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Characterization of different heat transfer fluids and degradation study by using a pilot plant device operating at real conditions

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  • López-González, D.
  • Valverde, J.L.
  • Sánchez, P.
  • Sanchez-Silva, L.

Abstract

A pilot plant was designed to evaluate the degradation of (heat transfer fluids) HTF for their application in (concentrating solar power) plants CSP. Firstly, the characterization of six HTFs was carried out: two ionic liquids ([BMIM][BF4] and [EMIM][BF4]), two molten salts (Hitec XL and solar salt), a commercial HTF (Mobiltherm 605) and an oil extracted from Nannochloropsis gaditana microalgae (NG oil). Mobiltherm 605 was selected for tuning the pilot plant due to its similarity to HTFs used in CSP, low cost and easy acquisition. The operating conditions were set according to thermogravimetric analysis. Thus, three isothermal experiments were carried out at 140, 160 ant 180 °C for 15 days. Mobiltherm 605 viscosity increased with time indicating that polymerization of hydrocarbon chains took place. Two mathematical models were developed to assess the HTF behaviour in the pilot plant. A mathematical model for the estimation of the most representative parameters (viscosity, heat capacity and overall heat transfer coefficient) of HTF performance was proposed. Furthermore, an activation/deactivation model was proposed to predict the variation of the estimated parameters with time. This model was validated with experimental viscosity measurements (average error of about 3%). Finally, the statistical significance of the model was proved.

Suggested Citation

  • López-González, D. & Valverde, J.L. & Sánchez, P. & Sanchez-Silva, L., 2013. "Characterization of different heat transfer fluids and degradation study by using a pilot plant device operating at real conditions," Energy, Elsevier, vol. 54(C), pages 240-250.
    • Handle: RePEc:eee:energy:v:54:y:2013:i:c:p:240-250
    DOI: 10.1016/j.energy.2013.01.056
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    1. Liu, Guangmin & Qiao, Lina & Zhang, Hong & Zhao, Dan & Su, Xudong, 2014. "The effects of illumination factors on the growth and HCO3− fixation of microalgae in an experiment culture system," Energy, Elsevier, vol. 78(C), pages 40-47.
    2. Lourdes A. Barcia & Rogelio Peón Menéndez & Juan Á. Martínez Esteban & Miguel A. José Prieto & Juan A. Martín Ramos & F. Javier De Cos Juez & Antonio Nevado Reviriego, 2015. "Dynamic Modeling of the Solar Field in Parabolic Trough Solar Power Plants," Energies, MDPI, vol. 8(12), pages 1-17, November.
    3. López-González, D. & Fernandez-Lopez, M. & Valverde, J.L. & Sanchez-Silva, L., 2014. "Pyrolysis of three different types of microalgae: Kinetic and evolved gas analysis," Energy, Elsevier, vol. 73(C), pages 33-43.
    4. Singh, Rajinesh & Rowlands, Andrew S. & Miller, Sarah A., 2013. "Effects of relative volume-ratios on dynamic performance of a direct-heated supercritical carbon-dioxide closed Brayton cycle in a solar-thermal power plant," Energy, Elsevier, vol. 55(C), pages 1025-1032.
    5. López-González, D. & Puig-Gamero, M. & Acién, F.G. & García-Cuadra, F. & Valverde, J.L. & Sanchez-Silva, L., 2015. "Energetic, economic and environmental assessment of the pyrolysis and combustion of microalgae and their oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1752-1770.
    6. Gustavo García-Martin & María I. Lasanta & María T. de Miguel & Andre Illana Sánchez & Francisco J. Pérez-Trujillo, 2021. "Corrosion Behavior of VM12-SHC Steel in Contact with Solar Salt and Ternary Molten Salt in Accelerated Fluid Conditions," Energies, MDPI, vol. 14(18), pages 1-16, September.

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