pages 1329-1342.
  • Handle: RePEc:eee:renene:v:185:y:2022:i:c:p:1329-1342
    DOI: 10.1016/j.renene.2021.12.052
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    References listed on IDEAS

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    1. Silva, Joel M. & Soria, M.A. & Madeira, Luis M., 2015. "Challenges and strategies for optimization of glycerol steam reforming process," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1187-1213.
    2. R. D. Cortright & R. R. Davda & J. A. Dumesic, 2002. "Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water," Nature, Nature, vol. 418(6901), pages 964-967, August.
    3. Cláudio Rocha & Miguel Angel Soria & Luís M. Madeira, 2022. "Olive Mill Wastewater Valorization through Steam Reforming Using Multifunctional Reactors: Challenges of the Process Intensification," Energies, MDPI, vol. 15(3), pages 1-51, January.
    4. Rocha, Cláudio & Soria, M.A. & Madeira, Luís M., 2021. "Screening of commercial catalysts for steam reforming of olive mill wastewater," Renewable Energy, Elsevier, vol. 169(C), pages 765-779.
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    Cited by:

    1. Carvalho, João & Nogueira, Anabela & Castro-Silva, Sérgio & Rocha, Cláudio & Madeira, Luís M., 2023. "Process simulation and techno-economic analysis of olive oil mill wastewater steam reforming," Energy, Elsevier, vol. 278(PB).
    2. Alfredo Crialesi & Barbara Mazzarotta & Marco Santalucia & Fabrizio Di Caprio & Alfonso Pozio & Alessia Santucci & Luca Farina, 2022. "Exploiting Olive Mill Wastewater via Thermal Conversion of the Organic Matter into Gaseous Biofuel—A Case Study," Energies, MDPI, vol. 15(8), pages 1-14, April.
    3. Cerqueira, Pedro & Soria, M.A. & Madeira, Luis M., 2023. "Valorization of olive mill wastewater via autothermal reforming for hydrogen production," Renewable Energy, Elsevier, vol. 219(P2).

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