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Pyrolysis and Thermogravimetric Study to Elucidate the Bioenergy Potential of Novel Feedstock Produced on Poor Soils While Keeping the Environmental Sustainability Intact

Author

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  • Muhammad Sajjad Ahmad

    (Bioenergy Research Centre, Department of Bioinformatics and Biotechnology, Government College University Faisalabad, Faisalabad 38000, Pakistan)

  • Muhammad Aamer Mehmood

    (Bioenergy Research Centre, Department of Bioinformatics and Biotechnology, Government College University Faisalabad, Faisalabad 38000, Pakistan
    School of Bioengineering, Sichuan University of Science and Engineering, Zigong 643000, China)

  • Huibo Luo

    (School of Bioengineering, Sichuan University of Science and Engineering, Zigong 643000, China)

  • Boxiong Shen

    (School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin 430068, China)

  • Muhammad Latif

    (Department of Zoology, University of Education, Faisalabad 38000, Pakistan)

  • Wan Azlina Wan Ab Karim Ghani

    (Department of Chemical and Environmental Engineering, Universiti Putra Malaysia, Selangor 43400, Malaysia
    Sustainable Process Engineering Research Center (SPERC), Faculty of Engineering, Universiti Putra Malaysia, Selangor 43400, Malaysia)

  • Nuha Abdulhamid Alkhattabi

    (Biochemistry Department, King Abdulaziz University, Jeddah 21551, Saudi Arabia)

  • Akram Ahmed Aloqbi

    (Biology Department, University of Jeddah, Jeddah 21577, Saudi Arabia)

  • Ebtihaj Jamaluddin Jambi

    (Biochemistry Department, King Abdulaziz University, Jeddah 21551, Saudi Arabia)

  • Munazza Gull

    (Biochemistry Department, King Abdulaziz University, Jeddah 21551, Saudi Arabia)

  • Umer Rashid

    (Institute of Advanced Technology, Universiti Putra Malaysia, Selangor 43400, Malaysia)

Abstract

This work focused on exploring the bioenergy potential of biomass produced on salt-affected soils by growing two types of grasses, namely Parthenium hysterophorus (carrot grass) and Pennesetum benthiumo (mott grass), without using fertilizers or pesticides. The whole plant biomass of both grasses was pyrolyzed at three heating rates (10, 30, and 50 °C min −1 ) in a joined Thermogravimetry–Differential Scanning Calorimetry (TGA–DSC) analyzer under an inert (nitrogen) environment. The pyrolysis of both grasses was shown to occur in a three-stage process, while most of the thermal transformation occurred at the temperature range of 240–400 °C. The pyrolytic behavior was assessed by estimating the kinetic parameters, using the isoconversional models of Kissenger–Akahira–Sunose and Ozawa–Flynn–Wall. The average values of the activation energy of carrot and mott grasses were shown to be 267 kJ mol −1 ( R 2 ≥ 0.98) and 188 kJ mol −1 ( R 2 ≥ 0.98), indicating the suitability of both grasses for co-pyrolysis. Whereas, the difference in the values of enthalpy change and the activation energy was shown to be <~5 kJ mol −1 at each fractional point, which indicated that the product formation was being favored. Moreover, the high heating values of carrot grass (18.25 MJ kg −1 ) and mott grass (18.63 MJ kg −1 ) have shown a remarkable bioenergy potential and suitability of co-pyrolysis for both grasses. This study will lead to establishing an energy-efficient and cost-effective process for the thermal transformation of biomass to bioenergy.

Suggested Citation

  • Muhammad Sajjad Ahmad & Muhammad Aamer Mehmood & Huibo Luo & Boxiong Shen & Muhammad Latif & Wan Azlina Wan Ab Karim Ghani & Nuha Abdulhamid Alkhattabi & Akram Ahmed Aloqbi & Ebtihaj Jamaluddin Jambi , 2019. "Pyrolysis and Thermogravimetric Study to Elucidate the Bioenergy Potential of Novel Feedstock Produced on Poor Soils While Keeping the Environmental Sustainability Intact," Sustainability, MDPI, vol. 11(13), pages 1-15, June.
  • Handle: RePEc:gam:jsusta:v:11:y:2019:i:13:p:3592-:d:244194
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    References listed on IDEAS

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    1. Maurizio Volpe & Carmelo D'Anna & Simona Messineo & Roberto Volpe & Antonio Messineo, 2014. "Sustainable Production of Bio-Combustibles from Pyrolysis of Agro-Industrial Wastes," Sustainability, MDPI, vol. 6(11), pages 1-17, November.
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    3. Maria Rosaria Boni & Agostina Chiavola & Simone Marzeddu, 2018. "Application of Biochar to the Remediation of Pb-Contaminated Solutions," Sustainability, MDPI, vol. 10(12), pages 1-14, November.
    4. Patel, Madhumita & Zhang, Xiaolei & Kumar, Amit, 2016. "Techno-economic and life cycle assessment on lignocellulosic biomass thermochemical conversion technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1486-1499.
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