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Ni/Ru–Mn/Al2O3 catalysts for steam reforming of toluene as model biomass tar

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  • Oh, Gunung
  • Park, Seo Yoon
  • Seo, Myung Won
  • Kim, Yong Ku
  • Ra, Ho Won
  • Lee, Jae-Goo
  • Yoon, Sang Jun

Abstract

The catalytic steam reforming of the major biomass tar component, toluene, was studied over two commercial Ni-based catalysts and two prepared Ru–Mn-promoted Ni-base catalysts, in the temperatures range 673–1073 K. Generally, the conversion of toluene and the H2 content in the product gas increased with temperature. A H2-rich gas was generated by the steam reforming of toluene, and the CO and CO2 contents in the product gas were reduced by the reverse Boudouard reaction. A naphtha-reforming catalyst (46-5Q) exhibited better performance in the steam reforming of toluene at temperatures over 873 K than a methane-reforming catalyst (Reformax 330). Ni/Ru–Mn/Al2O3 catalysts showed high toluene reforming performance at temperatures over 873 K. The results indicate that the observed high stability and coking resistance may be attributed to the promotional effects of Mn on the Ni/Ru–Mn/Al2O3 catalyst.

Suggested Citation

  • Oh, Gunung & Park, Seo Yoon & Seo, Myung Won & Kim, Yong Ku & Ra, Ho Won & Lee, Jae-Goo & Yoon, Sang Jun, 2016. "Ni/Ru–Mn/Al2O3 catalysts for steam reforming of toluene as model biomass tar," Renewable Energy, Elsevier, vol. 86(C), pages 841-847.
    • Handle: RePEc:eee:renene:v:86:y:2016:i:c:p:841-847
    DOI: 10.1016/j.renene.2015.09.013
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    References listed on IDEAS

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    1. Anis, Samsudin & Zainal, Z.A., 2011. "Tar reduction in biomass producer gas via mechanical, catalytic and thermal methods: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2355-2377, June.
    2. Jun Tao & Leiqiang Zhao & Changqing Dong & Qiang Lu & Xiaoze Du & Erik Dahlquist, 2013. "Catalytic Steam Reforming of Toluene as a Model Compound of Biomass Gasification Tar Using Ni-CeO 2 /SBA-15 Catalysts," Energies, MDPI, vol. 6(7), pages 1-13, July.
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    Cited by:

    1. Yuan, Hongyou & Wu, Shubin & Yin, Xiuli & Huang, Yanqin & Guo, Daliang & Wu, Chuangzhi, 2018. "Adjustment of biomass product gas to raise H2/CO ratio and remove tar over sodium titanate catalysts," Renewable Energy, Elsevier, vol. 115(C), pages 288-298.
    2. Rakesh N, & Dasappa, S., 2018. "A critical assessment of tar generated during biomass gasification - Formation, evaluation, issues and mitigation strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1045-1064.
    3. Gao, Ningbo & Salisu, Jamilu & Quan, Cui & Williams, Paul, 2021. "Modified nickel-based catalysts for improved steam reforming of biomass tar: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    4. Yang Gao & Huaqing Xie & Zhenyu Yu & Mengxin Qin & Zhenguo Wu & Panlei Wang & Xi Zhao & Shiyi Zhang, 2023. "Two-Stage Dry Reforming Process for Biomass Gasification: Product Characteristics and Energy Analysis," Energies, MDPI, vol. 16(12), pages 1-13, June.
    5. Lu, Min & Xiong, Zuhong & Fang, Kejing & Li, Xi & Li, Jiqing & Li, Tao, 2020. "Steam reforming of toluene over nickel catalysts supported on coal gangue ash," Renewable Energy, Elsevier, vol. 160(C), pages 385-395.

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