IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i18p5903-d637668.html
   My bibliography  Save this article

Corrosion Behavior of VM12-SHC Steel in Contact with Solar Salt and Ternary Molten Salt in Accelerated Fluid Conditions

Author

Listed:
  • Gustavo García-Martin

    (Surface Engineering and Nanostructured Materials Research Group, Faculty of Chemical Sciences, Complutense University of Madrid, Complutense Avenue s/n, 28040 Madrid, Spain)

  • María I. Lasanta

    (Surface Engineering and Nanostructured Materials Research Group, Faculty of Chemical Sciences, Complutense University of Madrid, Complutense Avenue s/n, 28040 Madrid, Spain)

  • María T. de Miguel

    (Surface Engineering and Nanostructured Materials Research Group, Faculty of Chemical Sciences, Complutense University of Madrid, Complutense Avenue s/n, 28040 Madrid, Spain)

  • Andre Illana Sánchez

    (Surface Engineering and Nanostructured Materials Research Group, Faculty of Chemical Sciences, Complutense University of Madrid, Complutense Avenue s/n, 28040 Madrid, Spain)

  • Francisco J. Pérez-Trujillo

    (Surface Engineering and Nanostructured Materials Research Group, Faculty of Chemical Sciences, Complutense University of Madrid, Complutense Avenue s/n, 28040 Madrid, Spain)

Abstract

Ternary low melting point mixtures with the addition of LiNO 3 and Ca(NO 3 ) 2 have been presented as direct system candidates for CSP technologies due to having better physical and chemical properties than those of Solar Salt. In this study, thermal, physical and chemical properties are measured as is the corrosive behavior of stainless alloy VM12 (Cr 12%) when in contact with Solar Salt, 60% NaNO 3 -40% KNO 3 (wt.%) and ternary 46% NaNO 3 -19% Ca(NO 3 ) 2 -35% LiNO 3 (wt.%). Gravimetric weight change measurements were performed on the test specimens, which were tested under accelerated fluid conditions (0.2 m s −1 ) at 500 °C for 2000 h. This research confirms the potential of this novel formulation as a thermal storage medium and validates the suitability of ferritic VM12-SHC stainless steel as a structural material for CSP technology with Solar Salt. Meanwhile, the results obtained by scanning electron microscopy and X-ray diffraction indicate a reduction in the protective character of the oxide layer formed on this alloy when the medium contains calcium and lithium components.

Suggested Citation

  • Gustavo García-Martin & María I. Lasanta & María T. de Miguel & Andre Illana Sánchez & Francisco J. Pérez-Trujillo, 2021. "Corrosion Behavior of VM12-SHC Steel in Contact with Solar Salt and Ternary Molten Salt in Accelerated Fluid Conditions," Energies, MDPI, vol. 14(18), pages 1-16, September.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:18:p:5903-:d:637668
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/18/5903/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/18/5903/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Fernández, Ángel G. & Gomez-Vidal, Judith C., 2017. "Thermophysical properties of low cost lithium nitrate salts produced in northern Chile for thermal energy storage," Renewable Energy, Elsevier, vol. 101(C), pages 120-125.
    2. Mohammad, Mehedi Bin & Brooks, Geoffrey Alan & Rhamdhani, M. Akbar, 2017. "Thermal analysis of molten ternary lithium-sodium-potassium nitrates," Renewable Energy, Elsevier, vol. 104(C), pages 76-87.
    3. Villada, Carolina & Bonk, Alexander & Bauer, Thomas & Bolívar, Francisco, 2018. "High-temperature stability of nitrate/nitrite molten salt mixtures under different atmospheres," Applied Energy, Elsevier, vol. 226(C), pages 107-115.
    4. González-Roubaud, Edouard & Pérez-Osorio, David & Prieto, Cristina, 2017. "Review of commercial thermal energy storage in concentrated solar power plants: Steam vs. molten salts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 133-148.
    5. Parrado, C. & Marzo, A. & Fuentealba, E. & Fernández, A.G., 2016. "2050 LCOE improvement using new molten salts for thermal energy storage in CSP plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 505-514.
    6. Walczak, Magdalena & Pineda, Fabiola & Fernández, Ángel G. & Mata-Torres, Carlos & Escobar, Rodrigo A., 2018. "Materials corrosion for thermal energy storage systems in concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 86(C), pages 22-44.
    7. Fernández, Angel G. & Muñoz-Sánchez, Belen & Nieto-Maestre, Javier & García-Romero, Ana, 2019. "High temperature corrosion behavior on molten nitrate salt-based nanofluids for CSP plants," Renewable Energy, Elsevier, vol. 130(C), pages 902-909.
    8. Wang, Tao & Mantha, Divakar & Reddy, Ramana G., 2013. "Novel low melting point quaternary eutectic system for solar thermal energy storage," Applied Energy, Elsevier, vol. 102(C), pages 1422-1429.
    9. López-González, D. & Valverde, J.L. & Sánchez, P. & Sanchez-Silva, L., 2013. "Characterization of different heat transfer fluids and degradation study by using a pilot plant device operating at real conditions," Energy, Elsevier, vol. 54(C), pages 240-250.
    10. Cabeza, Luisa F. & Gutierrez, Andrea & Barreneche, Camila & Ushak, Svetlana & Fernández, Ángel G. & Inés Fernádez, A. & Grágeda, Mario, 2015. "Lithium in thermal energy storage: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1106-1112.
    11. Gil, Antoni & Medrano, Marc & Martorell, Ingrid & Lázaro, Ana & Dolado, Pablo & Zalba, Belén & Cabeza, Luisa F., 2010. "State of the art on high temperature thermal energy storage for power generation. Part 1--Concepts, materials and modellization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 31-55, January.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Adrián Caraballo & Santos Galán-Casado & Ángel Caballero & Sara Serena, 2021. "Molten Salts for Sensible Thermal Energy Storage: A Review and an Energy Performance Analysis," Energies, MDPI, vol. 14(4), pages 1-15, February.
    2. Fernández, Angel G. & Gomez-Vidal, Judith & Oró, Eduard & Kruizenga, Alan & Solé, Aran & Cabeza, Luisa F., 2019. "Mainstreaming commercial CSP systems: A technology review," Renewable Energy, Elsevier, vol. 140(C), pages 152-176.
    3. Skrbek, Kryštof & Bartůněk, Vilém & Sedmidubský, David, 2022. "Molten salt-based nanocomposites for thermal energy storage: Materials, preparation techniques and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 164(C).
    4. Villada, Carolina & Bonk, Alexander & Bauer, Thomas & Bolívar, Francisco, 2018. "High-temperature stability of nitrate/nitrite molten salt mixtures under different atmospheres," Applied Energy, Elsevier, vol. 226(C), pages 107-115.
    5. Luisa F. Cabeza & Emiliano Borri & Cristina Prieto, 2022. "Bibliometric Map on Corrosion in Concentrating Solar Power Plants," Energies, MDPI, vol. 15(7), pages 1-16, April.
    6. Delise, T. & Tizzoni, A.C. & Menale, C. & Telling, M.T.F. & Bubbico, R. & Crescenzi, T. & Corsaro, N. & Sau, S. & Licoccia, S., 2020. "Technical and economic analysis of a CSP plant presenting a low freezing ternary mixture as storage and transfer fluid," Applied Energy, Elsevier, vol. 265(C).
    7. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    8. Fernández, Ángel G. & Gomez-Vidal, Judith C., 2017. "Thermophysical properties of low cost lithium nitrate salts produced in northern Chile for thermal energy storage," Renewable Energy, Elsevier, vol. 101(C), pages 120-125.
    9. Jayathunga, D.S. & Karunathilake, H.P. & Narayana, M. & Witharana, S., 2024. "Phase change material (PCM) candidates for latent heat thermal energy storage (LHTES) in concentrated solar power (CSP) based thermal applications - A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    10. Saranprabhu, M.K. & Rajan, K.S., 2019. "Magnesium oxide nanoparticles dispersed solar salt with improved solid phase thermal conductivity and specific heat for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 141(C), pages 451-459.
    11. Arias, I. & Cardemil, J. & Zarza, E. & Valenzuela, L. & Escobar, R., 2022. "Latest developments, assessments and research trends for next generation of concentrated solar power plants using liquid heat transfer fluids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    12. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Rood, Mark, 2017. "Thermal energy storage systems for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 82-100.
    13. Islam, Md Tasbirul & Huda, Nazmul & Abdullah, A.B. & Saidur, R., 2018. "A comprehensive review of state-of-the-art concentrating solar power (CSP) technologies: Current status and research trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 987-1018.
    14. Turrini, Sebastiano & Bettonte, Marco & Eccher, Massimo & Grigiante, Maurizio & Miotello, Antonio & Brusa, Roberto S., 2018. "An innovative small-scale prototype plant integrating a solar dish concentrator with a molten salt storage system," Renewable Energy, Elsevier, vol. 123(C), pages 150-161.
    15. ELSihy, ELSaeed Saad & Mokhtar, Omar & Xu, Chao & Du, Xiaoze & Adel, Mohamed, 2023. "Cyclic performance characterization of a high-temperature thermal energy storage system packed with rock/slag pebbles granules combined with encapsulated phase change materials," Applied Energy, Elsevier, vol. 331(C).
    16. Opolot, Michael & Zhao, Chunrong & Liu, Ming & Mancin, Simone & Bruno, Frank & Hooman, Kamel, 2022. "A review of high temperature (≥ 500 °C) latent heat thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 160(C).
    17. Wang, Qiliang & Pei, Gang & Yang, Hongxing, 2021. "Techno-economic assessment of performance-enhanced parabolic trough receiver in concentrated solar power plants," Renewable Energy, Elsevier, vol. 167(C), pages 629-643.
    18. Xu, Xinhai & Vignarooban, K. & Xu, Ben & Hsu, K. & Kannan, A.M., 2016. "Prospects and problems of concentrating solar power technologies for power generation in the desert regions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1106-1131.
    19. Ahmed, Sumair Faisal & Khalid, M. & Rashmi, W. & Chan, A. & Shahbaz, Kaveh, 2017. "Recent progress in solar thermal energy storage using nanomaterials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 450-460.
    20. Li, Xiang & Wang, Yang & Wu, Shuang & Xie, Leidong, 2018. "Preparation and investigation of multicomponent alkali nitrate/nitrite salts for low temperature thermal energy storage," Energy, Elsevier, vol. 160(C), pages 1021-1029.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:18:p:5903-:d:637668. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.