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An All-Vanadium Redox Flow Battery: A Comprehensive Equivalent Circuit Model

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  • Muhammed Samil Yesilyurt

    (Mechatronics Engineering, Yildiz Technical University, Istanbul 34349, Türkiye)

  • Huseyin Ayhan Yavasoglu

    (Mechatronics Engineering, Yildiz Technical University, Istanbul 34349, Türkiye)

Abstract

In this paper, we propose a sophisticated battery model for vanadium redox flow batteries (VRFBs), which are a promising energy storage technology due to their design flexibility, low manufacturing costs on a large scale, indefinite lifetime, and recyclable electrolytes. Primarily, fluid distribution is analysed using computational fluid dynamics (CFD) considering only half-cells. Based on the analysis results, a novel model is developed in the MATLAB Simulink environment which is capable of identifying both the steady-state and dynamic characteristics of VRFBs. Unlike the majority of published studies, the inherent characteristics of the flow battery, such as shunt current, ion diffusion, and pumping energy consumption, are considered. Furthermore, simplified charge transfer resistance (CTR) is taken into account based on electrochemical impedance spectroscopy (EIS) measurement results. The accuracy of the model was determined by comparing the simulation results generated by the equivalent circuit battery model developed in this study with real datasets. The obtained results indicate that the developed model has an accuracy of 3% under the sample operating conditions selected. This study can also be used to fill the gap left by the absence of the VRFB battery model in commonly used programs for renewable energy systems, such as TRNSYS.

Suggested Citation

  • Muhammed Samil Yesilyurt & Huseyin Ayhan Yavasoglu, 2023. "An All-Vanadium Redox Flow Battery: A Comprehensive Equivalent Circuit Model," Energies, MDPI, vol. 16(4), pages 1-14, February.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:4:p:2040-:d:1073284
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    References listed on IDEAS

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    1. Bizhong Xia & Zhen Sun & Ruifeng Zhang & Zizhou Lao, 2017. "A Cubature Particle Filter Algorithm to Estimate the State of the Charge of Lithium-Ion Batteries Based on a Second-Order Equivalent Circuit Model," Energies, MDPI, vol. 10(4), pages 1-15, April.
    2. Alejandro Clemente & Ramon Costa-Castelló, 2020. "Redox Flow Batteries: A Literature Review Oriented to Automatic Control," Energies, MDPI, vol. 13(17), pages 1-31, September.
    3. Argyrou, Maria C. & Christodoulides, Paul & Kalogirou, Soteris A., 2018. "Energy storage for electricity generation and related processes: Technologies appraisal and grid scale applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 804-821.
    4. Hina Fathima A & Kaliannan Palanisamy & Sanjeevikumar Padmanaban & Umashankar Subramaniam, 2018. "Intelligence-Based Battery Management and Economic Analysis of an Optimized Dual-Vanadium Redox Battery (VRB) for a Wind-PV Hybrid System," Energies, MDPI, vol. 11(10), pages 1-18, October.
    5. Shujuan Meng & Binyu Xiong & Tuti Mariana Lim, 2019. "Model-Based Condition Monitoring of a Vanadium Redox Flow Battery," Energies, MDPI, vol. 12(15), pages 1-16, August.
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    Cited by:

    1. Yesilyurt, Muhammed Samil & Ozcan, Huseyin Gunhan & Yavasoglu, Huseyin Ayhan, 2023. "Co-simulation-based conventional exergy evaluation of a hybrid energy generation-vanadium redox flow battery-air source heat pump system," Energy, Elsevier, vol. 281(C).

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