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Fuel-N Evolution during the Pyrolysis of Industrial Biomass Wastes with High Nitrogen Content

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  • Hongfang Chen

    (Department of Environmental Science and Technology, Tokyo Institute of Technology, G5-8, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan)

  • Yin Wang

    (Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China)

  • Guangwen Xu

    (Institute of Process Engineering, Chinese Academy of Sciences, No. 1 Zhongguancun North Second Street, Beijing 100190, China)

  • Kunio Yoshikawa

    (Department of Environmental Science and Technology, Tokyo Institute of Technology, G5-8, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan)

Abstract

In this study, sewage sludge and mycelial waste from antibiotic production were pyrolyzed in a batch scale fixed-bed reactor as examples of two kinds of typical industrial biomass wastes with high nitrogen content. A series of experiments were conducted on the rapid pyrolysis and the slow pyrolysis of these wastes in the temperature range from 500–800 °C to investigate the Fuel-N transformation behavior among pyrolysis products. The results showed that Fuel-N conversion to Char-N intimately depended on the pyrolysis temperature and the yield of Char-N reduced with the increase of the pyrolysis temperature . Under the same pyrolysis conditions, Tar-N production mainly depended on complex properties of the different biomasses, including volatile matter, nitrogen content and biomass functional groups. HCN was the predominant NO x precursor in the rapid pyrolysis of biomass, whereas in the slow pyrolysis of mycelial waste, more NH 3 was produced than HCN due to the additional NH 3 formation through the hydrogenation reaction of Char-N, HCN and H radicals. At the same time, some part of the char was analyzed by Fourier Transform infrared spectroscopy (FTIR) to get more information on the nitrogen functionality changes and the tar was also characterized by Gas Chromatography and Mass Spectrometry (GCMS) to identify typical nitrogenous tar compounds. Finally, the whole nitrogen distribution in products was discussed.

Suggested Citation

  • Hongfang Chen & Yin Wang & Guangwen Xu & Kunio Yoshikawa, 2012. "Fuel-N Evolution during the Pyrolysis of Industrial Biomass Wastes with High Nitrogen Content," Energies, MDPI, vol. 5(12), pages 1-21, December.
  • Handle: RePEc:gam:jeners:v:5:y:2012:i:12:p:5418-5438:d:22331
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    References listed on IDEAS

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    1. Chen, Hongfang & Namioka, Tomoaki & Yoshikawa, Kunio, 2011. "Characteristics of tar, NOx precursors and their absorption performance with different scrubbing solvents during the pyrolysis of sewage sludge," Applied Energy, Elsevier, vol. 88(12), pages 5032-5041.
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    Cited by:

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    2. Xiaorui Liu & Zhongyang Luo & Chunjiang Yu & Bitao Jin & Hanchao Tu, 2018. "Release Mechanism of Fuel-N into NO x and N 2 O Precursors during Pyrolysis of Rice Straw," Energies, MDPI, vol. 11(3), pages 1-13, February.
    3. Zhan, Hao & Zhuang, Xiuzheng & Song, Yanpei & Yin, Xiuli & Wu, Chuangzhi, 2018. "Insights into the evolution of fuel-N to NOx precursors during pyrolysis of N-rich nonlignocellulosic biomass," Applied Energy, Elsevier, vol. 219(C), pages 20-33.
    4. Benítez, Almudena & Amaro-Gahete, Juan & Chien, Yu-Chuan & Caballero, Álvaro & Morales, Julián & Brandell, Daniel, 2022. "Recent advances in lithium-sulfur batteries using biomass-derived carbons as sulfur host," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    5. Zhao, Peitao & Shen, Yafei & Ge, Shifu & Chen, Zhenqian & Yoshikawa, Kunio, 2014. "Clean solid biofuel production from high moisture content waste biomass employing hydrothermal treatment," Applied Energy, Elsevier, vol. 131(C), pages 345-367.
    6. Evangelopoulos, Panagiotis & Kantarelis, Efthymios & Yang, Weihong, 2017. "Experimental investigation of the influence of reaction atmosphere on the pyrolysis of printed circuit boards," Applied Energy, Elsevier, vol. 204(C), pages 1065-1073.
    7. Cao, Songshan & Duan, Feng & Wang, Ping & Chyang, ChienSong, 2018. "Biochar contribution in biomass reburning technology and transformation mechanism of its nitrogen foundational groups at different oxygen contents," Energy, Elsevier, vol. 155(C), pages 272-280.

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