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Test and Modelling of Solid Oxide Fuel Cell Durability: A Focus on Interconnect Role on Global Degradation

Author

Listed:
  • Roberto Spotorno

    (Department of Chemistry and Industrial Chemistry (DCCI), University of Genoa, Via Dodecaneso 31, 16146 Genoa, Italy)

  • Fiammetta Rita Bianchi

    (Department of Civil, Chemical and Environmental Engineering (DICCA), University of Genoa, Via Opera Pia 15b, 16145 Genoa, Italy)

  • Daniele Paravidino

    (Department of Chemistry and Industrial Chemistry (DCCI), University of Genoa, Via Dodecaneso 31, 16146 Genoa, Italy)

  • Barbara Bosio

    (Department of Civil, Chemical and Environmental Engineering (DICCA), University of Genoa, Via Opera Pia 15b, 16145 Genoa, Italy)

  • Paolo Piccardo

    (Department of Chemistry and Industrial Chemistry (DCCI), University of Genoa, Via Dodecaneso 31, 16146 Genoa, Italy)

Abstract

High-temperature fuel cells are a promising technology due to their high energy efficiency and low environmental impacts compared to conventional engines. Nevertheless, they have a limited lifetime which reduces the use to a few application fields. Among them, Solid Oxide Fuel Cells (SOFCs) have had a recent development at the industrial level in two possible configurations: anode- and electrolyte-supported design. Considering the impossibility to experimentally distinguish the effects of every degradation mechanism on global cell performance, each layer should be tested singularly through ex situ tests and then assembled into a virgin cell to evaluate its role on the whole system by in situ tests. However, this procedure results as quite complex, and some further microstructural changes could occur during cell sintering. In order to overcome these constraints, the proposed approach paired ex situ experimental observations on a single element with modelling results on global SOFC. As a case study, CoMnO/Crofer22 APU and CuMnO/AISI 441 interconnect samples were tested, measuring their resistance variation for some hundreds of hours, followed by a detailed post-mortem microstructural analysis. Based on a previously validated local model, SIMFC (SIMulation of Fuel Cells), the durability of commercial anode- and electrolyte-supported cells was simulated, adding specific degradation functions only for the interconnects in order to highlight their influence on SOFC performance.

Suggested Citation

  • Roberto Spotorno & Fiammetta Rita Bianchi & Daniele Paravidino & Barbara Bosio & Paolo Piccardo, 2022. "Test and Modelling of Solid Oxide Fuel Cell Durability: A Focus on Interconnect Role on Global Degradation," Energies, MDPI, vol. 15(8), pages 1-19, April.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:8:p:2762-:d:790129
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    References listed on IDEAS

    as
    1. Fiammetta Rita Bianchi & Barbara Bosio, 2021. "Operating Principles, Performance and Technology Readiness Level of Reversible Solid Oxide Cells," Sustainability, MDPI, vol. 13(9), pages 1-23, April.
    2. Fiammetta Rita Bianchi & Arianna Baldinelli & Linda Barelli & Giovanni Cinti & Emilio Audasso & Barbara Bosio, 2020. "Multiscale Modeling for Reversible Solid Oxide Cell Operation," Energies, MDPI, vol. 13(19), pages 1-16, September.
    3. Emilio Audasso & Fiammetta Rita Bianchi & Barbara Bosio, 2020. "2D Simulation for CH 4 Internal Reforming-SOFCs: An Approach to Study Performance Degradation and Optimization," Energies, MDPI, vol. 13(16), pages 1-19, August.
    4. Gallo, Marco & Costabile, Carmine & Sorrentino, Marco & Polverino, Pierpaolo & Pianese, Cesare, 2020. "Development and application of a comprehensive model-based methodology for fault mitigation of fuel cell powered systems," Applied Energy, Elsevier, vol. 279(C).
    5. Guida, Maurizio & Postiglione, Fabio & Pulcini, Gianpaolo, 2015. "A random-effects model for long-term degradation analysis of solid oxide fuel cells," Reliability Engineering and System Safety, Elsevier, vol. 140(C), pages 88-98.
    6. Stoynov, Zdravko & Vladikova, Daria & Burdin, Blagoy & Laurencin, Jerome & Montinaro, Dario & Raikova, Gergana & Schiller, Günter & Szabo, Patric, 2018. "Differential analysis of SOFC current-voltage characteristics," Applied Energy, Elsevier, vol. 228(C), pages 1584-1590.
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