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Recent Progress and New Perspectives on Metal Amide and Imide Systems for Solid-State Hydrogen Storage

Author

Listed:
  • Sebastiano Garroni

    (International Research Centre in Critical Raw Materials—ICCRAM, Universidad de Burgos, Plaza Misael Banuelos s/n, 09001 Burgos, Spain)

  • Antonio Santoru

    (Institute of Materials Research, Materials Technology, Helmholtz-Zentrum Geesthacht GmbH, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

  • Hujun Cao

    (Institute of Materials Research, Materials Technology, Helmholtz-Zentrum Geesthacht GmbH, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

  • Martin Dornheim

    (Institute of Materials Research, Materials Technology, Helmholtz-Zentrum Geesthacht GmbH, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

  • Thomas Klassen

    (Institute of Materials Research, Materials Technology, Helmholtz-Zentrum Geesthacht GmbH, Max-Planck-Straße 1, 21502 Geesthacht, Germany
    Department of Mechanical Engineering, Helmut Schmidt University, Holstenhofweg 85, 22043 Hamburg, Germany)

  • Chiara Milanese

    (Pavia Hydrogen Lab, C.S.G.I. & Department of Chemistry, Physical-Chemistry Section, University of Pavia, Viale Taramelli, 16, 27100 Pavia, Italy)

  • Fabiana Gennari

    (Centro Atómico Bariloche (CNEA) e Instituto Balseiro (UNCuyo), Bariloche, Río Negro R8402AGP, Argentina)

  • Claudio Pistidda

    (Institute of Materials Research, Materials Technology, Helmholtz-Zentrum Geesthacht GmbH, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

Abstract

Hydrogen storage in the solid state represents one of the most attractive and challenging ways to supply hydrogen to a proton exchange membrane (PEM) fuel cell. Although in the last 15 years a large variety of material systems have been identified as possible candidates for storing hydrogen, further efforts have to be made in the development of systems which meet the strict targets of the Fuel Cells and Hydrogen Joint Undertaking (FCH JU) and U.S. Department of Energy (DOE). Recent projections indicate that a system possessing: (i) an ideal enthalpy in the range of 20–50 kJ/mol H 2 , to use the heat produced by PEM fuel cell for providing the energy necessary for desorption; (ii) a gravimetric hydrogen density of 5 wt. % H 2 and (iii) fast sorption kinetics below 110 °C is strongly recommended. Among the known hydrogen storage materials, amide and imide-based mixtures represent the most promising class of compounds for on-board applications; however, some barriers still have to be overcome before considering this class of material mature for real applications. In this review, the most relevant progresses made in the recent years as well as the kinetic and thermodynamic properties, experimentally measured for the most promising systems, are reported and properly discussed.

Suggested Citation

  • Sebastiano Garroni & Antonio Santoru & Hujun Cao & Martin Dornheim & Thomas Klassen & Chiara Milanese & Fabiana Gennari & Claudio Pistidda, 2018. "Recent Progress and New Perspectives on Metal Amide and Imide Systems for Solid-State Hydrogen Storage," Energies, MDPI, vol. 11(5), pages 1-28, April.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:5:p:1027-:d:142826
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    References listed on IDEAS

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    1. Paul J. J. Welfens & Christian Richter & Holger C. Wolf, 2019. "Transitions," International Economics and Economic Policy, Springer, vol. 16(4), pages 563-564, October.
    2. Ping Chen & Zhitao Xiong & Jizhong Luo & Jianyi Lin & Kuang Lee Tan, 2002. "Interaction of hydrogen with metal nitrides and imides," Nature, Nature, vol. 420(6913), pages 302-304, November.
    3. Donald L. Anton & Christine J. Price & Joshua Gray, 2011. "Affects of Mechanical Milling and Metal Oxide Additives on Sorption Kinetics of 1:1 LiNH 2 /MgH 2 Mixture," Energies, MDPI, vol. 4(5), pages 1-19, May.
    4. Han Wang & Hujun Cao & Guotao Wu & Teng He & Ping Chen, 2015. "The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH 2 ) 2 –3LiH–LiBH 4," Energies, MDPI, vol. 8(7), pages 1-12, July.
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    1. Gökhan Gizer & Hujun Cao & Julián Puszkiel & Claudio Pistidda & Antonio Santoru & Weijin Zhang & Teng He & Ping Chen & Thomas Klassen & Martin Dornheim, 2019. "Enhancement Effect of Bimetallic Amide K 2 Mn(NH 2 ) 4 and In-Situ Formed KH and Mn 4 N on the Dehydrogenation/Hydrogenation Properties of Li–Mg–N–H System," Energies, MDPI, vol. 12(14), pages 1-12, July.
    2. Julián Puszkiel & José M. Bellosta von Colbe & Julian Jepsen & Sergey V. Mitrokhin & Elshad Movlaev & Victor Verbetsky & Thomas Klassen, 2020. "Designing an AB 2 -Type Alloy (TiZr-CrMnMo) for the Hybrid Hydrogen Storage Concept," Energies, MDPI, vol. 13(11), pages 1-26, June.
    3. Erika Michela Dematteis & Jussara Barale & Marta Corno & Alessandro Sciullo & Marcello Baricco & Paola Rizzi, 2021. "Solid-State Hydrogen Storage Systems and the Relevance of a Gender Perspective," Energies, MDPI, vol. 14(19), pages 1-26, September.

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