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Influence of Carbon Particle Characteristics on Oxidative Filtration Under Biomass Gasification Gas Atmosphere

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  • Junfei Jiang

    (Department of Electrical Engineering, Nanchang Institute of Technology, Nanchang 330099, China
    Key Laboratory of Energy Low-Carbon Conversion and Storage, Jiangxi Provincial Department of Education, Nanchang 330009, China)

  • Xingying Ji

    (Department of Electrical Engineering, Nanchang Institute of Technology, Nanchang 330099, China
    Key Laboratory of Energy Low-Carbon Conversion and Storage, Jiangxi Provincial Department of Education, Nanchang 330009, China)

  • Qingyan Ling

    (Department of Electrical Engineering, Nanchang Institute of Technology, Nanchang 330099, China)

  • Peilan Luo

    (Department of Electrical Engineering, Nanchang Institute of Technology, Nanchang 330099, China
    Key Laboratory of Energy Low-Carbon Conversion and Storage, Jiangxi Provincial Department of Education, Nanchang 330009, China)

  • Fengfeng Liu

    (Department of Electrical Engineering, Nanchang Institute of Technology, Nanchang 330099, China
    Key Laboratory of Energy Low-Carbon Conversion and Storage, Jiangxi Provincial Department of Education, Nanchang 330009, China)

  • Pengfei Zhao

    (Department of Electrical Engineering, Nanchang Institute of Technology, Nanchang 330099, China
    Key Laboratory of Energy Low-Carbon Conversion and Storage, Jiangxi Provincial Department of Education, Nanchang 330009, China)

  • Haodong Feng

    (Department of Electrical Engineering, Nanchang Institute of Technology, Nanchang 330099, China)

  • Xiaojun Wu

    (Department of Electrical Engineering, Nanchang Institute of Technology, Nanchang 330099, China)

Abstract

The oxidation of filter cake particles (FCPs) is beneficial for preventing filter media blockage during the hot filtration of raw biomass gasification gas. The influence of particle characteristics on hot oxidative filtration was investigated through characterization, kinetic study, and lab-scale experiments. The characterization results indicated that FCPs are particles with C content of more than 60%, containing –CH n and C=O functional groups. After pyrolysis treatment, these functional groups gradually diminished, while the degree of atomic nucleus condensation increased. The oxidation kinetic calculation indicated that the oxidation activation energy of particles ranged from 55.24 to 117.84 kJ/mol, and higher treatment temperatures could reduce the particle reactivity. The hot oxidative filtration at 400 °C revealed that the primary reaction was C + O 2 = CO 2 rather than combustion or oxidation of combustive gas components. Furthermore, it was observed that the active minerals on the surface of carbon particles would promote the catalytic oxidation of CO. Experimental findings confirmed that the untreated FCPs containing abundant –CH n functional groups could effectively react with low-concentration O 2 . However, the presence of active minerals on the particle surface likely promoted CO oxidation within the FCP layer, thereby reducing the calorific value of the product gas.

Suggested Citation

  • Junfei Jiang & Xingying Ji & Qingyan Ling & Peilan Luo & Fengfeng Liu & Pengfei Zhao & Haodong Feng & Xiaojun Wu, 2025. "Influence of Carbon Particle Characteristics on Oxidative Filtration Under Biomass Gasification Gas Atmosphere," Energies, MDPI, vol. 18(5), pages 1-16, February.
    • Handle: RePEc:gam:jeners:v:18:y:2025:i:5:p:1015-:d:1595264
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    References listed on IDEAS

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    2. Choi, Seungmok & Oh, Kwang-Chul & Lee, Chun-Bum, 2014. "The effects of filter porosity and flow conditions on soot deposition/oxidation and pressure drop in particulate filters," Energy, Elsevier, vol. 77(C), pages 327-337.
    3. Li, Shuo & Baeyens, Jan & Dewil, Raf & Appels, Lise & Zhang, Huili & Deng, Yimin, 2021. "Advances in rigid porous high temperature filters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
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