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Enhanced Hydrogen Storage Properties of Li-RHC System with In-House Synthesized AlTi 3 Nanoparticles

Author

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  • Thi-Thu Le

    (Institute of Hydrogen Technology, Helmholtz-Zentrum Hereon GmbH, D-21502 Geesthacht, Germany)

  • Claudio Pistidda

    (Institute of Hydrogen Technology, Helmholtz-Zentrum Hereon GmbH, D-21502 Geesthacht, Germany)

  • Julián Puszkiel

    (Institute of Hydrogen Technology, Helmholtz-Zentrum Hereon GmbH, D-21502 Geesthacht, Germany
    Faculty of Mechanical Engineering, Helmut Schmidt University/University of the Federal Armed Forces, 22043 Hamburg, Germany)

  • María Victoria Castro Riglos

    (Department of Metalphysics, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) and Centro Atómico Bariloche, San Carlos de Bariloche R8402AGP, Argentina)

  • David Michael Dreistadt

    (Institute of Hydrogen Technology, Helmholtz-Zentrum Hereon GmbH, D-21502 Geesthacht, Germany)

  • Thomas Klassen

    (Institute of Hydrogen Technology, Helmholtz-Zentrum Hereon GmbH, D-21502 Geesthacht, Germany
    Faculty of Mechanical Engineering, Helmut Schmidt University/University of the Federal Armed Forces, 22043 Hamburg, Germany)

  • Martin Dornheim

    (Institute of Hydrogen Technology, Helmholtz-Zentrum Hereon GmbH, D-21502 Geesthacht, Germany)

Abstract

In recent years, the use of selected additives for improving the kinetic behavior of the system 2LiH + MgB 2 (Li-RHC) has been investigated. As a result, it has been reported that some additives (e.g., 3TiCl 3 ·AlCl 3 ), by reacting with the Li-RHC components, form nanostructured phases (e.g., AlTi 3 ) possessing peculiar microstructural properties capable of enhancing the system’s kinetic behavior. The effect of in-house-produced AlTi 3 nanoparticles on the hydrogenation/dehydrogenation kinetics of the 2LiH + MgB 2 (Li-RHC) system is explored in this work, with the aim of reaching high hydrogen storage performance. Experimental results show that the AlTi 3 nanoparticles significantly improve the reaction rate of the Li-RHC system, mainly for the dehydrogenation process. The observed improvement is most likely due to the similar structural properties between AlTi 3 and MgB 2 phases which provide an energetically favored path for the nucleation of MgB 2 . In comparison with the pristine material, the Li-RHC doped with AlTi 3 nanoparticles has about a nine times faster dehydrogenation rate. The results obtained from the kinetic modeling indicate a change in the Li-RHC hydrogenation reaction mechanism in the presence of AlTi 3 nanoparticles.

Suggested Citation

  • Thi-Thu Le & Claudio Pistidda & Julián Puszkiel & María Victoria Castro Riglos & David Michael Dreistadt & Thomas Klassen & Martin Dornheim, 2021. "Enhanced Hydrogen Storage Properties of Li-RHC System with In-House Synthesized AlTi 3 Nanoparticles," Energies, MDPI, vol. 14(23), pages 1-16, November.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:23:p:7853-:d:685799
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    References listed on IDEAS

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    2. Huen Lee & Jong-won Lee & Do Youn Kim & Jeasung Park & Yu-Taek Seo & Huang Zeng & Igor L. Moudrakovski & Christopher I. Ratcliffe & John A. Ripmeester, 2005. "Tuning clathrate hydrates for hydrogen storage," Nature, Nature, vol. 434(7034), pages 743-746, April.
    3. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
    4. Ping Chen & Zhitao Xiong & Jizhong Luo & Jianyi Lin & Kuang Lee Tan, 2002. "Interaction of hydrogen with metal nitrides and imides," Nature, Nature, vol. 420(6913), pages 302-304, November.
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