IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i9p3746-d1134398.html
   My bibliography  Save this article

Hydrogen Production from Supercritical Water Gasification of Model Compounds of Crude Glycerol from Biodiesel Industries

Author

Listed:
  • Kapil Khandelwal

    (Department of Chemical and Biological Engineering, University of Saskatchewan, Saskatoon, SK S7N 5A9, Canada)

  • Philip Boahene

    (Department of Chemical and Biological Engineering, University of Saskatchewan, Saskatoon, SK S7N 5A9, Canada)

  • Sonil Nanda

    (Department of Chemical and Biological Engineering, University of Saskatchewan, Saskatoon, SK S7N 5A9, Canada)

  • Ajay K. Dalai

    (Department of Chemical and Biological Engineering, University of Saskatchewan, Saskatoon, SK S7N 5A9, Canada)

Abstract

Biodiesel production through transesterification results in a large quantity of crude glycerol as a byproduct, the utilization of which is technically and economically challenging. Because of the ability to efficiently process wet feedstocks, supercritical water gasification (SCWG) is utilized in this study to convert crude glycerol into hydrogen-rich syngas. A significant challenge addressed through this study is the decomposition routes of different heterogeneous components of crude glycerol during SCWG. Pure glycerol, methanol and oleic acid were investigated for SCWG as the model compounds of crude glycerol. SCWG of model compounds at temperature, pressure, feedstock concentration and reaction time of 500 °C, 23–25 MPa, 10 wt% and 1 h, respectively, revealed methanol to exhibit the highest H 2 yield of 7.7 mmol/g, followed by pure glycerol (4.4 mmol/g) and oleic acid (1.1 mmol/g). The effects of feedstock concentration from 30 wt% to 10 wt% increased H 2 yield from all model compounds. Response surface methodology (RSM) was used to develop a response curve to visualize the interactive behavior and develop model equations for the prediction of H 2 -rich gas yields as a function of the composition of model compounds in the crude glycerol mixture. Predictive models showed a good agreement with experimental results, demonstrating high accuracy and robustness of the model. These findings demonstrated a strong potential of crude glycerol for SCWG to generate H 2 -rich syngas.

Suggested Citation

  • Kapil Khandelwal & Philip Boahene & Sonil Nanda & Ajay K. Dalai, 2023. "Hydrogen Production from Supercritical Water Gasification of Model Compounds of Crude Glycerol from Biodiesel Industries," Energies, MDPI, vol. 16(9), pages 1-19, April.
  • Handle: RePEc:gam:jeners:v:16:y:2023:i:9:p:3746-:d:1134398
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/9/3746/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/16/9/3746/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Tapah, B.F. & Santos, R.C.D. & Leeke, G.A., 2014. "Processing of glycerol under sub and supercritical water conditions," Renewable Energy, Elsevier, vol. 62(C), pages 353-361.
    2. Okolie, Jude A. & Nanda, Sonil & Dalai, Ajay K. & Berruti, Franco & Kozinski, Janusz A., 2020. "A review on subcritical and supercritical water gasification of biogenic, polymeric and petroleum wastes to hydrogen-rich synthesis gas," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    3. Supamathanon, Natkanin & Boonserm, Kornkanok & Osakoo, Nattawut & Wittayakun, Jatuporn & Prayoonpokarach, Sanchai & Chanlek, Narong & Dungkaew, Winya, 2023. "Potassium supported on zeolite-geopolymer hybrid materials as a new solid base catalyst for transesterification of soybean oil," Renewable Energy, Elsevier, vol. 202(C), pages 1460-1469.
    4. Chen, Jingwei & Fu, Liangyu & Tian, Ming & Kang, Siyi & E, Jiaqiang, 2022. "Comparison and synergistic effect analysis on supercritical water gasification of waste thermoplastic plastics based on orthogonal experiments," Energy, Elsevier, vol. 261(PA).
    5. Yan, Mi & Liu, Yu & Song, Yucai & Xu, Aiming & Zhu, Gaojun & Jiang, Jiahao & Hantoko, Dwi, 2022. "Comprehensive experimental study on energy conversion of household kitchen waste via integrated hydrothermal carbonization and supercritical water gasification," Energy, Elsevier, vol. 242(C).
    6. Hu, Yulin & Gong, Mengyue & Xing, Xuelian & Wang, Haoyu & Zeng, Yimin & Xu, Chunbao Charles, 2020. "Supercritical water gasification of biomass model compounds: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Su, Hongcai & Yan, Mi & Wang, Shurong, 2022. "Recent advances in supercritical water gasification of biowaste catalyzed by transition metal-based catalysts for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    2. Chen, Yunan & Yi, Lei & Yin, Jiarong & Jin, Hui & Guo, Liejin, 2022. "Sewage sludge gasification in supercritical water with fluidized bed reactor: Reaction and product characteristics," Energy, Elsevier, vol. 239(PB).
    3. Shahbeik, Hossein & Peng, Wanxi & Kazemi Shariat Panahi, Hamed & Dehhaghi, Mona & Guillemin, Gilles J. & Fallahi, Alireza & Amiri, Hamid & Rehan, Mohammad & Raikwar, Deepak & Latine, Hannes & Pandalon, 2022. "Synthesis of liquid biofuels from biomass by hydrothermal gasification: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    4. Chen, Zhijie & Wei, Wei & Chen, Xueming & Liu, Yiwen & Shen, Yansong & Ni, Bing-Jie, 2024. "Upcycling of plastic wastes for hydrogen production: Advances and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 195(C).
    5. Jun Sheng Teh & Yew Heng Teoh & Heoy Geok How & Thanh Danh Le & Yeoh Jun Jie Jason & Huu Tho Nguyen & Dong Lin Loo, 2021. "The Potential of Sustainable Biomass Producer Gas as a Waste-to-Energy Alternative in Malaysia," Sustainability, MDPI, vol. 13(7), pages 1-31, April.
    6. Ferraz de Campos, Victor Arruda & Silva, Valter Bruno & Cardoso, João Sousa & Brito, Paulo S. & Tuna, Celso Eduardo & Silveira, José Luz, 2021. "A review of waste management in Brazil and Portugal: Waste-to-energy as pathway for sustainable development," Renewable Energy, Elsevier, vol. 178(C), pages 802-820.
    7. David D. J. Antia, 2023. "Conversion of Waste Synthesis Gas to Desalination Catalyst at Ambient Temperatures," Waste, MDPI, vol. 1(2), pages 1-29, May.
    8. Santa Margarida Santos & Ana Carolina Assis & Leandro Gomes & Catarina Nobre & Paulo Brito, 2022. "Waste Gasification Technologies: A Brief Overview," Waste, MDPI, vol. 1(1), pages 1-26, December.
    9. Xu, Jialing & Rong, Siqi & Sun, Jingli & Peng, Zhiyong & Jin, Hui & Guo, Liejin & Zhang, Xiang & Zhou, Teng, 2022. "Optimal design of non-isothermal supercritical water gasification reactor: From biomass to hydrogen," Energy, Elsevier, vol. 244(PB).
    10. Xue, Xiaodong & Liu, Changchun & Han, Wei & Wang, Zefeng & Zhang, Na & Jin, Hongguang & Wang, Xiaodong, 2023. "Proposal and investigation of a high-efficiency coal-fired power generation system enabled by chemical recuperative supercritical water coal gasification," Energy, Elsevier, vol. 267(C).
    11. Latika Bhatia & Harit Jha & Tanushree Sarkar & Prakash Kumar Sarangi, 2023. "Food Waste Utilization for Reducing Carbon Footprints towards Sustainable and Cleaner Environment: A Review," IJERPH, MDPI, vol. 20(3), pages 1-20, January.
    12. Umair Yaqub Qazi, 2022. "Future of Hydrogen as an Alternative Fuel for Next-Generation Industrial Applications; Challenges and Expected Opportunities," Energies, MDPI, vol. 15(13), pages 1-40, June.
    13. Djandja, Oraléou Sangué & Kang, Shimin & Huang, Zizhi & Li, Junqiao & Feng, Jiaqi & Tan, Zaiming & Salami, Adekunlé Akim & Lougou, Bachirou Guene, 2023. "Machine learning prediction of fuel properties of hydrochar from co-hydrothermal carbonization of sewage sludge and lignocellulosic biomass," Energy, Elsevier, vol. 271(C).
    14. Florentina Maxim & Iuliana Poenaru & Elena Ecaterina Toma & Giuseppe Stefan Stoian & Florina Teodorescu & Cristian Hornoiu & Speranta Tanasescu, 2021. "Functional Materials for Waste-to-Energy Processes in Supercritical Water," Energies, MDPI, vol. 14(21), pages 1-23, November.
    15. Anufriev, I.S., 2021. "Review of water/steam addition in liquid-fuel combustion systems for NOx reduction: Waste-to-energy trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    16. Galadima, Ahmad & Muraza, Oki, 2014. "Biodiesel production from algae by using heterogeneous catalysts: A critical review," Energy, Elsevier, vol. 78(C), pages 72-83.
    17. Goswami, Kishor & Choudhury, Hari K., 2015. "To grow or not to grow? Factors influencing the adoption of and continuation with Jatropha in North East India," Renewable Energy, Elsevier, vol. 81(C), pages 627-638.
    18. Feng, Hongyu & Cui, Jintao & Xu, Zhang & Hantoko, Dwi & Zhong, Li & Xu, Donghai & Yan, Mi, 2023. "Sewage sludge treatment via hydrothermal carbonization combined with supercritical water gasification: Fuel production and pollution degradation," Renewable Energy, Elsevier, vol. 210(C), pages 822-831.
    19. Radhakrishnan, Rokesh & Patra, Pradipta & Das, Manali & Ghosh, Amit, 2021. "Recent advancements in the ionic liquid mediated lignin valorization for the production of renewable materials and value-added chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    20. Doppalapudi, A.T. & Azad, A.K. & Khan, M.M.K., 2023. "Advanced strategies to reduce harmful nitrogen-oxide emissions from biodiesel fueled engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 174(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:9:p:3746-:d:1134398. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.