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Tuneable mesoporous silica material for hydrogen storage application via nano-confined clathrate hydrate construction

Author

Listed:
  • Radu-George Ciocarlan

    (Universiteitsplein 1)

  • Judit Farrando-Perez

    (University of Alicante (UA))

  • Daniel Arenas-Esteban

    (University of Antwerp)

  • Maarten Houlleberghs

    (Celestijnenlaan 200F)

  • Luke L. Daemen

    (Oak Ridge National Laboratory)

  • Yongqiang Cheng

    (Oak Ridge National Laboratory)

  • Anibal J. Ramirez-Cuesta

    (Oak Ridge National Laboratory)

  • Eric Breynaert

    (Celestijnenlaan 200F)

  • Johan Martens

    (Celestijnenlaan 200F)

  • Sara Bals

    (University of Antwerp)

  • Joaquin Silvestre-Albero

    (University of Alicante (UA))

  • Pegie Cool

    (Universiteitsplein 1)

Abstract

Safe storage and utilisation of hydrogen is an ongoing area of research, showing potential to enable hydrogen becoming an effective fuel, substituting current carbon-based sources. Hydrogen storage is associated with a high energy cost due to its low density and boiling point, which drives a high price. Clathrates (gas hydrates) are water-based (ice-like) structures incorporating small non-polar compounds such as H2 in cages formed by hydrogen bonded water molecules. Since only water is required to construct the cages, clathrates have been identified as a potential solution for safe storage of hydrogen. In bulk, pure hydrogen clathrate (H2O-H2) only forms in harsh conditions, but confined in nanospaces the properties of water are altered and hydrogen storage at mild pressure and temperature could become possible. Here, specifically a hydrophobic mesoporous silica is proposed as a host material, providing a suitable nano-confinement for ice-like clathrate hydrate. The hybrid silica material shows an important decrease of the pressure required for clathrate formation (approx. 20%) compared to the pure H2O-H2 system. In-situ inelastic neutron scattering (INS) and neutron diffraction (ND) provided unique insights into the interaction of hydrogen with the complex surface of the hybrid material and demonstrated the stability of nano-confined hydrogen clathrate hydrate.

Suggested Citation

  • Radu-George Ciocarlan & Judit Farrando-Perez & Daniel Arenas-Esteban & Maarten Houlleberghs & Luke L. Daemen & Yongqiang Cheng & Anibal J. Ramirez-Cuesta & Eric Breynaert & Johan Martens & Sara Bals &, 2024. "Tuneable mesoporous silica material for hydrogen storage application via nano-confined clathrate hydrate construction," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-52893-3
    DOI: 10.1038/s41467-024-52893-3
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    References listed on IDEAS

    as
    1. Usman, Muhammad R., 2022. "Hydrogen storage methods: Review and current status," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    2. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
    3. Zhou, Li, 2005. "Progress and problems in hydrogen storage methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 9(4), pages 395-408, August.
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