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The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH 2 ) 2 –3LiH–LiBH 4

Author

Listed:
  • Han Wang

    (Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
    Graduate School of the Chinese Academy of Sciences, Beijing 100049, China)

  • Hujun Cao

    (Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)

  • Guotao Wu

    (Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)

  • Teng He

    (Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)

  • Ping Chen

    (Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)

Abstract

2Mg(NH 2 ) 2 –3LiH–LiBH 4 composite exhibits an improved kinetic and thermodynamic properties in hydrogen storage in comparison with 2Mg(NH 2 ) 2 –3LiH. The peak temperature of hydrogen desorption drops about 10 K and the peak width shrinks about 50 K compared with the neat 2Mg(NH 2 ) 2 –3LiH. Its isothermal dehydrogenation and re-hydrogenation rates are respectively 2 times and 18 times as fast as those of 2Mg(NH 2 ) 2 –3LiH. A slope desorption region with higher equilibrium pressure is observed. By means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) analyses, the existence of Li 2 BNH 6 is identified and its roles in kinetic and thermodynamic enhancement are discussed.

Suggested Citation

  • Han Wang & Hujun Cao & Guotao Wu & Teng He & Ping Chen, 2015. "The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH 2 ) 2 –3LiH–LiBH 4," Energies, MDPI, vol. 8(7), pages 1-12, July.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:7:p:6898-6909:d:52363
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    References listed on IDEAS

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    1. Ping Chen & Zhitao Xiong & Jizhong Luo & Jianyi Lin & Kuang Lee Tan, 2002. "Interaction of hydrogen with metal nitrides and imides," Nature, Nature, vol. 420(6913), pages 302-304, November.
    2. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
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    Cited by:

    1. Sebastiano Garroni & Antonio Santoru & Hujun Cao & Martin Dornheim & Thomas Klassen & Chiara Milanese & Fabiana Gennari & Claudio Pistidda, 2018. "Recent Progress and New Perspectives on Metal Amide and Imide Systems for Solid-State Hydrogen Storage," Energies, MDPI, vol. 11(5), pages 1-28, April.
    2. Craig M. Jensen & Etsuo Akiba & Hai-Wen Li, 2016. "Hydrides: Fundamentals and Applications," Energies, MDPI, vol. 9(4), pages 1-2, April.
    3. Gökhan Gizer & Hujun Cao & Julián Puszkiel & Claudio Pistidda & Antonio Santoru & Weijin Zhang & Teng He & Ping Chen & Thomas Klassen & Martin Dornheim, 2019. "Enhancement Effect of Bimetallic Amide K 2 Mn(NH 2 ) 4 and In-Situ Formed KH and Mn 4 N on the Dehydrogenation/Hydrogenation Properties of Li–Mg–N–H System," Energies, MDPI, vol. 12(14), pages 1-12, July.

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