IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i17p6131-d895883.html
   My bibliography  Save this article

Experimental Optimization with the Emphasis on Techno-Economic Analysis of Production and Purification of High Value-Added Bioethanol from Sustainable Corn Stover

Author

Listed:
  • Sara E. AbdElhafez

    (Fabrication Technology Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Tarek Taha

    (Environmental Biotechnology Department, Genetic Engineering and Biotechnology Research Institute (GEBRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Ahmed E. Mansy

    (Environment and Natural Materials Research Institute (ENMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Eman El-Desouky

    (Chemistry Department, Faculty of Science, Alexandria University, Ibrahimia 21321, Alexandria, Egypt)

  • Mohamed A. Abu-Saied

    (Polymeric Materials Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Khloud Eltaher

    (Chemistry Department, Faculty of Science, Alexandria University, Ibrahimia 21321, Alexandria, Egypt)

  • Ali Hamdy

    (Environmental Biotechnology Department, Genetic Engineering and Biotechnology Research Institute (GEBRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Gomaa El Fawal

    (Polymeric Materials Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Amr Gamal

    (Physics Department, Faculty of Science, Alexandria University, Moharam Bek 21568, Alexandria, Egypt)

  • Aly M. Hashim

    (Central Laboratory, City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Abdallah S. Elgharbawy

    (Materials Science Department, Institute of Graduate Studies and Research (IGSR), Alexandria University, Shatby 21526, Alexandria, Egypt
    The Egyptian Ethylene and Derivatives Company (ETHYDCO), Ameriya 23511, Alexandria, Egypt)

  • Mona M. Abd El-Latif

    (Fabrication Technology Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Hesham Hamad

    (Fabrication Technology Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt
    Faculty of Chemistry, University of Warsaw, Pasteur 1, 02-093 Warsaw, Poland)

  • Rehab M. Ali

    (Fabrication Technology Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

Abstract

Bioethanol-derived biomass is a green sustainable source of energy that is highly recommended as an efficient alternative to the replacement of fossil fuels. However, this type of bioethanol production is always expensive with very low bioethanol concentration. Therefore, this work aims to represent a facile and green approach for bioethanol production with high concentration and purity as well as reasonable cost from corn stover (CS). The goal of this study is to characterize CS and its treated samples with maleic acid (CSM) using various characterization analyses, such as proximate and ultimate analysis, HHV, TGA, FTIR, SEM, and CHNS. The bioethanol production stages: Pretreatment, enzymatic degradation, fermentation, and finally bioethanol separation and purification via the pervaporation process, which have been investigated and optimized are associated with the economic analysis. The optimum operating condition of the pretreatment process was 2% maleic acid, 1:20 solid-to-liquid ratio at 45 psi, 120 °C, and 1 h of operation in the autoclave. This process contributes to 53 and 45% lignin and hemicellulose removal, 98% cellulose recovery, and a glucose yield of 741 mg/dL. The yeast isolate succeeded in the production of 1230 mg/dL of bioethanol. This isolated yeast strain was close to Pichia nakasei with a similarity of 98%, and its amplified 18S rRNA gene sequence was deposited in GenBank with the accession number MZ675535. Poly (MMA- co -MA) membrane was synthesized, characterized, and its efficiency for increasing the bioethanol concentration was evaluated using the integrated pervaporation technique. The techno-economic analysis is presented in detail to evaluate the process profitability, which achieves a considerable profit for the whole duration of the project without any losses as it reaches a net profit of USD 1 million in 2023, reaching USD 2.1 million in 2047 for a company with a capacity of 32 thousand tons per year. The sequential strategy offers a promising approach for efficient bioethanol production under mild and environmentally friendly conditions that enable its implication industrially.

Suggested Citation

  • Sara E. AbdElhafez & Tarek Taha & Ahmed E. Mansy & Eman El-Desouky & Mohamed A. Abu-Saied & Khloud Eltaher & Ali Hamdy & Gomaa El Fawal & Amr Gamal & Aly M. Hashim & Abdallah S. Elgharbawy & Mona M. A, 2022. "Experimental Optimization with the Emphasis on Techno-Economic Analysis of Production and Purification of High Value-Added Bioethanol from Sustainable Corn Stover," Energies, MDPI, vol. 15(17), pages 1-33, August.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:17:p:6131-:d:895883
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/17/6131/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/17/6131/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Campbell, Robert M. & Anderson, Nathaniel M. & Daugaard, Daren E. & Naughton, Helen T., 2018. "Financial viability of biofuel and biochar production from forest biomass in the face of market price volatility and uncertainty," Applied Energy, Elsevier, vol. 230(C), pages 330-343.
    2. Yusuf, Abdulfatah Abdu & Inambao, Freddie L., 2020. "Characterization of Ugandan biomass wastes as the potential candidates towards bioenergy production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 117(C).
    3. Singh, Yengkhom Disco & Mahanta, Pinakeswar & Bora, Utpal, 2017. "Comprehensive characterization of lignocellulosic biomass through proximate, ultimate and compositional analysis for bioenergy production," Renewable Energy, Elsevier, vol. 103(C), pages 490-500.
    4. Behera, Shuvashish & Arora, Richa & Nandhagopal, N. & Kumar, Sachin, 2014. "Importance of chemical pretreatment for bioconversion of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 91-106.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Nasib Qureshi & Xiaoqing Lin & Shunhui Tao & Siqing Liu & Haibo Huang & Nancy N. Nichols, 2023. "Can Xylose Be Fermented to Biofuel Butanol in Continuous Long-Term Reactors: If Not, What Options Are There?," Energies, MDPI, vol. 16(13), pages 1-21, June.
    2. Elsagan, Zahwa A. & Ali, Rehab M. & El-Naggar, Mohamed A. & El-Ashtoukhy, E.-S.Z. & AbdElhafez, Sara E., 2023. "New perspectives for maximizing sustainable bioethanol production from corn stover," Renewable Energy, Elsevier, vol. 209(C), pages 608-618.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. M'Arimi, M.M. & Mecha, C.A. & Kiprop, A.K. & Ramkat, R., 2020. "Recent trends in applications of advanced oxidation processes (AOPs) in bioenergy production: Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    2. Giulio Allesina & Simone Pedrazzi, 2021. "Barriers to Success: A Technical Review on the Limits and Possible Future Roles of Small Scale Gasifiers," Energies, MDPI, vol. 14(20), pages 1-23, October.
    3. Marisutti, Estela & Viegas, Bruno Marques & Rodrigues, Naira Poerner & Ayub, Marco Antônio Záchia & Rossi, Daniele Misturini, 2024. "Characterization and treatments in soybean hull for 2,3-Butanediol production using Klebsiella pneumoniae BLh-1 and Pantoea agglomerans BL1," Renewable Energy, Elsevier, vol. 224(C).
    4. Chapela, Sergio & Cid, Natalia & Porteiro, Jacobo & Míguez, José Luis, 2020. "Numerical transient modelling of the fouling phenomena and its influence on thermal performance in a low-scale biomass shell boiler," Renewable Energy, Elsevier, vol. 161(C), pages 309-318.
    5. Rastogi, Meenal & Shrivastava, Smriti, 2017. "Recent advances in second generation bioethanol production: An insight to pretreatment, saccharification and fermentation processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 330-340.
    6. Solarte-Toro, Juan Camilo & Romero-García, Juan Miguel & Martínez-Patiño, Juan Carlos & Ruiz-Ramos, Encarnación & Castro-Galiano, Eulogio & Cardona-Alzate, Carlos Ariel, 2019. "Acid pretreatment of lignocellulosic biomass for energy vectors production: A review focused on operational conditions and techno-economic assessment for bioethanol production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 587-601.
    7. Vaz, Fernanda Leitão & da Rocha Lins, Jennyfer & Alves Alencar, Bárbara Ribeiro & Silva de Abreu, Íthalo Barbosa & Vidal, Esteban Espinosa & Ribeiro, Ester & Valadares de Sá Barretto Sampaio, Everardo, 2021. "Chemical pretreatment of sugarcane bagasse with liquid fraction recycling," Renewable Energy, Elsevier, vol. 174(C), pages 666-673.
    8. Sadeghi Darvazeh, Saeed & Mansoori Mooseloo, Farzaneh & Gholian-Jouybari, Fatemeh & Amiri, Maghsoud & Bonakdari, Hossein & Hajiaghaei-Keshteli, Mostafa, 2024. "Data-driven robust optimization to design an integrated sustainable forest biomass-to-electricity network under disjunctive uncertainties," Applied Energy, Elsevier, vol. 356(C).
    9. Hu, Sheng-Chun & Cheng, Jie & Wang, Wu-Ping & Zhu, Ya-Hong & Kang, Kang & Zhu, Ming-Qiang & Huang, Xiao-Hua, 2022. "Preparation and analysis of pyroligneous liquor, charcoal and gas from lacquer wood by carbonization method based on a biorefinery process," Energy, Elsevier, vol. 239(PA).
    10. Nathaniel Anderson & Hongmei Gu & Richard Bergman, 2021. "Comparison of Novel Biochars and Steam Activated Carbon from Mixed Conifer Mill Residues," Energies, MDPI, vol. 14(24), pages 1-19, December.
    11. Ortiz, Leandro Rodriguez & Torres, Erick & Zalazar, Daniela & Zhang, Huili & Rodriguez, Rosa & Mazza, Germán, 2020. "Influence of pyrolysis temperature and bio-waste composition on biochar characteristics," Renewable Energy, Elsevier, vol. 155(C), pages 837-847.
    12. Kächele, Rebecca & Nurkowski, Daniel & Martin, Jacob & Akroyd, Jethro & Kraft, Markus, 2019. "An assessment of the viability of alternatives to biodiesel transport fuels," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    13. Cueva Zepeda, Lolita & Griffin, Gregory & Shah, Kalpit & Al-Waili, Ibrahim & Parthasarathy, Rajarathinam, 2023. "Energy potential, flow characteristics and stability of water and alcohol-based rice-straw biochar slurry fuel," Renewable Energy, Elsevier, vol. 207(C), pages 60-72.
    14. Zhang, Changwei & Wen, Hao & Chen, Changjing & Cai, Di & Fu, Chaohui & Li, Ping & Qin, Peiyong & Tan, Tianwei, 2019. "Simultaneous saccharification and juice co-fermentation for high-titer ethanol production using sweet sorghum stalk," Renewable Energy, Elsevier, vol. 134(C), pages 44-53.
    15. Yusuf, Abdulfatah Abdu & Inambao, Freddie L., 2020. "Characterization of Ugandan biomass wastes as the potential candidates towards bioenergy production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 117(C).
    16. Khodaei, Hassan & Olson, Chris & Nikrityuk, Petr, 2019. "Numerical investigations of the impact of inflow conditions on characteristics of a large-scale pyrolysis unit," Energy, Elsevier, vol. 169(C), pages 1101-1111.
    17. Chapela, S. & Porteiro, J. & Garabatos, M. & Patiño, D. & Gómez, M.A. & Míguez, J.L., 2019. "CFD study of fouling phenomena in small-scale biomass boilers: Experimental validation with two different boilers," Renewable Energy, Elsevier, vol. 140(C), pages 552-562.
    18. Zou, Shuzhen & Wang, Hui & Wang, Xiaojiao & Zhou, Sha & Li, Xue & Feng, Yongzhong, 2016. "Application of experimental design techniques in the optimization of the ultrasonic pretreatment time and enhancement of methane production in anaerobic co-digestion," Applied Energy, Elsevier, vol. 179(C), pages 191-202.
    19. Solarte-Toro, Juan Camilo & Chacón-Pérez, Yessica & Piedrahita-Rodríguez, Sara & Poveda Giraldo, Jhonny Alejandro & Teixeira, José António & Moustakas, Konstantinos & Alzate, Carlos Ariel Cardona, 2020. "Effect of dilute sulfuric acid pretreatment on the physicochemical properties and enzymatic hydrolysis of coffee cut-stems," Energy, Elsevier, vol. 195(C).
    20. McKenzie Thomas & Kimberly L. Jensen & Dayton M. Lambert & Burton C. English & Christopher D. Clark & Forbes R. Walker, 2021. "Consumer Preferences and Willingness to Pay for Potting Mix with Biochar," Energies, MDPI, vol. 14(12), pages 1-16, June.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:17:p:6131-:d:895883. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.