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Catalytic Steam Reforming of Toluene as a Model Compound of Biomass Gasification Tar Using Ni-CeO 2 /SBA-15 Catalysts

Author

Listed:
  • Jun Tao

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Leiqiang Zhao

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Changqing Dong

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Qiang Lu

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Xiaoze Du

    (Key Laboratory of Condition Monitoring and Control for Power Plant Equipment, Ministry of Education, North China Electric Power University, No.2 Beinong Road, Changping District, Beijing 102206, China)

  • Erik Dahlquist

    (School of Sustainable Development of Society and Technology, Mälardalen Univeristy, Västerås, SE-721 23, Sweden)

Abstract

Nickel supported on SBA-15 doped with CeO 2 catalysts (Ni-CeO 2 /SBA-15) was prepared, and used for steam reforming of toluene which was selected as a model compound of biomass gasification tar. A fixed-bed lab-scale set was designed and employed to evaluate the catalytic performances of the Ni-CeO 2 /SBA-15 catalysts. Experiments were performed to reveal the effects of several factors on the toluene conversion and product gas composition, including the reaction temperature, steam/carbon (S/C) ratio, and CeO 2 loading content. Moreover, the catalysts were subjected to analysis of their carbon contents after the steam reforming experiments, as well as to test the catalytic stability over a long experimental period. The results indicated that the Ni-CeO 2 /SBA-15 catalysts exhibited promising capabilities on the toluene conversion, anti-coke deposition and catalytic stability. The toluene conversion reached as high as 98.9% at steam reforming temperature of 850 °C and S/C ratio of 3 using the Ni-CeO 2 (3wt%)/SBA-15 catalyst. Negligible coke formation was detected on the used catalyst. The gaseous products mainly consisted of H 2 and CO, together with a little CO 2 and CH 4 .

Suggested Citation

  • Jun Tao & Leiqiang Zhao & Changqing Dong & Qiang Lu & Xiaoze Du & Erik Dahlquist, 2013. "Catalytic Steam Reforming of Toluene as a Model Compound of Biomass Gasification Tar Using Ni-CeO 2 /SBA-15 Catalysts," Energies, MDPI, vol. 6(7), pages 1-13, July.
  • Handle: RePEc:gam:jeners:v:6:y:2013:i:7:p:3284-3296:d:26924
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    References listed on IDEAS

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    1. Devi, Lopamudra & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G. & van Paasen, Sander V.B. & Bergman, Patrick C.A. & Kiel, Jacob H.A., 2005. "Catalytic decomposition of biomass tars: use of dolomite and untreated olivine," Renewable Energy, Elsevier, vol. 30(4), pages 565-587.
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    Cited by:

    1. Rakesh N, & Dasappa, S., 2018. "A critical assessment of tar generated during biomass gasification - Formation, evaluation, issues and mitigation strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1045-1064.
    2. Zhang, Zhikun & Liu, Lina & Shen, Boxiong & Wu, Chunfei, 2018. "Preparation, modification and development of Ni-based catalysts for catalytic reforming of tar produced from biomass gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 1086-1109.
    3. Duan, Wenjun & Yu, Qingbo & Liu, Junxiang & Wu, Tianwei & Yang, Fan & Qin, Qin, 2016. "Experimental and kinetic study of steam gasification of low-rank coal in molten blast furnace slag," Energy, Elsevier, vol. 111(C), pages 859-868.
    4. Li, Xueqin & Liu, Peng & Lei, Tingzhou & Wu, Youqing & Chen, Wenxuan & Wang, Zhiwei & Shi, Jie & Wu, Shiyong & Li, Yanling & Huang, Sheng, 2022. "Pyrolysis of biomass Tar model compound with various Ni-based catalysts: Influence of promoters characteristics on hydrogen-rich gas formation," Energy, Elsevier, vol. 244(PB).
    5. Oh, Gunung & Park, Seo Yoon & Seo, Myung Won & Kim, Yong Ku & Ra, Ho Won & Lee, Jae-Goo & Yoon, Sang Jun, 2016. "Ni/Ru–Mn/Al2O3 catalysts for steam reforming of toluene as model biomass tar," Renewable Energy, Elsevier, vol. 86(C), pages 841-847.
    6. Vincenzo Palma & Concetta Ruocco & Eugenio Meloni & Antonio Ricca, 2017. "Influence of Catalytic Formulation and Operative Conditions on Coke Deposition over CeO 2 -SiO 2 Based Catalysts for Ethanol Reforming," Energies, MDPI, vol. 10(7), pages 1-13, July.
    7. Gao, Ningbo & Salisu, Jamilu & Quan, Cui & Williams, Paul, 2021. "Modified nickel-based catalysts for improved steam reforming of biomass tar: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    8. No-Kuk Park & Young Jin Lee & Byung Chan Kwon & Tae Jin Lee & Suk Hwan Kang & Bum Ui Hong & Taejin Kim, 2019. "Optimization of Nickel-Based Catalyst Composition and Reaction Conditions for the Prevention of Carbon Deposition in Toluene Reforming," Energies, MDPI, vol. 12(7), pages 1-13, April.

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