IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v14y2022i15p9222-d873424.html
   My bibliography  Save this article

A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline

Author

Listed:
  • Tamara Tadić

    (Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Njegoševa 12, 11000 Belgrade, Serbia)

  • Bojana Marković

    (Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Njegoševa 12, 11000 Belgrade, Serbia)

  • Jelena Radulović

    (Anahem Laboratory, Mocartova 10, 11160 Belgrade, Serbia)

  • Jelena Lukić

    (Innovation Center of the Faculty of Technology and Metallurgy, Karnegijeva 4, 11000 Belgrade, Serbia)

  • Ljiljana Suručić

    (Faculty of Medicine, University of Banja Luka, Save Mrkalja 14, 78000 Banja Luka, Bosnia and Herzegovina)

  • Aleksandra Nastasović

    (Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Njegoševa 12, 11000 Belgrade, Serbia)

  • Antonije Onjia

    (Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia)

Abstract

A core-shell amino-functionalized glycidyl methacrylate magnetic molecularly imprinted polymer (MIP) was synthesized by the suspension polymerization/surface imprinting method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), mercury porosimetry, nitrogen gas adsorption–desorption, and elemental analysis. This MIP was used as the sorbent in dispersive solid-phase microextraction (DSPME) of aniline from textile wastewater prior to high-performance liquid chromatography-mass spectrometry (HPLC-MS) measurements. Since aniline is toxic and a probable human carcinogen, its determination in water is of great significance. This is a challenging task because aniline is usually present at trace levels. The effects of different DSPME variables on the preconcentration efficiency have been studied by using the Plackett–Burman screening design of experiments (DoE) followed by response surface methodology optimization using the Box-Behnken design. Thus, DoE enabled the investigation of several variables simultaneously. Under optimized conditions, aniline was effectively and selectively separated by a small amount of the DSPME sorbent and detected in real textile wastewater samples. The method detection limit of 1 ng mL −1 was attained, with good method linearity and acceptable recovery and precision. The results showed that the studied MIP could be a reliable DSPME sorbent for efficiently analyzing trace aniline in real wastewater samples.

Suggested Citation

  • Tamara Tadić & Bojana Marković & Jelena Radulović & Jelena Lukić & Ljiljana Suručić & Aleksandra Nastasović & Antonije Onjia, 2022. "A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline," Sustainability, MDPI, vol. 14(15), pages 1-15, July.
  • Handle: RePEc:gam:jsusta:v:14:y:2022:i:15:p:9222-:d:873424
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/14/15/9222/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/2071-1050/14/15/9222/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Mansur Abdulrasheed & Azham Zulkharnain & Nur Nadhirah Zakaria & Ahmad Fareez Ahmad Roslee & Khalilah Abdul Khalil & Suhaimi Napis & Peter Convey & Claudio Gomez-Fuentes & Siti Aqlima Ahmad, 2020. "Response Surface Methodology Optimization and Kinetics of Diesel Degradation by a Cold-Adapted Antarctic Bacterium, Arthrobacter sp. Strain AQ5-05," Sustainability, MDPI, vol. 12(17), pages 1-14, August.
    2. Athanasia K. Tolkou & George Z. Kyzas & Ioannis A. Katsoyiannis, 2022. "Arsenic(III) and Arsenic(V) Removal from Water Sources by Molecularly Imprinted Polymers (MIPs): A Mini Review of Recent Developments," Sustainability, MDPI, vol. 14(9), pages 1-16, April.
    3. Juan M. Trujillo-González & Juan D. Mahecha-Pulido & Marco A. Torres-Mora & Eric C. Brevik & Saskia D. Keesstra & Raimundo Jiménez-Ballesta, 2017. "Impact of Potentially Contaminated River Water on Agricultural Irrigated Soils in an Equatorial Climate," Agriculture, MDPI, vol. 7(7), pages 1-11, June.
    4. Suad E. Abughrin & Usama Alshana & Sezgin Bakirdere, 2022. "Magnetic Nanoparticle-Based Dispersive Solid-Phase Microextraction of Three UV Blockers Prior to Their Determination by HPLC-DAD," IJERPH, MDPI, vol. 19(10), pages 1-14, May.
    5. Sarra Tadrent & Anissa Khelfa & Christophe Len, 2020. "Effect of KOH Pretreatment on Lignocellulosic Waste for the Reduction of Nitrobenzene to Aniline without Metal," Sustainability, MDPI, vol. 12(11), pages 1-10, June.
    6. Jie Xu & Yi Liu & Chao Zhu & Honglei Jia & Changyan Tian & Hongrui Ma & Guanghui Lv, 2020. "NaCl Improves Suaeda salsa Aniline Tolerance in Wastewater," Sustainability, MDPI, vol. 12(18), pages 1-16, September.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Athanasia K. Tolkou & Dimitra K. Toubanaki & George Z. Kyzas, 2023. "Detection of Arsenic, Chromium, Cadmium, Lead, and Mercury in Fish: Effects on the Sustainable and Healthy Development of Aquatic Life and Human Consumers," Sustainability, MDPI, vol. 15(23), pages 1-17, November.
    2. Athanasia K. Tolkou & Dimitrios G. Trikkaliotis & George Z. Kyzas & Ioannis A. Katsoyiannis & Eleni A. Deliyanni, 2023. "Simultaneous Removal of As(III) and Fluoride Ions from Water Using Manganese Oxide Supported on Graphene Nanostructures (GO-MnO 2 )," Sustainability, MDPI, vol. 15(2), pages 1-19, January.
    3. Ahmad Fareez Ahmad Roslee & Siti Aqlima Ahmad & Claudio Gomez-Fuentes & Noor Azmi Shaharuddin & Khalilah Abdul Khalil & Azham Zulkharnain, 2021. "Scientometric Analysis of Diesel Pollutions in Antarctic Territories: A Review of Causes and Potential Bioremediation Approaches," Sustainability, MDPI, vol. 13(13), pages 1-24, June.
    4. Dongping Liu & Huibin Yu & Fang Yang & Li Liu & Hongjie Gao & Bing Cui, 2020. "Characterizing Humic Substances from Native Halophyte Soils by Fluorescence Spectroscopy Combined with Parallel Factor Analysis and Canonical Correlation Analysis," Sustainability, MDPI, vol. 12(23), pages 1-15, November.
    5. Gayathiri Verasoundarapandian & Chiew-Yen Wong & Noor Azmi Shaharuddin & Claudio Gomez-Fuentes & Azham Zulkharnain & Siti Aqlima Ahmad, 2021. "A Review and Bibliometric Analysis on Applications of Microbial Degradation of Hydrocarbon Contaminants in Arctic Marine Environment at Metagenomic and Enzymatic Levels," IJERPH, MDPI, vol. 18(4), pages 1-30, February.
    6. Rasidnie Razin Wong & Zheng Syuen Lim & Noor Azmi Shaharuddin & Azham Zulkharnain & Claudio Gomez-Fuentes & Siti Aqlima Ahmad, 2021. "Diesel in Antarctica and a Bibliometric Study on Its Indigenous Microorganisms as Remediation Agent," IJERPH, MDPI, vol. 18(4), pages 1-18, February.
    7. Huanran Liu & Dan Zhang & Xia Zhang & Chuanzhi Zhou & Pei Zhou & Yuee Zhi, 2020. "Medium Optimization for Spore Production of a Straw-Cellulose Degrading Actinomyces Strain under Solid-State Fermentation Using Response Surface Method," Sustainability, MDPI, vol. 12(21), pages 1-12, October.
    8. Shuai Lu & Yimeng Yang & Xiaosi Su & Kaining Yu & Xinzhou Wang, 2022. "Arsenic Adsorption and Desorption in Various Aqueous Media in the Nearshore Zone and Influencing Factors," Sustainability, MDPI, vol. 14(17), pages 1-17, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:14:y:2022:i:15:p:9222-:d:873424. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.