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Li 3 PO 4 -Coated Graphite Anode for Thermo-Electrochemically Stable Lithium-Ion Batteries

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  • Jong Hun Sung

    (Department of Chemistry and Chemical Institute for Functional Materials, Pusan National University, Busan 46241, Republic of Korea
    Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science & Technology (DGIST), Daegu 42988, Republic of Korea)

  • Taewan Kim

    (Department of Chemistry and Chemical Institute for Functional Materials, Pusan National University, Busan 46241, Republic of Korea)

  • Soljin Kim

    (Department of Chemistry and Chemical Institute for Functional Materials, Pusan National University, Busan 46241, Republic of Korea)

  • Fuead Hasan

    (Department of Chemistry and Chemical Institute for Functional Materials, Pusan National University, Busan 46241, Republic of Korea
    Department of Chemistry, The University of North Carolina at Charlotte, Charlotte, NC 28223, USA)

  • Sangram Keshari Mohanty

    (Department of Chemistry and Chemical Institute for Functional Materials, Pusan National University, Busan 46241, Republic of Korea)

  • Madhusudana Koratikere Srinivasa

    (Department of Chemistry and Chemical Institute for Functional Materials, Pusan National University, Busan 46241, Republic of Korea)

  • Sri Charan Reddy

    (Department of Chemistry and Chemical Institute for Functional Materials, Pusan National University, Busan 46241, Republic of Korea)

  • Hyun Deog Yoo

    (Department of Chemistry and Chemical Institute for Functional Materials, Pusan National University, Busan 46241, Republic of Korea)

Abstract

Extensive research on electrode materials has been sparked by the rising demand for high-energy-density rechargeable lithium-ion batteries (LIBs). Graphite is a crucial component of LIB anodes, as more than 90% of the commercialized cathodes are coupled with the graphite anode. For the advanced graphite anode, the fast charge–discharge electrochemical performance and the thermal stability need to be further improved in order to meet the growing demand. Herein, a graphite anode material’s thermo-electrochemical stability was improved by the surface coating of lithium phosphate (Li 3 PO 4 ; LPO). The graphite anode with a well-dispersed LPO-coating layer (graphite@LPO) demonstrated significant improvement in the cycle and rate performances. The graphite@LPO sample showed a capacity retention of 67.8% after 300 cycles at 60 °C, whereas the pristine graphite anode failed after 225 cycles, confirming the ameliorated thermo-electrochemical stability and cyclability by LPO coating. The improved thermo-electrochemical stability of the graphite@LPO anode was validated by the full-cell tests as well. The performance enhancement by LPO-coating is due to the suppression of the growth of the surface film and charge-transfer resistances during the repeated cycling, as evidenced by the electrochemical impedance spectroscopy analysis.

Suggested Citation

  • Jong Hun Sung & Taewan Kim & Soljin Kim & Fuead Hasan & Sangram Keshari Mohanty & Madhusudana Koratikere Srinivasa & Sri Charan Reddy & Hyun Deog Yoo, 2023. "Li 3 PO 4 -Coated Graphite Anode for Thermo-Electrochemically Stable Lithium-Ion Batteries," Energies, MDPI, vol. 16(17), pages 1-11, August.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:17:p:6141-:d:1223504
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    References listed on IDEAS

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    1. Gert Berckmans & Maarten Messagie & Jelle Smekens & Noshin Omar & Lieselot Vanhaverbeke & Joeri Van Mierlo, 2017. "Cost Projection of State of the Art Lithium-Ion Batteries for Electric Vehicles Up to 2030," Energies, MDPI, vol. 10(9), pages 1-20, September.
    2. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
    3. Jaguemont, J. & Boulon, L. & Dubé, Y., 2016. "A comprehensive review of lithium-ion batteries used in hybrid and electric vehicles at cold temperatures," Applied Energy, Elsevier, vol. 164(C), pages 99-114.
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    Cited by:

    1. Hangning Liu & Lin Wang & Yi Cao & Yingjun Ma & Shan Wang & Jie Wang & Haidong Liu, 2024. "Rational Design of Electrolyte Additives for Improved Solid Electrolyte Interphase Formation on Graphite Anodes: A Study of 1,3,6-Hexanetrinitrile," Energies, MDPI, vol. 17(13), pages 1-11, July.

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